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A kind of slightly water-soluble fertilizer and preparation method thereof

A slightly water-soluble fertilizer technology, applied in fertilizer mixtures, fertilization devices, applications, etc., can solve the problems of difficult degradation of coating materials, secondary pollution costs, etc.

Active Publication Date: 2011-12-07
BEIJING ACADEMY OF AGRICULTURE & FORESTRY SCIENCES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] There are two main problems in the current slow and controlled release fertilizer products: (1) Coated fertilizer is the main product of slow and controlled release fertilizer at present, and its disadvantage is that the coating material is difficult to degrade, and it is easy to cause secondary pollution and high cost , the reason is that refractory substances are used as the coating material, and the coated fertilizer is developed by using energy-intensive equipment; (2) the coated fertilizer mainly uses thermoplastic (solid) material as the coating material, and the fertilizer product is Nutrient release is mainly affected by accumulated temperature when the soil field water holding capacity is greater than 40%, and nutrients can be effectively supplied to crops with the change of accumulated temperature; however, when the soil field water holding capacity is less than 40%, nutrient release is inhibited and it is difficult to effectively supply crop demand
However, in relatively arid and semi-arid rain-fed agricultural areas, because the field water holding capacity of the soil is often lower than 40%, it is difficult for the current slow-release fertilizers to release a certain amount of nutrients in time with the rainfall and migrate to the effective absorption range of the crops with the water. Therefore, At present, there is an urgent need to develop a slightly water-soluble fertilizer that can release certain nutrients instantaneously with rainfall or irrigation and has certain slow-release properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1, the preparation of slightly water-soluble fertilizer

[0024] (1) Preparation of slightly water-soluble materials

[0025] Add 0.28g polyglutamic acid PGA to water and stir until dissolved to obtain a completely dissolved aqueous solution, add 47.5g glucose to the aqueous solution, heat to 55°C and keep warm for 85min; then add 0.4g sulfuric acid (concentration: 98 %), 16.5g glucose and 3.8g acrylic acid mixed monomer, heat the system to 80°C and keep it warm for 140min; then add 3.5g sodium hydroxide to the system to adjust the pH value of the system to 9, add 5g acrylic acid to cool the system to 60°C and keep it warm for 85 minutes; then use 1.9g of potassium hydroxide to adjust the system to neutral, then add 1.5g of calcium stearate and stir for 28 minutes to obtain a film-forming solution; then cast the resulting film-forming solution into a film A slightly water-soluble material is obtained; the thickness of the material is 0.05-0.1mm, and the wate...

Embodiment 2

[0028] Embodiment 2, the preparation of slightly water-soluble fertilizer

[0029] (1) Preparation of slightly water-soluble materials

[0030] Add 0.42g polyvinyl alcohol PVA to water and stir until dissolved to obtain a fully dissolved polyol aqueous solution; add 51.2g starch to the aqueous solution, heat to 65°C and keep it warm for 55min; then add 1.3g hydrochloric acid (concentration: 38 %), 16.5g starch and 5.8g methyl methacrylate, heat the system to 95°C and keep it warm for 60min; then add 4.2g potassium hydroxide to the system to adjust the pH value of the system to 8.9, add 4.3g ethyl acrylate , lower the temperature of the system to 80°C and keep it warm for 45min; then adjust the system to neutral with 1.33g of potassium hydroxide, then add 2.0g of potassium stearate and stir for 30min to obtain a film-forming solution; then cast the obtained film-forming solution The slightly water-soluble material can be obtained by forming a film. The thickness of the materi...

Embodiment 3

[0033] Embodiment 3, the preparation of slightly water-soluble fertilizer

[0034] (1) Preparation of slightly water-soluble materials

[0035] Add 0.7g polyethylene glycol PEG to water and stir until dissolved to obtain a completely dissolved aqueous solution; add 46.6g starch to the aqueous solution, heat to 70°C and keep warm for 55min; then add 2.2g hydrochloric acid (concentration is 38.4% ), 21.1g of starch and 4.7g of ethyl methacrylate, heating the system to 90°C and keeping it warm for 60 minutes; then adding 4.8g of potassium hydroxide to the system to adjust the pH of the system to 8.1, adding 4.0g of butyl acrylate, Cool the system down to 65°C and keep it warm for 85 minutes; then use 0.7g of potassium hydroxide to adjust the system to neutral, then add 1.1g of calcium hardate and stir for 28 minutes to obtain a film-forming solution; then use the drying method to prepare the obtained film-forming solution The slightly water-soluble material can be obtained by fi...

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Abstract

The invention discloses a slightly water-soluble fertilizer and a preparation method thereof. The method comprises the following the steps of: (1) adding a crosslinking agent into an aqueous solution of a polymer a for reacting, wherein the polymer a is polyglutamic acid, polyvinyl alcohol, polyethylene glycol or polyvinylpyrrolidone; (2) adding an acidifying agent, a crosslinking agent and a mixed monomer into the system in the step (1) for reacting continually; (3) adding an alkalizer and a crosslinking agent into the system in the step (2) for reacting continually, adjusting the pH value to neutral, adding a plasticizer and stirring to obtain a film forming solution, and preparing the film forming solution into a film to obtain a slightly water-soluble material; and (4) granulating thefertilizer and the slightly water-soluble material, and packing with the slightly water-soluble material to obtain the slightly water-soluble fertilizer.

Description

technical field [0001] The invention relates to a slightly water-soluble fertilizer and a preparation method thereof, belonging to the field of interdisciplinary research on water-soluble and wrapped fertilizers. Background technique [0002] There are two main problems in the current slow and controlled release fertilizer products: (1) Coated fertilizer is the main product of slow and controlled release fertilizer at present, and its disadvantage is that the coating material is difficult to degrade, and it is easy to cause secondary pollution and high cost , the reason is that refractory substances are used as the coating material, and the coated fertilizer is developed by using energy-intensive equipment; (2) the coated fertilizer mainly uses thermoplastic (solid) material as the coating material, and the fertilizer product is Nutrient release is mainly affected by accumulated temperature when the soil field water holding capacity is greater than 40%, and nutrients can be ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
Inventor 肖强刘宝存曹兵徐秋明衣文平杨俊刚倪小会邹国元杨宜斌李鸿雁
Owner BEIJING ACADEMY OF AGRICULTURE & FORESTRY SCIENCES
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