Positive electrode current collector for lithium ion secondary battery, positive electrode for lithium ion secondary battery, and process for production of positive electrode current collector for lithium ion secondary battery
A technology for positive electrode current collectors and secondary batteries, applied in secondary batteries, electrode carriers/current collectors, battery electrodes, etc., can solve the problems of reduced battery life, poor adhesion, peeling, etc., and achieve improved battery life, easy and The effect of reliable production and improvement of adhesion
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no. 1 example
[0088] Next, the positive electrode that satisfies the requirements of the present invention and the positive electrode that does not meet the requirements of the present invention will be shown to compare the adhesion of the current collector and the positive electrode active material layer at the interface. First, the positive electrode used in this embodiment will be described along the manufacturing process. In addition, the comparative example 4 of this example is assumed to be a positive electrode in which an intermediate film of carbon is formed on a current collector made of a conductive material described in Patent Document 1.
[0089] (1) Aluminum foil manufacturing process
[0090] In the aluminum foil manufacturing process, the same treatment was performed in Examples 1 to 12 and Comparative Examples 1 to 10. That is, the aluminum plate was rolled to produce an aluminum foil having a length of 50 mm × a width of 50 mm × a thickness of 15 μm.
[0091] (2) Surface layer f...
no. 2 example
[0108] Next, in order to investigate more preferable forms of the current collector and the positive electrode of the present invention, an example for comparing the wettability of the surface of the current collector is shown. In addition, this characteristic is only a desirable characteristic of the present invention. Therefore, even if this characteristic is not satisfied and the adhesion of the first embodiment is satisfied, the minimum objective of the invention can be achieved. In this example, using Examples 1 to 12 and Comparative Examples 1 to 3, and 5 to 8 manufactured by the same manufacturing process as the aforementioned first example, the following measurement and evaluation were performed.
[0109] (1) Measurement of the composition of the surface layer
[0110] After the aforementioned surface layer formation process, the composition of the surface layer was measured by AES.
[0111] (2) Measurement and evaluation of water contact angle
[0112] After the aforemention...
no. 3 example
[0120] Next, in order to investigate more preferable forms of the current collector and the positive electrode of the present invention, an example with comparative corrosion resistance is shown. In addition, this characteristic is merely a desired characteristic of the present invention. Therefore, even if this characteristic is not satisfied and the adhesion of the first embodiment is satisfied, the minimum objective of the present invention can still be achieved. In this example, using Examples 3 to 5, 8, 9, and 13 and Comparative Examples 8 to 10 manufactured by the same manufacturing process as the aforementioned first example, the following treatment was performed.
[0121] (1) Measurement of the composition of the surface layer
[0122] After the aforementioned surface layer formation process, the composition of the surface layer was measured by AES.
[0123] (2) Evaluation of corrosion resistance
[0124] Using the positive electrode produced by the method described above, a ...
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