Terpene isopropyl carbonate gasoline antiknock
A technology of isopropyl carbonate and gasoline antiknock agent, applied in the preparation of carbon dioxide or inorganic carbonate, reagents, petroleum industry, etc., can solve the problems of limiting the production and application of MTBE, and achieve the effect of improving the explosion-proof effect
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Embodiment 1
[0015] Add 70 g of α-pinene, 30 g of isopropanol, and 0.1 g of tetraethylammonium bromide catalyst into a 500 mL autoclave, stir and heat up to 120°C. Add carbon dioxide from the guide pipe to make the pressure of the reactor reach 4MPa, and start stirring. During the reaction process, the carbon dioxide pressure was controlled between 4MPa±0.02MPa, and the reaction time was 6 hours. Then reduce the temperature of the reactor to 40°C, and vent excess carbon dioxide through the guide tube. The material was discharged from the bottom of the reaction kettle to obtain light yellow transparent liquid A-terpene isopropyl carbonate.
Embodiment 2
[0017] Add 84 g of α-pinene, 30 g of isopropanol, and 0.2 g of tetraethylammonium bromide catalyst into a 500 mL autoclave, and stir to raise the temperature to 80°C. Add carbon dioxide from the guide tube to make the pressure of the reactor reach 6MPa, and start stirring. During the reaction process, the carbon dioxide pressure was controlled between 6MPa±0.02MPa, and the reaction time was 6 hours. Then reduce the temperature of the reactor to 40°C, and vent excess carbon dioxide through the guide tube. The material was released from the bottom of the reaction kettle to obtain light yellow transparent liquid B-terpene isopropyl carbonate.
Embodiment 3
[0019] Add 70 g of α-pinene, 30 g of isopropanol, and 0.5 g of tetraethylammonium bromide catalyst into a 500 mL autoclave, stir and heat up to 60°C. Add carbon dioxide from the guide pipe to make the pressure of the reactor reach 8MPa, and start stirring. During the reaction process, the carbon dioxide pressure was controlled between 8MPa±0.02MPa, and the reaction time was 6 hours. Then reduce the temperature of the reactor to 40°C, and vent excess carbon dioxide through the guide tube. The material was released from the bottom of the reaction kettle to obtain light yellow transparent liquid C-terpene isopropyl carbonate.
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