Preparation method of CeO2-ZrO2-Al2O3 oxygen-storage material
A technology of ceo2-zro2-al2o3 and oxygen storage materials, which is applied in the field of microwave calcination co-precipitation preparation, can solve the problems of incomplete cerium-zirconium complexes, uneven particle mixing, and insufficient uniformity, and achieve easy automatic control and thermal stability Good, high heating effect
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Embodiment 1
[0029] Firstly, 25%Ce(NO 3 ) 3 ·6H 2 O, 25%Zr(NO 3 ) 4 ·8H 2 O and 50%Al(NO 3 ) 3 ·6H 2 O was added to deionized water to prepare a mixed salt solution, and 2% H 2 o 2 Will Ce 3+ Oxidized to Ce 4+ , the solution changed from colorless to light yellow, then added 5% PVA, and stirred for 30min. Then mix ammonium carbonate and ammonia water according to the mass ratio of 1:1 to prepare a buffered alkali solution for later use. The mixed salt solution and the prepared buffered alkali solution are mixed by co-current method and continuously stirred, and the pH of the solution is controlled to be 8. After the purplish red precipitation is complete, it is aged at 85°C for 8h. The aged solution was vacuum filtered to obtain CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor filter cake A. The obtained CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor filter cake is dried in a 2.45GHz frequency industrial microwave oven with a microwave heating power ...
Embodiment 2
[0031] Firstly, 25%Ce(NO 3 ) 3 ·6H 2 O, 25%Zr(NO 3 ) 4 ·8H 2 O and 50%Al(NO 3 ) 3 ·6H 2 O was added to deionized water to prepare a mixed salt solution, and 3% H 2 o 2 Will Ce 3+ Oxidized to Ce 4+ , the solution changed from colorless to light yellow, then added 7.5% PVA, and stirred for 45min. Then, ammonium carbonate and ammonia water are formulated into a buffered alkali solution according to the mass ratio of 3:2 for later use. The mixed salt solution and the prepared buffered alkali solution are mixed in parallel and continuously stirred to control the pH of the solution to 9. After the purplish red precipitation is complete, it is aged at 90°C for 6h. The aged solution was vacuum filtered and spray-dried to obtain CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor powder B. The obtained CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor filter cake is dried in a 2.45GHz frequency industrial microwave oven with a microwave heating power o...
Embodiment 3
[0033] Firstly, 25%Ce(NO 3 ) 3 ·6H 2 O, 25%Zr(NO 3 ) 4 ·8H 2 O and 50%Al(NO 3 ) 3 ·6H 2 O was added to deionized water to prepare a mixed salt solution, and 5% H 2 o 2 Will Ce 3+ Oxidized to Ce 4+ , the solution changed from colorless to light yellow, then added 10% PVA, and stirred for 60min. Then, ammonium carbonate and ammonia water are formulated into a buffered alkali solution according to the mass ratio of 4:3 for later use. The mixed salt solution and the prepared buffered alkali solution are mixed by co-current method and continuously stirred, and the pH of the solution is controlled to be 10. After the purplish red precipitation is complete, it is aged at 95°C for 4h. The aged solution was vacuum filtered and spray-dried to obtain CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor powder C. The obtained CeO 2 -ZrO 2 -Al 2 o 3 Oxygen storage material precursor filter cake is dried in a 2.45GHz frequency industrial microwave oven with a micro...
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