Eureka AIR delivers breakthrough ideas for toughest innovation challenges, trusted by R&D personnel around the world.

Preparation method of dialkylphosphinate metal salt

A technology of dialkylphosphinic acid and dialkylphosphinic acid, which is applied in the field of preparation of dialkylphosphinic acid metal salts, can solve the problems of difficult resin mixing, low tap density, poor fluidity, etc., and achieve simplification The effect of production equipment, small particle size and convenient operation

Inactive Publication Date: 2013-06-26
ZHUHAI WANTONG CHEM
View PDF10 Cites 18 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In order to overcome the problems of the existing dialkylphosphinic acid metal salt flame retardants such as low tap density, poor fluidity, easy to raise dust, and difficult to mix with resin, the purpose of the present invention is to provide a kind of flame retardant with small particle size and high density. The preparation method of dialkyl phosphinic acid metal salt with good fluidity and easy uniform distribution in resin

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of dialkylphosphinate metal salt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] To prepare aluminum diethylphosphinate, heat 1440g (3mol) 30% sodium diethylphosphinate solution to 95°C, add 0.01% mass fraction (based on the mass of sodium diethylphosphinate solution) Silane coupling agent KH560, add 333g of aluminum sulfate (M=666) solid within 25min to form a white solid, cool, filter, wash the precipitate with 6L of deionized water, and dry at 200°C for 16h. 383.4 g of aluminum diethylphosphinate was obtained, with a yield of 98.3% and a moisture content of 0.2%.

[0046] Tap density (g / L): 562; Particle size (μm) distribution: D(10): 18.672; D(50): 56.348; D(90): 77.549

[0047] IR: 779cm -1 , 1076 cm -1 , 1151 cm -1 , 2879 cm -1 , 2959 cm -1

Embodiment 2

[0049] Prepare aluminum diethylphosphinate as in Example 1, heat 822.9g (4mol) of 70% sodium diethylphosphinate solution to 150°C, in 4440g of 10% aluminum sulfate by mass (M=666) Add 0.5% mass fraction of silane coupling agent KH560 (based on the mass of aluminum sulfate solution) to the mixture of water and water, and add the aluminum sulfate solution to the sodium diethylphosphinate solution dropwise within 10 hours to form a white solid , cooled, filtered, washed the precipitate with 8L deionized water, and dried at 200°C for 16h. 507.5 g of aluminum diethylphosphinate was obtained, with a yield of 97.6% and a moisture content of 0.3%.

[0050] Tap density (g / L): 571; Particle size (μm) distribution: D(10): 12.248; D(50): 41.471; D(90): 63.825

Embodiment 3

[0052] Prepare aluminum diethylphosphinate with Example 1, heat 1728g (1.2mol) 10% sodium diethylphosphinate solution to 100°C, add 0.1% mass fraction (based on the amount of sodium diethylphosphinate solution The mass fraction of the silane coupling agent KH560, 0.05% mass fraction of the silane coupling agent KH560 (based on the mass percentage of aluminum sulfate solution of Benchmark), add the aluminum sulfate solution dropwise to the sodium diethylphosphinate solution within 1 hour to form a white solid, cool, filter, wash the precipitate with 2L of deionized water, and dry at 200°C for 16 hours. 151.0 g of aluminum diethylphosphinate was obtained, with a yield of 96.8% and a moisture content of 0.5%.

[0053] Tap density (g / L): 610; Particle size (μm) distribution: 13.219; D(50): 45.387; D(90): 70.516

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a dialkylphosphinate metal salt. The preparation method comprises the following steps: a) adding a coupling agent into a water solution of dialkyl phosphinic acid and / or a dialkylphosphinate alkali metal salt to get the water solution of dialkyl phosphinic acid and / or the dialkylphosphinate alkali metal salt containing the coupling agent; and b) adding the coupling agent or not adding the coupling agent into a mixture of a metal compound and water, and further reacting with the water solution of dialkyl phosphinic acid and / or the dialkylphosphinate alkali metal salt containing the coupling agent to generate the dialkylphosphinate metal salt. The dialkylphosphinate metal salt obtained by the preparation method disclosed by the invention has small particle size and good flowability; and furthermore, when the particle size is less than 90 mu m, in particular to 40 mu m, the tap density can still above 600g / L, and the problems that such flame retardants are easy to raise dust during the feeding process and less prone to uniformly mixing with resin can be well solved. The preparation method disclosed by the invention has the advantages of simple process and convenience in operation, and the coupling agent is low in price and easy to obtain; and simultaneously, production equipment is simplified and production cost is reduced.

Description

technical field [0001] The invention belongs to the technical field of flame retardant synthesis, and in particular relates to a method for preparing dialkylphosphinic acid metal salts with small particle size and high density. Background technique [0002] Polymer materials (plastics, rubber, synthetic fibers, etc.) are widely used in construction, automobiles, medical and health care, and household appliances because of their light weight, low price, and corrosion resistance. However, polymer materials are usually flammable or combustible, and the requirements for their flame retardancy are getting higher and higher in practical applications. In order to ensure the safety of synthetic materials and meet the requirements of environmental protection, the most effective method is to add halogen-free flame retardants to synthetic materials. [0003] Dialkyl phosphinates have been proven to be highly efficient halogen-free flame retardants and are widely used in synthetic mate...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C07F9/30C08K5/5313C08L67/02
Inventor 卢昌利柴生勇李积德孔蕾陈林
Owner ZHUHAI WANTONG CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com