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Preparation method of mixed fluorescent film for broadband silicon-based detector

A detector and broadband technology, which is applied in the field of preparation of mixed fluorescent films, can solve the problems that frequency conversion films cannot achieve effective response sensitivity, weak response, etc. Effect

Inactive Publication Date: 2013-09-11
UNIV OF SHANGHAI FOR SCI & TECH
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Problems solved by technology

[0003] The present invention is aimed at the problem that the current frequency-converting film that converts ultraviolet light into visible light cannot achieve effective response sensitivity in a wider ultraviolet band, and proposes a method for preparing a mixed fluorescent film for a wide-band silicon-based detector. Lumogen powder It is mixed with Coronene powder according to a specific process and spin-coated to form a film. This hybrid film overcomes the defect of weak response of a single fluorescent material in some bands, and achieves complementary enhancement in the spectral response range.

Method used

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Embodiment Construction

[0011] Preparation method of mixed fluorescent film for broadband silicon-based detector:

[0012] First, the Lumogen powder and the Coronene powder were pre-treated using an agate mortar, respectively, and put into a designated beaker after processing.

[0013] Secondly, use toluene solution as a solvent and nitrocellulose colloidal solution as a binder, and put them together into a beaker containing fluorescent powder. During the configuration process, use a magnetic stirrer to heat and stir the mixed solution to make a suspended colloidal solution. .

[0014] Finally, take an appropriate amount of suspension colloid solution, drop it on the photosensitive surface or on the quartz glass substrate, and at the same time, vacuum absorb the sample on a spin coater, and spin coat it to form a film.

[0015] The hybrid frequency conversion film prepared by the invention can effectively absorb ultraviolet light, and the excitation spectrum covers deep ultraviolet to near ultraviol...

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Abstract

The invention relates to a preparation method of a mixed fluorescent film for a broadband silicon-based detector, which comprises the following steps of: performing grinding pretreatment of Lumogen powder and Coronene powder respectively by use of an agate mortar, and then putting into a designated beaker; preparing a suspension colloidal solution by taking a toluene solution as a solvent and a nitrocotton colloidal solution as an adhesive; fetching a proper amount of the suspension colloidal solution, and dropwise adding on a photosensitive surface or quartz glass substrate; and meanwhile, performing vacuum adsorption of a sample on a spin coater, and performing spin coating to obtain a film. The preparation method does not damage the crystal structure characteristics of two fluorescent materials so as to guarantee the consistency of the luminescence characteristics of the two fluorescent materials before and after film formation; the film compensates for the defect of low quantum efficiency of a single fluorescent material at partial band; compared with the traditional thermal evaporation technology, the preparation technology is simple to operate, and the material utilization rate is remarkably improved; and the preparation method provided by the invention reduces the experimental cost, and is time-saving and efficient and favorable for the industrial development of a silicon-based imaging device.

Description

technical field [0001] The invention relates to an ultraviolet enhanced coating technology, in particular to a preparation method of a mixed fluorescent film used for a wide-band silicon-based detector. Background technique [0002] Since the light wave in the ultraviolet band has a very small penetration depth in polysilicon, general imaging devices such as CCD and CMOS have a weak response in the ultraviolet band. Since photodetectors such as CCD and CMOS were put into commercial production, people have been working hard to find a way to improve the ultraviolet response ability of the detector. In order to improve the sensitivity of the detector to ultraviolet radiation, a feasible way is to coat the device with a frequency conversion film that can convert ultraviolet light into visible light. There are many fluorescent substances, but substances that can convert UV and EUV light into visible light still need to meet certain conditions: First, their emission spectrum must...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/06H01L31/101H01L31/0216H01L31/0232
Inventor 陶春先何梁张大伟卢忠荣洪瑞金黄元申
Owner UNIV OF SHANGHAI FOR SCI & TECH
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