High temperature carbon dioxide adsorbent and preparation method
A carbon dioxide and adsorbent technology, applied in the field of high-temperature carbon dioxide adsorbent, can solve the problems of low absorption rate, stability, repeatability, long reaction time, low absorption rate, etc., achieving simple preparation process, stable sample performance, The effect of reducing energy consumption
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Embodiment 1
[0018] SiO 2 : Li 2 CO 3 : (sodium carbonate + potassium carbonate) according to the molar ratio of 1:2:0.01 to mix the ingredients, take 200g into the beaker, then add ethanol and stir evenly, then pour into the ball mill, homogenize and refine again. Sinter at 750°C for 2 hours, and then grind and refine again to obtain a finer Na and K element co-doped lithium silicate ceramic material. The obtained co-doped lithium silicate material is tested for carbon dioxide absorption rate in a thermogravimetric analyzer , During the test, the temperature was raised from room temperature to 700°C at a rate of 5°C / min, and it was kept at 700°C for 20 minutes to take advantage of the full progress of the reaction. When it reached the adsorption-release equilibrium, the absorption rate was 25wt%, and then carried out When the temperature continues to rise, carbon dioxide will be released. When the temperature reaches 900°C, all carbon dioxide will be released. Repeat this to test the nu...
Embodiment 2
[0020] The preparation method is the same as in Example 1, except that the sintering time is 6 hours, and the others are the same as 1. The absorption rate when reaching the absorption-release equilibrium is 28wt%, and at the same time, when the number of cycles is 10, the attenuation is 3.4%.
Embodiment 3
[0022] SiO 2 : Li 2 CO 3 : (sodium carbonate + potassium carbonate) according to the molar ratio of 1:2:0.02 to mix the ingredients, take 200g into the beaker, then add ethanol and stir evenly, then pour into the ball mill, homogenize and refine again. Sintered at 800°C for 6 hours, then finer Na and K element co-doped lithium silicate ceramic materials were obtained by grinding again, and the obtained co-doped lithium silicate materials were tested for carbon dioxide absorption rate, which reached the adsorption-release The absorption rate at equilibrium is 45wt%, and the attenuation is 3% when the number of cycles is 15.
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