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Preparation method for ocean engineering reinforced concrete silane emulsion protective agent

A technology of reinforced concrete and silane emulsion, which is applied in the anticorrosion field of marine engineering materials, can solve the problems of direct emulsification without silane monomer and difficult emulsification, and achieve the effects of shortening the complete curing time, small molecular weight, and low volatilization rate

Active Publication Date: 2012-07-04
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] However, silane monomer is difficult to emulsify directly due to its strong hydrophobicity, volatility, and the characteristics of easy hydrolysis under acid, alkali catalyst and high shear force.
At present, there are no reports on the direct emulsification of silane monomers at home and abroad

Method used

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  • Preparation method for ocean engineering reinforced concrete silane emulsion protective agent
  • Preparation method for ocean engineering reinforced concrete silane emulsion protective agent
  • Preparation method for ocean engineering reinforced concrete silane emulsion protective agent

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Embodiment Construction

[0025] The preparation method of the marine engineering reinforced concrete silane emulsion protective agent in the present invention comprises the following steps: stirring and dissolving the emulsifier in advance with 40 to 80 parts by mass of deionized water in the reactor, and slowly Add 20 to 60 parts by mass of silane monomer, and then emulsify at 30 to 60°C for 6 to 12 hours under stirring at 400 to 1200 rpm to obtain a uniform and stable micro-nano emulsion, which is the product; the silane monomer It is a silane monomer with at least three ethoxy groups; the emulsifier includes at least two non-ionic emulsifiers, and the total addition amount is 2-10% of the silane monomer. Among the emulsifiers, any nonionic emulsifier is used as the main emulsifier, and other nonionic emulsifiers are used as auxiliary emulsifiers, and the mass ratio of the main emulsifier to the auxiliary emulsifier is 2:1 to 6:1 .

[0026] The test data in each embodiment sees the following table:...

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Abstract

The invention relates to the field of corrosion protection of ocean engineering materials, and aims to provide a preparation method for an ocean engineering reinforced concrete silane emulsion protective agent. The method comprises the following steps of: previously stirring and dissolving an emulsifier in a reaction kettle by using 40-80 parts by mass of de-ionized water; slowly adding 20-60 parts by mass of silane monomer under high shear force; and then emulsifying at 30-60 DEG C under low-speed stirring for 6-12 hours to obtain uniform stable micro-nano emulsion, namely a product. By using the method, 90 percent of surface water absorption can be reduced, the effect of obstructing erosion of concrete reinforcement by a marine corrosion medium can be achieved, an internal vapor discharge passage is also kept, and internal atmospheric pressure produced to a film layer is reduced. Compared with a pure silane monomer impregnant, the volatilization rate is low, the utilization rate of silane is increased, the infiltration distance is increased, and the full curing time is greatly shortened. Compared with the conventional polysiloxane emulsion, the process is simple, the molecular weight of a filming substance is smaller, the infiltration capacity is stronger, and the filming capacity is higher.

Description

technical field [0001] The invention relates to a preparation method of a silane emulsion protective agent for marine engineering reinforced concrete, belonging to the field of marine engineering material anticorrosion. Background technique [0002] With the construction of the coastal economic belt represented by the blue economic zone, during the "Twelfth Five-Year Plan" period, my country will build a large number of infrastructure, ships and marine engineering equipment in the fields of marine resource development, marine transportation, etc., thus giving birth to the The huge market demand of the marine anti-corrosion industry. [0003] Due to the natural characteristics of strong radiation, high salinity, high humidity, and typhoons in the marine environment, concrete structures will crack and expand, metal materials will be corroded and damaged, and polymer materials will be deformed and deteriorated, so that the service life of traditional engineering materials is onl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/50
Inventor 杨辉徐强詹树林樊先平申乾宏王敏嘉
Owner ZHEJIANG UNIV
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