Method for forming fine patterns of semiconductor device using directed self assembly process
A technology of directional self-assembly and fine patterning, which is applied in semiconductor/solid-state device manufacturing, microstructure technology, and photolithography on patterned surfaces, etc. It can solve the problems of forming slot defects, the whole process is intricate, hardened patterns are difficult to remove, etc. question
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[0024] [Example 1 and Comparative Example 1] Formation of fine patterns of semiconductor devices and their evaluation
[0025] A 33 nm argon fluoride organic anti-reflection coating composition (DARC-A125, manufactured by Toshin Semicon Co., Ltd.) was coated on the silicon wafer and heated at 240° C. for 60 seconds. A photoresist composition (DHA-7079 (argon fluoride photoresist), manufactured by Toshin Semicon Co., Ltd.) was coated and soft-baked at 105°C for 60 seconds to form a Linewidth photoresist pattern. Next, the wafer was exposed to an argon fluoride photolithography machine with an aperture number of 0.85 (ASML1200, manufactured by ASML) and heated at 95° C. for 60 seconds to amplify acidic substances generated during exposure. The heated wafer was dipped in a negative developing solution (n-butyl acetate) for 60 seconds and developed to form a line and space pattern (guide pattern) with a line width of 70 nm. In Comparative Example 1, after exposing the photoresis...
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