Polyester fiber mass flame-retardant master batch and preparation method thereof

A technology of flame retardant masterbatch and polyester fiber, which is applied in the manufacture of fire retardant and flame retardant filaments, etc., can solve the problems of high development cost of copolymerized flame retardants, poor flame retardant durability of fibers, and damage to physical properties of fibers. Conducive to healthy production, good flame retardant effect and small addition amount

Inactive Publication Date: 2014-04-09
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantage of this method is that the flame retardant performance is durable and washable, and the disadvantage is that the process is slightly complicated, the development cost of the copolymerized flame retardant is high, and the performance of the polyester is greatly affected.
[0004] (2) Blending flame retardant modification: This method is to blend and granulate ordinary polyester with flame retardants and then spin. Since it does not involve changes in the polymerization production process, it is simple and easy to operate, and the operating cost is low, but the fiber The flame retardant durability is worse than that of the copolymerization modification method
However, this method requires relatively high technical conditions, complicated process routes, and is difficult to industrialize.
[0007] (5) Flame retardant finishing of polyester fabric: The polyester fabric is dipped or padded in a solution containing a flame retardant, and then cross-linked to form a thin film on the outer layer of the fabric to achieve the flame retardant effect, but the flame retardant durability Not high, the fabric feels poor; at the same time, it has certain damage to the physical properties of the fiber, and the processing cost is high
[0008] Therefore, all there is certain defective in above-mentioned polyester fiber flame retardant method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A flame retardant masterbatch of polyester fiber before spinning, its components are proportioned by mass percentage: terpolymer resin 20%, decabromodiphenyl ether (DBDPO) 72%, talcum powder 1.5%, titanate coupling 2% polyethylene glycol, 0.5% compound of hindered phenol antioxidant 1010 and phosphite antioxidant 168, among which, the ternary copolymer resin is composed of diol terephthalate, Co-condensation polymer of three monomers of diol isophthalate and polyol terephthalate under the action of catalyst and stabilizer.

[0022] Preparation method: mix the components according to the weight ratio, then add them into a high-speed mixer with a rotation speed of 500-1500 rpm, mix at a mixing temperature of 140°C-180°C for 10-20 minutes, and then add the mixed materials into the double Melting and blending in a screw extruder, the melting temperature is controlled at 270°C-290°C, the screw speed is 100-300 rpm, sheared and mixed by a twin-screw extruder for 10-15 minutes...

Embodiment 2

[0024] A flame-retardant masterbatch of polyester fiber before spinning, the components of which are: 10% ternary copolymer resin, 80% tetrabromobisphenol A bishydroxyethyl ether (TBA-EO), 2% kaolin , 3% silane coupling agent, 4% trimethylolethane, 1% compound of hindered phenol antioxidant 1010 and phosphite antioxidant 168, in which the ternary copolymer resin is made of terephthalate Co-condensation polymer of three monomers of diol formate, diol isophthalate and polyol terephthalate under the action of catalyst and stabilizer.

[0025] Preparation method: mix the components according to the weight ratio, then add them into a high-speed mixer with a rotation speed of 500-1500 rpm, mix at a mixing temperature of 140°C-180°C for 10-20 minutes, and then add the mixed materials into the double Melting and blending in a screw extruder, the melting temperature is controlled at 270°C-290°C, the screw speed is 100-300 rpm, sheared and mixed by a twin-screw extruder for 10-15 minute...

Embodiment 3

[0027] A kind of flame retardant masterbatch of polyester fiber before spinning, its components are proportioned by mass percentage: terpolymer resin 30%, decabromodiphenyl ether (DBDPO) 65%, aluminum hydroxide 1%, aluminum-titanium composite couple 1.5% of joint agent, 2% of calcium stearate, 0.5% of compound of hindered phenol antioxidant 1076 and phosphite antioxidant 168, among which, ternary copolymer resin is made of diol terephthalate Co-condensation polymer of three monomers, diol isophthalate and polyol terephthalate, under the action of catalyst and stabilizer.

[0028] Preparation method: mix the components according to the weight ratio, then add them into a high-speed mixer with a rotation speed of 500-1500 rpm, mix at a mixing temperature of 140°C-180°C for 10-20 minutes, and then add the mixed materials into the double Melting and blending in a screw extruder, the melting temperature is controlled at 270°C-290°C, the screw speed is 100-300 rpm, sheared and mixed ...

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Abstract

The invention discloses a polyester fiber mass flame-retardant master batch and a preparation method thereof. The polyester fiber mass flame-retardant master batch comprises, by mass, 10-30% of a resin carrier, 50-80% of a flame retardant, 0.5-2% of a nucleating agent, 0.5-3% of a coupling agent, 2-4% of a dispersant and 0.1-1% of an antioxidant. A terpolymer resin is adopted as the carrier, has a good compatibility with a polyester fiber, and has a good fluidity, and the prepared flame-retardant master batch has the advantages of good flame retardation property, small consumption, good thermal stability, low cost, simple use, environmental protection, benefiting for healthy production and the like when the flame-retardant master batch is used in the mass flame retardation modification of the polyester fiber. The preparation method is simple and practical, and has a wide application prospect.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a polyester fiber pre-spinning flame-retardant masterbatch and a preparation method thereof. Background technique [0002] Polyester fiber refers to polyethylene terephthalate (PET) fiber, which has excellent performance, easy-to-obtain raw materials, and a wide range of uses. It is the fastest growing, highest-yield, and most widely used synthetic fiber. Synthetic fibers are known as the king of fibers in the 21st century. Polyester fibers are widely used in clothing, carpets and decorative fabrics due to their excellent properties such as high strength, dimensional stability, and chemical corrosion resistance. However, polyester fibers are flammable and flammable fibers, and flame retardant treatment of polyester fibers to reduce the risk of polyester fabrics in fire has become a research direction that has been widely concerned. Usually, the flame retardant of poly...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08K13/02C08K5/06C08K5/136C08K3/34C08K3/22D01F1/07
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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