A kind of preparation method of special brominated epoxy resin for copper clad laminate and the product thereof
A technology for brominated epoxy resin and liquid epoxy resin, which is applied in the field of preparation methods and the products obtained therefrom, can solve the problems of unstable process and general indicators, and achieves good process stability, stable product quality and feasibility. strong effect
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Embodiment 1
[0027] Embodiment 1, the preparation method of brominated epoxy resin special for copper clad laminates of the present invention is as follows:
[0028]Put bisphenol A type liquid epoxy resin into the reaction kettle, under the protection of nitrogen, heat to 78 ° C, start stirring, put tetrabromobisphenol A, bisphenol A type liquid epoxy resin and tetrabromobisphenol A by weight Feed at a ratio of 1:1; heat up to 88°C within 30 minutes after the feed is complete, and add 0.08% tetrabutylammonium bromide, methyltriphenylammonium bromide and polyethylene glycol ( Weight ratio 0.2:1:0.07) mixture; heat and control the temperature at 168 ° C, react for 1 hour to obtain an intermediate resin; add 80% of the amount of tetrabromobisphenol A to the reactor again Bisphenol A liquid epoxy resin , control the reaction temperature at 148°C, react under stirring for 13min to obtain brominated epoxy resin; stop nitrogen flow, add tetrabromobisphenol A addition of 73% acetone to dissolve t...
Embodiment 2
[0030] Embodiment 2, the preparation method of brominated epoxy resin special for copper clad laminates of the present invention is as follows:
[0031] Put bisphenol A type liquid epoxy resin into the reaction kettle, under the protection of nitrogen, heat to 82 ℃, start stirring, put into tetrabromobisphenol A, bisphenol A type liquid epoxy resin and tetrabromobisphenol A by weight Feed at a ratio of 1.4:1; heat up to 92°C within 60 minutes after the feed, add 0.08% tetrabutylammonium bromide, methyltriphenylammonium bromide and polyethylene glycol ( weight ratio 0.4:1:0.09) mixture; heat and control the temperature at 172°C, react for 2 hours to obtain an intermediate resin; add 82% bisphenol A liquid epoxy resin in the amount of tetrabromobisphenol A to the reaction kettle , control the reaction temperature at 152°C, react under stirring for 17min to obtain brominated epoxy resin; stop nitrogen flow, add tetrabromobisphenol A addition of 76% acetone to dissolve the prepa...
Embodiment 3
[0033] Embodiment 3, the preparation method of brominated epoxy resin special for copper clad laminates of the present invention is as follows:
[0034] Put bisphenol A liquid epoxy resin into the reaction kettle, under the protection of nitrogen, heat to 80°C, start stirring, put tetrabromobisphenol A, bisphenol A liquid epoxy resin and tetrabromobisphenol A by weight Feed at a ratio of 1.2:1; heat up to 90°C within 40 minutes after the feed, add 0.08% tetrabutylammonium bromide, methyltriphenylammonium bromide and polyethylene glycol ( Weight ratio 0.3:1:0.08) mixture; heat and control the temperature at 170°C, react for 2 hours to obtain an intermediate resin; add 81% bisphenol A liquid epoxy resin in the amount of tetrabromobisphenol A to the reaction kettle , control the reaction temperature at 150°C, react under stirring for 15 minutes to obtain brominated epoxy resin; stop nitrogen flow, add tetrabromobisphenol A addition of 73% acetone to dissolve the prepared bromin...
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