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Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof

An environmentally friendly and blending technology, applied in the field of polymer materials, to achieve high strength, short burning time, and high environmental protection performance

Active Publication Date: 2014-04-30
SHANGHAI PRET COMPOSITES +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, different from the relatively simple components and synthesis process of halogen-based flame retardants, the phosphorus-nitrogen intumescent halogen-free flame retardant IFR often involves the synthesis and use of multiple organic compounds, which will inevitably affect the performance of flame retardants. Some environmental indicators such as odor and total carbon (TVOC) of flammable materials have negative impacts, especially when used as automotive interior parts, and related situations have not attracted attention in the current research on halogen-free flame retardant

Method used

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  • Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof
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  • Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Soak 3g of carbon fiber in 1mol / L NaOH solution for 24 hours, take it out and filter it, put it into a muffle furnace, burn it at 600°C under aerobic conditions for 30 minutes, rinse it repeatedly with deionized water after cooling, and dry it The carbon fiber after surface activation treatment is obtained.

[0033] Weigh 57g of PC resin, 30g of ABS resin, and 10g of flame retardant, and put them into a high-speed mixer together with 3g of carbon fiber and mix them evenly. Put the obtained mixed raw material into the main feeding bin of twin-screw extrusion, and put it into the barrel of the main machine through the feeding screw. The diameter of the screw of the extruder is 35 mm, the ratio of length to diameter L / D=36, and the speed of the main machine is 400 rpm , the control temperature of each section of the main barrel (from the feed port to the outlet of the machine head) is 215°C, 220°C, 225°C, 230°C, 230°C, 230°C, and the speed of the main engine is 300 rpm. Af...

Embodiment 2

[0035] Soak 6g of carbon fiber in 1mol / L NaOH solution for 24 hours, take it out and filter it, put it in a muffle furnace, burn it at 600°C under aerobic conditions for 30 minutes, rinse it repeatedly with deionized water after cooling, and dry it The carbon fiber after surface activation treatment is obtained.

[0036] Weigh 57g of PC resin, 27g of ABS resin, and 10g of flame retardant, put them into a high-speed mixer together with 6g of carbon fiber and mix them evenly. Put the obtained mixed raw material into the main feeding bin of twin-screw extrusion, and put it into the barrel of the main machine through the feeding screw. The diameter of the screw of the extruder is 35 mm, the ratio of length to diameter L / D=36, and the speed of the main machine is 400 rpm , the control temperature of each section of the main barrel (from the feed port to the outlet of the machine head) is 215°C, 220°C, 225°C, 230°C, 230°C, 230°C, and the speed of the main engine is 300 rpm. After me...

Embodiment 3

[0038] Soak 8g of carbon fiber in 1mol / L NaOH solution for 24 hours, take it out and filter it, put it into a muffle furnace, burn it at 800°C under aerobic conditions for 30 minutes, rinse it repeatedly with deionized water after cooling, and dry it The carbon fiber after surface activation treatment is obtained.

[0039] Weigh 57g of PC resin, 25g of ABS resin, and 10g of flame retardant, and put them into a high-speed mixer together with 8g of carbon fiber and mix them evenly. Put the obtained mixed raw material into the main feeding bin of twin-screw extrusion, and put it into the barrel of the main machine through the feeding screw. The diameter of the screw of the extruder is 35 mm, the ratio of length to diameter L / D=36, and the speed of the main machine is 400 rpm , the control temperature of each section of the main barrel (from the feed port to the outlet of the machine head) is 215°C, 220°C, 225°C, 230°C, 230°C, 230°C, and the speed of the main engine is 300 rpm. Af...

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Abstract

The invention discloses a highly environmental-friendly flame retardant reinforced PC / ABS blending material and a preparation method thereof. The flame retardant reinforced PC / ABS blending material comprises the following raw materials in percentage by weight: 50-80% of PC, 10-30% of ABS, 5-15% of flame retardant and 3-15% of carbon fiber. The carbon fiber is subjected to surface activating treatment. The flame retardant reinforced PC / ABS blending material obtained through the technical scheme of the invention has the many advantages, such as high strength, high flame retardance and high environmental-friendly property. By addition of the carbon fiber subjected to surface activation, stretching and bending performance of the blending material can be enhanced, and various organic volatile matter constituents in the PC / ABS can be adsorbed effectively by lots of micropores on the surface of the carbon fiber, so that multiple environmental indexes, such as material odor and TVOC (Total Volatile Organic Compounds), are improved, more importantly, the promotion of environmental performance is not at the cost of sacrificing the flame retardance of material, on the contrary, the flame retardance of the blending material is also promoted, the combustion time of the blending material away from the fire becomes shorter, and the self-extinguish ability of the blending material becomes better.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a highly environmentally friendly flame-retardant reinforced polycarbonate (PC) / acrylonitrile-butadiene-styrene (ABS) blend material and a preparation method thereof. Background technique [0002] On the one hand, the PC / ABS blend material has the high mechanical properties, impact resistance, excellent heat resistance and chemical resistance of PC materials, and the addition of ABS can make up for the processing problems caused by the high melt viscosity of PC. , so that the processing fluidity of the material is greatly improved, and there is good compatibility between the two, so it is widely used in the fields of automobile interior and exterior decoration, electric tools, household appliances and lighting equipment. [0003] With the continuous development of the modern automobile industry, automobiles have become an indispensable and important tool in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L55/02C08K13/06C08K9/02C08K9/00C08K7/06B29B9/06B29C47/92B29C48/92
CPCB29C48/625B29C48/04B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 郑云龙陈永东郭思斯张祥福周文
Owner SHANGHAI PRET COMPOSITES
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