Flexible circuit board and structure of bend section of flexible circuit board
A flexible circuit board, bending part technology, applied in the directions of printed circuit components, printed circuits, printed circuits, etc., can solve the problems of flexible circuit board design constraints, and achieve the effects of high durability, excellent durability, and excellent flexibility
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[0082] Hereinafter, the present invention will be described more specifically based on Examples and Comparative Examples. In addition, the kind of copper foil used in Examples etc. and the synthesis|combination of a polyimide-acid solution are as follows.
[0083] [copper foil A]
[0084] Commercially available rolled copper foil with a purity of 99.9% and a thickness of 9 μm.
[0085] [copper foil B]
[0086] Commercially available electrolytic copper foil with a purity of 99.9% and a thickness of 9 μm.
[0087] [copper foil C]
[0088] Oxygen-free copper foil, purity 99.99%, thickness 9μm, processing condition A.
[0089] Impurities (mass ppm) Oxygen: 2, Silver: 18, Phosphorus: 2.1, Sulfur: 4, Iron: 1.5
[0090] [copper foil D]
[0091] Refined copper foil, purity 99.999%, thickness 9μm, processing condition A.
[0092] Impurities (mass ppm) Oxygen: 2, Silver: 5, Phosphorus: 0.01, Sulfur: 0.01, Iron: 0.002
[0093] [copper foil E]
[0094] Refined copper foil, purit...
Synthetic example 1)
[0108] N,N-Dimethylacetamide was charged into a reaction vessel capable of introducing nitrogen gas while being equipped with a thermocouple and a stirrer. In this reaction container, 2,2-bis[(4-(4 aminophenoxy)phenyl)]propane (BAPP) was dissolved in the container while stirring. Next, add pyromellitic anhydride (PMDA). The total amount of monomers charged was 15% by weight. Afterwards, the stirring was continued for 3 hours to obtain a resin solution of polyimide acid a. The solution viscosity of the resin solution of this polyimide-acid a was 3,000 cps.
Synthetic example 2)
[0110] N,N-Dimethylacetamide was charged into a reaction vessel capable of introducing nitrogen gas while being equipped with a thermocouple and a stirrer. 2,2'-Dimethyl-4,4'-diaminobiphenyl (m-TB) was put into this reaction container. Next, add 3,3’,4,4’-biphenyltetraic anhydride (BPDA) and pyromellitic anhydride (PMDA). The total amount of monomers charged was 15 wt%, and the molar (mol) ratio (BPDA:PMDA) of each acid anhydride was charged so that it was 20:80. Thereafter, stirring was continued for 3 hours to obtain a resin solution of polyimide b. The solution viscosity of the resin solution of this polyimide-acid b was 20,000 cps.
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