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Polishing pad cleaning solution and use method thereof

A cleaning liquid and polishing pad technology, which is applied in the field of silicon wafer polishing pad cleaning, polishing pad cleaning liquid, and polishing pad cleaning liquid after silicon wafer circular polishing, which can solve the problems of clogging the pores of polishing pads, silicon wafer surface deformation, and dethickening rate Decrease and other problems to achieve the effect of reducing scratch rate, reducing surface tension and preventing redeposition

Inactive Publication Date: 2013-05-01
SHENZHEN LEAGUER MATERIAL +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, during the recycling process of the polishing liquid, it will cause the accumulation of polishing products and harmful ions in the polishing liquid, and these accumulations will be continuously deposited on the polishing pad
With continuous polishing cycles, residues that accumulate on the pad can clog the pores of the pad, resulting in a decrease in dethickness rate
In severe cases, lumps will form and cover the surface of the polishing pad, resulting in deformation of the silicon wafer surface after polishing, resulting in defects such as corrosion and scratches
In addition, the metal ions deposited on the surface of the polishing pad will be adsorbed on the surface of the silicon wafer, making subsequent cleaning difficult
Usually, the polishing pad is scrubbed with deionized water for 1 to 2 minutes after each polishing, which can slow down the accumulation of residues, but the effect is very limited

Method used

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  • Polishing pad cleaning solution and use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Preparation of cleaning solution: Add polyoxyethylene ether nonionic surfactant, cleaning aid, anti-caking agent, solubilizer, wetting agent and pH regulator to deionized water in sequence under constant stirring, and continue Stir until well combined. The content of each component is respectively: polyoxyethylene ether nonionic surfactant (JFC-E) 1wt%, cleaning aid (sodium tripolyphosphate) 3wt%, caking inhibitor (polyacrylic acid) 0.1wt%, increase Solvent (ethanol) 20wt%, wetting agent (tetraethylamine perfluorooctane sulfonate) 0.04wt%, pH regulator (ammonia) 0.1wt%; the pH of the cleaning solution is 8.0.

[0042] Cleaning method: scrub the polishing pad once with deionized water after using it for 30 minutes; scrub it once with the cleaning solution of the present invention after every 1 hour of using the polishing pad. Specifically: dilute the prepared cleaning solution by 20 times, use a common PVA brush on the polished non-woven polishing pad, scrub for 1 min a...

Embodiment 2

[0044] Preparation of cleaning solution: Add surfactant, cleaning aid, anti-caking agent, solubilizer, wetting agent and pH regulator to deionized water in sequence under continuous stirring, and continue stirring until uniform. The content of each component is: surfactant (Pingajia-O) 5wt%, cleaning aid (sodium hexametaphosphate) 0.5wt%, caking inhibitor (polyacrylamide) 5wt%, solubilizer (acetone ) 15wt%, wetting agent (perfluorooctane sulfonate ammonium) 0.1wt%, pH regulator (ammonium bicarbonate) 2wt%; the pH value of the cleaning solution is 8.7.

[0045] Cleaning method: the polishing pad is scrubbed with deionized water once every 30 minutes of use; the polishing pad is scrubbed with the cleaning solution of the present invention once every 2 hours of use. Specifically: dilute the prepared cleaning solution by 30 times, use an ordinary PVA brush to scrub the polished non-woven polishing pad for 2 minutes at a flow rate of 3L / min, and then use deionized water to wash the...

Embodiment 3

[0047] Preparation of cleaning solution: Add surfactant, cleaning aid, anti-caking agent, solubilizer, wetting agent and pH regulator to deionized water in sequence under continuous stirring, and continue stirring until uniform. The content of each component is respectively: surfactant (octylphenol polyoxyethylene ether) 10wt%, cleaning aid (sodium tetrapolyphosphate) 5wt%, caking inhibitor (sodium polyacrylate) 3wt%, solubilizer ( Isopropanol) 10wt%, wetting agent (perfluorooctane sulfonate amine) 0.01wt%, pH regulator (isopropanolamine) 5wt%; the pH value of the cleaning solution is 10.0.

[0048] Cleaning method: scrub the polishing pad with deionized water once every 30 minutes of use; scrub the polishing pad with the cleaning solution of the present invention once every 1.5 hours of use. Specifically: dilute the prepared cleaning solution by 40 times, use an ordinary PVA brush to scrub the polished non-woven polishing pad for 1.5 minutes at a flow rate of 3L / min, and then...

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PUM

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Abstract

The invention discloses a polishing pad cleaning solution and a use method thereof, and belongs to the field of silicon wafer polishing pad cleaning technology. The cleaning solution comprises a polyoxyethylene ether non-ionic surface active agent, a cleaning addition agent, a blocking prevention agent, a solubilizing agent, a wetting agent and a PH (potential of hydrogen) conditioning agent, and the pH value of the cleaning solution ranges from 8.0 to 10.0. In a circularly polishing process, after the polishing, the polishing pad cleaning solution is diluted for 20-40 times, and then a polishing pad is scrubbed with a flow rate of 5L / min (maximum flow) for 1 min. With the adoption of the cleaning solution and the cleaning method, residual fouling and ion residues accumulated on the polishing pad in the circularly polishing process can be effectively removed, so that the moisture retention of the polishing pad can be increased, and the service life of the polishing pad is prolonged. The cleaning solution can be recycled, the price and the cost are low, and the cleaning solution has the advantages of simple processing, controllability and the like when used in cleaning.

Description

technical field [0001] The invention relates to a polishing pad cleaning liquid and a method for using the same, belonging to the technical field of silicon wafer polishing pad cleaning, in particular to the technical field of a polishing pad cleaning liquid used for silicon wafer circular polishing. Background technique [0002] Semiconductor materials, mainly silicon materials, are the most important basic functional materials in the electronic information industry, and occupy a very important position in the national economy and military industry. More than 95% of the world's semiconductor devices are made of silicon materials, and 85% of integrated circuits are also made of silicon materials. Obtaining silicon wafers with higher surface processing precision is an important link in the manufacture of integrated circuits, which is directly related to the pass rate of integrated circuits. Using chemical mechanical polishing (CMP) technology to planarize the surface of semi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11D1/83C11D3/60C11D3/075C11D3/37C11D3/20C11D3/04C11D3/10C11D3/30B08B7/04B08B3/08
Inventor 陈高攀潘国顺顾忠华龚桦邹春莉
Owner SHENZHEN LEAGUER MATERIAL
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