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A kind of flame-retardant nanoporous SIO2 multistage composite thermal insulation board and preparation method thereof

A nanoporous, thermal insulation board technology, applied in the field of building thermal insulation materials, can solve the problems of complex specific process and modification, limited large-scale application, thick composite material thickness, etc., and achieves excellent thermal insulation effect, excellent barrier effect, and good flexibility. and compressive strength

Inactive Publication Date: 2016-04-27
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its poor mechanical properties and high cost limit its large-scale application in practical engineering.
Feng Junzong of National University of Defense Technology used tetraethyl orthosilicate as silicon source, prepared sol by acid-base two-step method, impregnated fiber felt in sol and then gelled, and prepared flexible thermal insulation composite material under supercritical drying (Feng Jun Zong, Rare Metal Materials and Engineering, 2008, 37 (2): 170-173), the raw materials of this document are similar to those of the composite felt in this patent, but the specific process and modification are more complicated, and the thickness of the prepared composite material is relatively high. thicker, more expensive
Chinese patent application number 95197068.2 "A composite material containing airgel, its preparation method and application" and Chinese patent application number 200510110528.5 "SiO2 airgel for adsorption-two-component non-woven felt composite material and its manufacturing process Method", also adopts the technology of SiO2 airgel and other materials, but its products mostly use inorganic fiber mats with high cost as the core material, and the overall cost is high, which limits its large-scale application in the field of building energy conservation

Method used

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  • A kind of flame-retardant nanoporous SIO2 multistage composite thermal insulation board and preparation method thereof
  • A kind of flame-retardant nanoporous SIO2 multistage composite thermal insulation board and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] 1. Weigh 1.852g of ammonium fluoride (NH4F) and add it to 100mL of deionized water. Then weigh 20.5 g of ammonia solution and add it to the above solution to prepare ammonia water / ammonium fluoride acid-base buffer solution.

[0035] 2. Take 70g of deionized water and 86.8g of absolute ethanol, mix them uniformly, then add 3.64g of ammonia water / ammonium fluoride solution into it, and mix them uniformly by ultrasonic to obtain a catalyst solution. Take 47g of tetraethyl orthosilicate (TEOS), add it into 86.8g of absolute ethanol, and mix it uniformly by ultrasonic to obtain a precursor solution. Add the catalyst solution into the precursor solution, mix it uniformly by ultrasonic, and quickly pour it into a square mold equipped with 30cm*30cm*1mm inorganic fiber needle felt. Stand still for 5-30min to obtain a composite gel.

[0036] 3. Add an appropriate amount of absolute ethanol solution to the composite gel device and age for at least 24 hours, and change the etha...

Embodiment 2

[0039] The first 1-3 steps are similar to Example 1. In the fourth step, a 30cm*30cm*1mm ultra-thin composite felt is fixed in the middle of the phenolic foam board mold, and the distance between the upper and lower surfaces is adjusted (about 15mm). Then, the phenolic foaming raw material is stirred and evenly coated on the upper and lower surfaces of the composite felt, and finally left to stand at room temperature for a period of time for foaming to form an integrally formed single-layer inorganic composite felt and double-layer phenolic foam composite sandwich panel.

Embodiment 3

[0041] The overall process is similar to Example 1, except that in the 4th step, the phenolic foamed sheet is replaced with a polyurethane foamed sheet. A single-layer polyurethane foam composite board covered by an integrally formed double-layer inorganic composite felt can be obtained.

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Abstract

The invention provides a novel flame-retardant nanopore SiO2 multistage compound insulation board and a preparation method thereof. The compound insulation board is formed by an organic foam inner core and an ultrathin inorganic cladding layer multistage compound; the multistage compound comprises a single-layer organic foam inner core and a multilayer ultrathin inorganic cladding layer compound, a multilayer organic foam inner core and a single-layer ultrathin inorganic cladding layer compound, and a multilayer organic foam inner core and a multilayer ultrathin inorganic cladding layer compound. According to the compound insulation board and the preparation method thereof, the preparation cost is low, the process is simple, conditions are mild, batch production of the compound insulation board can be realized, the compound insulation board has a wide application prospect in the fields of construction, traffic, petrochemical industry, aviation and aerospace, and energy source.

Description

technical field [0001] The technical field of the invention belongs to the field of building insulation materials, and relates to a method for preparing a flame-retardant and heat-insulating composite material, specifically a nanoporous SiO2 / inorganic fiber needle-punched felt multi-stage composite material and its preparation method. Background technique [0002] With the rapid advancement of my country's industrialization process, rapid economic development, and continuous improvement of urbanization, energy issues have become the main factor restricting economic development, and energy conservation is urgent. The development of thermal insulation materials is closely related to whether my country can realize the strategy of green, energy saving and sustainable development. As our country pays more and more attention to energy conservation and environmental protection, the insulation technology of building maintenance structures is also increasingly strengthened, especiall...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): E04B1/80D06M11/79B32B27/12B32B27/40B32B27/42B32B37/15
CPCY02A30/242Y02B80/10
Inventor 王戈金召奎高鸿毅彭超豪栾奕齐悦彭雄钱伟
Owner UNIV OF SCI & TECH BEIJING
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