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Iron-series deoxidizing agent

An iron-based deoxidizer and filler technology, applied in the field of deoxidizers, can solve the problems of high technical requirements in the ingredients and packaging links, the performance of the deoxidizer is not stable enough, and is not suitable for use in large packaging, so that the packaging process is easier to operate and reduce. Moisture loss, stable and reliable performance

Inactive Publication Date: 2015-02-25
HANGZHOU JUJU TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. If the content of activated carbon as a catalyst is increased, the catalytic reaction speed will be greatly increased, resulting in the accumulation of heat, resulting in the evaporation of internal water, which in turn restricts the oxygen absorption reaction, resulting in unstable performance of the deoxidizer; at the same time, it will affect the production The ingredients and packaging process in the process have high technical requirements; the subcontracting time of the product in the process of putting into the modified atmosphere packaging is shortened, and the operation difficulty is increased
[0005] 2. If the content of iron powder is increased, the total oxygen absorption capacity will be increased, but due to the smaller particle size and higher density of iron powder, the overall density of the formula will be too large
[0006] To sum up, when the content of catalyst and reduced iron powder in the deoxidizer formula is relatively high, the performance of the deoxidizer will be unstable, the processing operation will be complicated, the cost of raw materials will be high, and it will not be suitable for large packaging.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Accurately weigh 65kg of reduced iron powder, 11kg of zeolite, 4kg of vermiculite, and 2kg of superabsorbent resin into the sugar coating machine, and stir evenly. Add 2.5kg of sodium chloride to 13.5kg of tap water and stir until completely dissolved. Put the salt water into the shower, spray it slowly and evenly into the sugar coating machine, and mix the materials evenly with an iron rake. Add 2kg of activated carbon and stir evenly. Take it out with a candy shovel, put it in a bag and ripen it for later use.

[0035] Determination of performance of iron-based deoxidizer. Specific method: select two grain piles 0D4-1 and 0D4-2 in different positions, both of which are 19.5m long x 5.8m wide x 4.25m high, and the sealing method is five-sided sealing of polyvinyl chloride film grooved tubes, and put in deoxidation Before injection, the negative pressure in the membrane is required to be 500Pa-250Pa, and the half-life is more than 5min. The specification of the deox...

Embodiment 2

[0039] Accurately weigh 65kg of reduced iron powder, 11kg of zeolite, 4kg of diatomaceous earth, and 2kg of superabsorbent resin into the sugar coating machine, and stir evenly. Add 2.5kg of calcium chloride to 13.5kg of tap water and stir until completely dissolved. Put the salt water into the shower, spray it slowly and evenly into the sugar coating machine, and mix the materials evenly with an iron rake. Add 2kg of activated carbon and stir evenly. Take it out with a candy shovel, put it in a bag and ripen it for later use.

[0040] Determination of performance of iron-based deoxidizer. Concrete method: with embodiment 1. Wherein the initial oxygen concentration is 20.6%.

[0041] After being treated with iron-based deoxidizer for 48 hours, the oxygen concentration in the film of the above grain piles all dropped to below 14.9%, and after 88 days, the oxygen concentration in the film of each grain pile dropped to below 1.5%.

Embodiment 3

[0043] Accurately weigh 50kg of reduced iron powder, 29.8kg of zeolite, 2.8kg of white carbon black, 0.8kg of superabsorbent resin, and 2.8kg of calcium hydroxide into the sugar coating machine, and stir evenly. Add 2.1kg of potassium bromide to 10.6kg of tap water and stir until completely dissolved. Put the salt water into the shower, spray it slowly and evenly into the sugar coating machine, and mix the materials evenly with an iron rake. Add 1.1kg of activated carbon and stir evenly. Take it out with a candy shovel, put it in a bag and ripen it for later use.

[0044] Determination of performance of iron-based deoxidizer. Concrete method: with embodiment 1. Wherein the initial oxygen concentration is 20.6%.

[0045] After being treated with iron-based deoxidizer for 48 hours, the oxygen concentration in the above-mentioned grain piles decreased to below 15.3%, and after 88 days, the oxygen concentration in each grain pile dropped to below 2.3%.

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PUM

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Abstract

The invention discloses an iron-series deoxidizing agent. The agent is prepared from raw materials comprising, by weight, 45-65% of reductive iron powder, 0.2-2% of activated carbon, 1.5-3.5% of electrolyte, 12.5-43% of fillers, 0.2-2% of polyacrylic acid-series super absorbent resin, 0-5% of alkali compounds and 9-16% of tap water. The iron-series deoxidizing agent is stable and reliable in performance, easy and convenient to process and operate, low in cost and more suitable for large-package use, and can be widely applied to storage of grain like rice, japonica rice, corn and flour.

Description

technical field [0001] The invention relates to a deoxidizer, in particular to a deoxidizer in modified atmosphere packaging of grain depots. Background technique [0002] Deoxidizer is also called oxygen scavenger. It removes the free oxygen in the packaging or container through the rapid chemical reaction between the deoxidizer and oxygen, so that the stored product is in an oxygen-free environment, inhibits the harm of aerobic microorganisms and insect pests, and prevents the quality of oxidative fission. For safe storage purposes. Deoxidizers are divided into two categories: deoxidizers formed of inorganic materials and deoxidizers formed of organic materials. In recent years, the series of inorganic substances has developed rapidly. In terms of cost and safety, iron-based deoxidizers of inorganic materials are the most widely used deoxidizers in controlled atmosphere storage. [0003] Existing inorganic iron-based deoxidizers are generally realized by increasing the c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/06A23B9/20
Inventor 魏炬明鲍一鸣周晶
Owner HANGZHOU JUJU TECH
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