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Residual oil hydrogenation catalyst and preparation method and application thereof

A residue hydrogenation and catalyst technology, applied in the field of coal chemical industry, can solve the problems of high preparation cost, low metal removal rate, low catalytic activity, etc., and achieve the effects of high holding capacity, inhibiting coking, and improving activity

Active Publication Date: 2014-07-30
福建三聚福大化肥催化剂国家工程研究中心有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problems of low catalytic activity, low metal removal rate and high preparation cost of hydrogenation catalysts in the prior art, and provide a low-cost but high catalytic activity and high metal removal rate residue hydrogenation catalyst

Method used

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  • Residual oil hydrogenation catalyst and preparation method and application thereof
  • Residual oil hydrogenation catalyst and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Grinding and sieving natural bauxite to obtain 300 mesh bauxite;

[0026] (2) Grinding and sieving γ-FeOOH to obtain 300 mesh γ-FeOOH;

[0027] (3) Fully mix 10 parts by weight of bauxite, 80 parts by weight of γ-FeOOH and 10 parts by weight of activated carbon made of blue charcoal, wherein the specific surface area of ​​the activated carbon made of blue charcoal is 980m 2 / g, the pores with a pore radius of 100-200nm account for 60% of the total pore size distribution;

[0028] The activated carbon made of blue charcoal used in this step is to dry mix the commercially available activated carbon made of blue charcoal and KOH pore expander at a mass ratio of 1:2, and then mix it with oxygen and nitrogen (volume ratio 1:9). At 500°C for 0.5h in a tube furnace with an atmosphere; the reamed sample was pickled and washed with water, centrifuged, and dried at 100°C for 3h.

[0029] (4) Ball mill the mixture obtained after thorough mixing to an average particle size of...

Embodiment 2

[0031] (1) Grinding and sieving natural bauxite to obtain 200 mesh bauxite;

[0032] (2) Grinding and sieving γ-FeOOH to obtain 300 mesh γ-FeOOH;

[0033] (3) Fully mix 30 parts by weight of bauxite, 10 parts by weight of γ-FeOOH and 60 parts by weight of coconut shell activated carbon, wherein the specific surface area of ​​the activated carbon is 960m 2 / g, the pore radius of 100-200nm accounts for 61% of the total pore size distribution; the coconut shell activated carbon used in this step is to dry commercially available coconut shell activated carbon and NaOH pore expander with a mass ratio of 1:3 After mixing evenly, put it in a tube furnace with a mixed atmosphere of oxygen and nitrogen (volume ratio 1:8), and carry out hole expansion treatment at 500°C for 0.6h; It was obtained by drying at ℃ for 3h.

[0034] (4) Ball mill the mixture obtained after thorough mixing to an average particle size of 5um to obtain a uniform powder catalyst F2;

Embodiment 3

[0036] (1) Grinding and sieving natural bauxite to obtain 250 mesh bauxite;

[0037] (2) Grinding and sieving γ-FeOOH to obtain 200 mesh γ-FeOOH;

[0038] (3) Fully mix 10 parts by weight of bauxite, 70 parts by weight of γ-FeOOH and 20 parts by weight of woody activated carbon, wherein the specific surface area of ​​the activated carbon is 950m 2 / g, the pores with a pore radius of 100-200nm account for 62% of the total pore size distribution; the wood activated carbon used in this step is to dry mix the commercially available wood activated carbon and NaOH pore expander with a mass ratio of 1:2 After that, put it in a tube furnace with a mixed atmosphere of oxygen and nitrogen (volume ratio 1:9), and carry out hole expansion treatment at 1000°C for 0.5h; after acid washing and water washing, the expanded sample is centrifuged and dried at 100°C 3h got it.

[0039] (4) Ball mill the mixture obtained after thorough mixing to an average particle size of 7um to obtain a unifor...

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Abstract

The invention discloses a residual oil hydrogenation catalyst. The residual oil hydrogenation catalyst is prepared from the following components in parts by weight: 10-30 parts of monohydrallite, 10-80 parts of gamma-FeOOH and 10-60 parts of activated carbon. According to the application, the residual oil hydrogenation catalyst is prepared from monohydrallite, gamma-FeOOH and activated carbon through mixing, carbocation formed by cracking and H. are in direct contact outside, most of carbocation and H. are reacted to form required oil products, and thus coking caused by a condition that short chain hydrocarbon containing carbocation cannot be timely reacted with H. is inhibited; monohydrallite, gamma-FeOOH and activated carbon are blended in a reasonable mass ratio, so that the probability of coking of the catalyst in a high-temperature high-pressure process is reduced, and the metal removal rate of residual oil is improved; the concept that a carrier of a catalyst in the prior art is loaded with expensive active components such as cobalt and molybdenum is abandoned while cheap natural monohydrallite and gamma-FeOOH are used as raw materials, and thus the preparation cost of the catalyst is greatly reduced.

Description

technical field [0001] The invention relates to a residual oil hydrogenation catalyst and a preparation method thereof, belonging to the technical field of coal chemical industry. Background technique [0002] The world's oil resources are increasingly scarce, and the development of heavy and inferior crude oil makes the deep processing and upgrading technology of inferior residue / heavy oil more and more people's attention. Among them, the catalytic cracking process of residual oil is one of the most effective processes for lightening heavy oil, and the use of various hydrogenation catalysts is indispensable in the process of lightening residual oil. [0003] Patent CN103285929A discloses a heavy oil hydrogenation catalyst containing bauxite ore and its preparation and application. The catalyst is composed of bauxite ore powder and a dispersion medium. Based on the catalyst, the mass percentage of bauxite ore powder is 5-70%; the dispersion medium contains the following com...

Claims

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Application Information

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IPC IPC(8): B01J23/745C10G49/02
Inventor 江莉龙曹彦宁魏可镁林科李林马永德
Owner 福建三聚福大化肥催化剂国家工程研究中心有限公司
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