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Recycling method of fur oxidation dyeing chrome mordant dye liquor

A technology of oxidative dyeing and mordant dyeing, which is applied in dyeing, textiles and papermaking, etc. It can solve the problems of environmental pollution, pollution, waste of industrial salt and chemical materials, etc., and achieve the effect of reducing production costs and pollution

Inactive Publication Date: 2014-03-26
ZHEJIANG ZHONGHUI FUR & LEATHER +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The industrial salt whose main component is sodium chloride is also very serious to the environment, so the discharge of mordant dyeing waste liquid will 1) waste precious chromium resources; 2) waste industrial salt and other chemical materials; 3) increase the difficulty of fur processing sewage treatment , dichromate, sodium chloride will cause serious pollution to the environment
In addition, during chrome retanning or chrome mordant dyeing of chrome tanned fur, there will be chrome tanning agent detanned into the mordant solution. The chrome mordant solution contains a large amount of dichromate, which allows enterprises to accurately and quantitatively detect the mordant and industrial The salt content brings certain difficulties, so the recycling of chrome mordant solution is more difficult to control

Method used

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  • Recycling method of fur oxidation dyeing chrome mordant dye liquor
  • Recycling method of fur oxidation dyeing chrome mordant dye liquor

Examples

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Effect test

Embodiment 1

[0016] Example 1 Recycling process of dyeing black chrome mordant on mink fur blanket

[0017] 1) New chromium mordant dyeing process: total water volume 4 tons, mink fur blanket 200kg, temperature 31-32℃, potassium dichromate 2.7g / L, formic acid 0.3g / L, industrial salt 40g / L, wetting agent HAC (American Raunstein Company) 0.5g / L, pH=4.8.

[0018] Operation: in the slotting. Add water to the groove, adjust the temperature and the amount of water, add potassium dichromate, industrial salt, penetrant, and formic acid, and stroke for 15 minutes to dissolve and distribute evenly, and the pH reaches 4.8. Shake off the fur blanket after shaking. It was added to the slot (200kg) facing outwards, stroked for 60 minutes, and then stroked for 10 minutes every hour. The total time is 10 hours, the peeling of the skin and the water, the mordanting waste that was thrown out and the remaining mordanting waste in the groove are collected and reused.

[0019] 2) The first recycle of mordant dyein...

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Abstract

The invention discloses a recycling method of fur oxidation dyeing chrome mordant dye liquor, which comprises the following steps: preparing new mordant dye liquor, adding fur and performing mordant dyeing; performing microfiltration treatment on fur chrome mordant dyeing waste liquid by use of filter cloth to remove impurities; and supplementing sodium bichromate or potassium bichromate, industrial salt and a penetrant, so that the chrome mordant dye liquor can be recycled repeatedly, and the pollution of bichromate is remarkably alleviated. According to statistics, by the method disclosed by the invention, the recycling frequency of the chrome mordant dye liquor can exceed 100 times, the bichromate is saved by 20%-40%, the industrial salt is saved by 50%-75%, the penetrant is saved by over 90%, and water is saved by over 70%, thereby greatly reducing the production cost and remarkably alleviating environmental pollution.

Description

Technical field [0001] The invention relates to a method for recycling fur oxidation dyeing chromium mordant liquor. Background technique [0002] Dyeing can increase the variety of fur products and increase the added value of products. Oxidation dyeing of fur refers to dyeing with oxidation dye, a special dye for fur. Oxidation dyes are special dyes for fur, so they are also called fur dyes, or Ursi and Ursul dyes. In fact, oxidation dyes are only intermediates of dyes. They cannot directly color the fur, and must undergo oxidation to develop color. Oxidation dyes have the advantages of small molecules, good permeability, low dyeing temperature (28℃-32℃), soft color, realistic imitation dyeing, and little adverse effect on the feel of fur skins. Therefore, oxidation dyeing is widely used in mink, Dyeing of high-end furs such as fox, yellow wolf, muskrat and imitation dyeing of high-end fur with low-end fur. However, the fastness of oxidation dyes is not high, so mordant dyei...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/36D06P1/32D06P3/30
Inventor 马建标程凤侠俞中坚张晓镭王学川
Owner ZHEJIANG ZHONGHUI FUR & LEATHER
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