Antistatic flame-resistant environmentally stable peelable protective film and preparation method thereof
A protective film and antistatic technology, applied in the direction of conductive adhesives, film/sheet adhesives, adhesive types, etc., can solve the problems of reducing the protective effect of the film, cracking and loss of the protective film, and achieve good Environmental stability, good antistatic, meet the effect of antistatic
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Embodiment 1
[0040] Dissolve 20kg of dibasic vinyl chloride resin (Korean Hanwha CP-430, degree of polymerization 450, vinyl acetate content 15%, glass transition temperature 63°C) in 80kg of butane with a volume ratio of 1:1 at 70°C. In the mixed solvent of ketone and ethyl acetate, polymer solution A is obtained;
[0041] 20kg polyether polyurethane (Basf, Germany, Elastollan TPU 1180A10, density 1.11g / cm 3 , hardness (Shore A, ASTM 2240) 80, glass transition temperature -43°C), stirred and dissolved in 80 kg N,N-dimethylformamide (DMF) at 70°C to obtain polymer solution B;
[0042] With 1kg graphene, 0.5kg compatible modifier (ternary chlorinated resin L-311, sunshine chemical industry, molecular weight 27000, vinyl acetate weight content 13-16%, maleic acid weight content 1.7-2.1%, vitrification temperature 76°C), 0.5kg acetyl tri-n-butyl citrate was ground by a slurry mill or ultrasonically assisted and dispersed in 100 kg methyl ethyl ketone / ethyl acetate (volume ratio = 1:1), and a...
Embodiment 2
[0047] Take 50 milliliters of polymer solution A and 20 milliliters of polymer solution B in a 100 milliliter beaker for mechanical stirring and mixing, take an appropriate amount of the mixed solution and apply it to glass substrates, stainless steel substrates, paint-protected metal substrates, Baking varnish on wooden substrates and cement substrates, drying naturally to form a film.
Embodiment 3
[0049] The preparation procedure of the peelable protective film is the same as in Example 2, and 10 milliliters of polymer solution B is mixed with 50 milliliters of polymer solution A.
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