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A Method for Capturing Carbon Dioxide in Flue Gas Using Renewable Carbide Slag

A technology of carbon dioxide and carbide slag, which is applied in chemical instruments and methods, separation methods, air quality improvement, etc., can solve the problems of low effective utilization rate of carbide slag, burial and stacking, and low environmental benefits, and achieve good pore structure and heat dissipation. Effects of stability, improvement of absorption efficiency, and high specific surface area

Inactive Publication Date: 2016-04-06
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, method (1) is mainly adopted for the treatment and disposal of calcium carbide slag. This treatment method will occupy a large amount of land, pollute shallow groundwater and cause soil salinization. Therefore, this method cannot effectively utilize calcium carbide slag, an industrial waste. and governance
The resource utilization of carbide slag mainly includes: (1) Chinese invention patent No. ZL200810116928.0 introduces the wet flue gas desulfurization process using carbide slag as absorbent, (2) Chinese invention patent No. 200810146495.3 introduces A kind of utilization calcium carbide slag to prepare high-purity CaCO 3 However, the effective utilization rate of calcium carbide slag is still very low, and most of them are still buried and piled up, which brings pollution to the environment
[0006] Therefore, with the increasing trend of global warming caused by the greenhouse gases emitted by human beings, the international community has paid more attention to the issue of greenhouse gas emission reduction in recent years, and extensive research on carbon dioxide capture technology has been carried out. 2 In the method, the environmental benefit is low, the attenuation coefficient of the absorbent is large, and the calcium carbide slag as industrial waste pollutes the environment and cannot be effectively used. The present invention uses calcium carbide slag as the calcium-based Absorbent circulation captures CO in flue gas 2

Method used

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  • A Method for Capturing Carbon Dioxide in Flue Gas Using Renewable Carbide Slag
  • A Method for Capturing Carbon Dioxide in Flue Gas Using Renewable Carbide Slag

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Comparison of calcium carbide slag collected in a coal chemical plant with commercially available Ca(OH) using a fixed bed reactor 2 CO under low temperature calcination conditions 2 Absorptive properties. Carbide slag particle size: 160-180 mesh; calcination reaction temperature: 840℃; calcination time 10min; carbonization reaction temperature: 700℃; carbonization time: 20min; a total of 40 cycles of CO capture were investigated 2 (Note: the conversion of CaO in the absorbent is used to characterize CO 2 absorption efficiency). The results show that: (1) At the end of 40 cycles, the carbide slag and Ca(OH) 2 CO 2 The absorption efficiencies were 35.18% and 32.57%, respectively; (2) During the 40-cycle capture process, the calcium carbide slag and Ca(OH) 2 CO 2 The absorption efficiency attenuation coefficients are 0.16426 and 0.21140 respectively (the larger the attenuation coefficient is, the faster the attenuation speed is), thus indicating that: in ensuring th...

Embodiment 2

[0032] A fixed bed reactor was used to compare the CO concentration of carbide slag collected from a coal chemical plant and commercial limestone under low temperature calcination conditions 2 Absorptive properties. Carbide slag particle size: 160-180 mesh; calcination reaction temperature: 840℃; calcination time 10min; carbonization reaction temperature: 700℃; carbonization time: 20min; a total of 40 cycles of CO capture were investigated 2 absorption efficiency. The results show that: (1) At the end of 40 cycles, the CO of carbide slag and limestone 2 The absorption efficiencies were 35.18% and 26.22%, respectively; (2) During 40 cycles, the average CO of carbide slag and limestone 2 The absorption efficiencies were 41.01% and 38.14%, respectively; (3) CO of carbide slag and limestone 2 The absorption efficiency attenuation coefficients are 0.16426 and 0.28030, respectively, thus indicating that: in the guaranteed CO 2 Under the premise of absorption efficiency, carbide ...

Embodiment 3

[0034] A fixed bed reactor was used to compare the CO concentration of carbide slag collected from a coal chemical plant and commercial limestone at higher calcination temperatures 2 Absorptive properties. Carbide slag particle size: 160-180 mesh; calcination reaction temperature: 940℃; calcination time 10min; carbonization reaction temperature: 700℃; carbonization time: 20min; a total of 20 cycles of CO capture were investigated 2 absorption efficiency. The results show that: (1) the CO concentration of carbide slag and limestone at the end of 20 cycles 2 The absorption efficiencies were 28.30% and 22.53%, respectively; (2) During the 20-cycle capture process, the CO of carbide slag and limestone 2 The attenuation coefficients of absorption efficiency are 0.23958 and 0.39961, respectively, thus indicating that: for high temperature calcination conditions, carbide slag is effective against CO 2 The attenuation of absorption efficiency is also less than that of commercial li...

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Abstract

The invention relates to the application field of carbide slag, and in particular relates to a method for trapping carbon dioxide from smoke by renewable carbide slag. According to the invention, the method for trapping carbon dioxide from smoke by renewable carbide slag comprises the following steps: 1) calcining the carbide slag to obtain an absorbent with an effective constituent of calcium oxide; 2) adding the absorbent of step 1) to a carbonization reactor to absorb carbon dioxide from the smoke to obtain calcium carbonate and clean smoke; 3) calcining the calcium carbonate of step 2) to regenerate the absorbent; 4) eliminating the inactive constituents from the regenerated absorbent of step 3), adding new carbide slag, returning to step 2) for recycling, and repeating steps 2) to 4). The invention has the advantage of following the environment protection concept of treating wastes by wastes, so as to lower the discharge of carbon dioxide from the smoke, and has favorable application prospects.

Description

technical field [0001] The invention relates to the application field of carbide slag, in particular to a method for capturing carbon dioxide in flue gas by using renewable carbide slag. Background technique [0002] The trend of global warming caused by greenhouse gases has become an environmental issue that the international community is generally concerned about. 2 It is the most important type of greenhouse gas, and its greenhouse effect accounts for about 77% of all greenhouse gases, thus controlling CO 2 Emissions are essential for controlling the greenhouse effect and slowing down the trend of climate change. China is the most populous country in the world, and its energy consumption structure is dominated by coal. Therefore, the country is used as the statistical unit to calculate the total amount. At present, China is the world's largest emitter of greenhouse gases. As a developing country, with the acceleration of the modernization process, China's greenhouse gas...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/81B01D53/50B01D53/62B09B3/00
CPCY02A50/20Y02W30/20
Inventor 李松庚林伟刚宋文立姚建中张登峰
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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