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Deacidifying method for paper cultural relics

A technology of paper cultural relics and deacidification method, which is applied in the post-treatment of waste paper, etc., can solve the problems of books and newspapers that are difficult to preserve for a long time, accelerate paper acidification, air pollution, etc., achieve large-scale rapid deacidification treatment and avoid damage , Deacidification uniform effect

Inactive Publication Date: 2011-11-16
ZHEJIANG UNIV
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the 19th century, people have generally found that books and newspapers written and printed on mechanical paper are difficult to preserve for a long time.
The reason is that the aluminum sulfate retained in the manufacturing process of mechanical paper becomes acidic after being hydrolyzed, which causes the paper to acidify and "self-destruct". In addition, the development of modern economy has caused increasing air pollution, which has also accelerated the acidification of paper.
[0003] In order to protect the integrity of cultural resources and rescue acidified paper documents, various deacidification methods have been studied, but none of them are ideal: the aqueous solution method is easy to cause paper wrinkles, adhesion, and discoloration, and it is difficult to quantify; the organic solvent method is flammable, Toxic and other safety hazards; gas phase method must have vacuum coordination, long processing cycle and expensive equipment

Method used

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  • Deacidifying method for paper cultural relics
  • Deacidifying method for paper cultural relics

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 1) Spread the acidified paper cultural relics flat on the flat plate;

[0021] 2) Inject ammonia and Ca(OH) into the bubbler 2 , OH- and Ca 2+ The molar ratio of helium and nitrogen is 1:0.006, and a mixed gas of helium and nitrogen with a purity of 99.99% is passed into the bubbler, and the flow ratio of helium and nitrogen is He:N 2 =2:5, the total flow is 0.15 m 3 / h, the ion source reagent is transported to the plasma spray gun and ejected from the nozzle;

[0022] 3) Turn on the plasma excitation pulse power supply, adjust the voltage to 5kV, and the frequency to 2.0kHz to form a stable OH- and Ca 2+ The ion flame; start the spray gun scanning device, the high-energy OH- ions and Ca 2+ The ion jet is sprayed onto the surface of the flattened paper relics for deacidification for 1 minute.

[0023] The pH value of the deacidified paper was tested according to the standard procedure to quantify the deacidification effect. At the same time, the tensile index, soft...

Embodiment 2

[0026] 1) Spread the acidified paper cultural relics flat on the flat plate;

[0027] 2) Inject Ca(OH) into the bubbler 2 and KOH, OH- and Ca 2+ The molar ratio of helium and nitrogen is 1:0.002, and a mixed gas of helium and nitrogen with a purity of 99.99% is passed into the bubbler, and the flow ratio of helium and nitrogen is He:N 2 =5:5, the total flow is 0.10 m 3 / h, the ion source reagent is transported to the plasma spray gun and ejected from the nozzle;

[0028] 3) Turn on the plasma excitation pulse power supply, adjust the voltage to 10kV, and the frequency to 1.2kHz to form a stable OH- and Ca 2+ The ion flame; start the spray gun scanning device, the high-energy OH- ions and Ca 2+ The ion jet is sprayed onto the surface of the flattened paper relics for deacidification for 3 minutes.

[0029] The pH value of the deacidified paper was tested according to the standard procedure to quantify the deacidification effect. At the same time, the tensile index, softnes...

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PUM

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Abstract

The invention discloses a de-acidifying method for paper cultural relics, which comprises the following steps of: 1) flatly spreading acidified paper cultural relics on a flat board; 2) injecting an ion source reagent including OH- and Ca<2+> into a bubbler, and importing a mixed gas of helium gas and nitrogen to serve as a carrier gas, and transmitting the ion source reagent to a plasma spray gun; 3) turning on a plasma excitation pulse power source, forming ion flames containing OH- and Ca<2+> at the muzzle of the plasma spray gun; and spraying the ion flames to scan the surface of the flattened paper cultural relics to perform deacidifying processing. In the method disclosed by the invention, a plasma discharging form is adopted under normal temperature and normal pressure work conditions, thereby complex and expensive vacuum equipment are avoided being used, and damages of an aqueous solution infusion method to a paper body are avoided; and the method disclosed by the invention can be used for realizing rapid large-area deacidifying processing and has the advantages of uniformity for de-acidification, stable process, and suitability for industrialized large-scale production.

Description

technical field [0001] The invention relates to a normal temperature and pressure plasma deacidification method suitable for paper cultural relics. Background technique [0002] Most of the huge amount of ancient books and documents left over from past dynasties in our country are written and printed on handmade paper or mechanical paper. They are the precious cultural heritage of the Chinese nation and have important historical and cultural value that cannot be copied. Paper plays an important role as a carrier for recording history and transmitting and continuing the essence of culture. However, since the 19th century, people have generally found that books and newspapers written and printed on mechanical paper are difficult to preserve for a long time. The reason is that the aluminum sulfate retained in the manufacturing process of mechanical paper becomes acidic after being hydrolyzed, which causes the paper to acidify and "self-destruct". In addition, the development o...

Claims

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Application Information

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IPC IPC(8): D21H25/18
Inventor 张溪文
Owner ZHEJIANG UNIV
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