Lead and carbon composite material-containing lead-carbon super storage battery and preparation method thereof
A technology of super battery and composite material, applied in the field of lead-carbon super battery and its preparation, can solve the problems of reducing battery life, lead plaster falling off, etc., and achieve the effects of improving low temperature performance, prolonging cycle life and reducing material cost
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Embodiment 1
[0032] 60wt% lead powder, 35wt% lead-carbon composite material with a lead content of 35wt%, 0.05wt% polyester fiber with a length of 8mm and a diameter of 12μm, 0.1wt% carbon black, 0.15wt% sodium lignosulfonate, The storage battery was uniformly dry mixed with humic acid 0.8 wt%, 0.4 wt% barium sulfate, then added 10% deionized water of the total weight of the above solid raw materials for wet mixing, and then added 7% of the total weight of the above solid raw materials with a density of 1.3g / cm 3 sulfuric acid solution; mixed for 1.5 hours, the temperature of the paste was controlled to be 50-60°C during the paste process, and when the temperature dropped to 45°C, the material was discharged to obtain the negative lead paste for lead-carbon super batteries, and then the negative lead paste was coated on both sides Covered on the 2.5mm thick grid-shaped lead alloy grid, cured at 40-70°C and relative humidity of 90-99% for 24-72 hours, and then at 50-80°C and relative humid...
Embodiment 2
[0036]75wt% lead powder, 20wt% lead-carbon composite material containing 55wt% lead, 0.07wt% polyester fiber with a length of 8mm and a diameter of 12μm, 0.23wt% carbon black, 0.9wt% sodium lignosulfonate, 1.0 wt% of the storage battery was uniformly dry mixed with humic acid and 2.8 wt% barium sulfate, then added 13% of the total weight of the above solid raw materials for wet mixing, and then added 11% of the total weight of the above solid raw materials to a density of 1.3g / cm 3 sulfuric acid solution; mixed for 2 hours, the temperature of the paste during the control and paste process was 50~60°C, and when the temperature dropped to 45°C, the material was discharged to obtain the negative lead paste for lead-carbon super batteries, and then the negative lead paste was coated on both sides Covered on the 2.5mm thick grid-shaped lead alloy grid, cured at 40-70°C and relative humidity of 90-99% for 24-72 hours, and then at 50-80°C and relative humidity of 20-40 % under the ...
Embodiment 3
[0040] 1wt% lead powder, 95wt% lead-carbon composite material with a lead content of 45wt%, 0.06wt% polyester fiber with a length of 8mm and a diameter of 12μm, 0.8wt% carbon black, 1.14wt% sodium lignosulfonate, 1.7 wt% storage battery was uniformly dry mixed with humic acid and 0.3wt% barium sulfate, then added 11% deionized water of the total weight of the above solid raw materials for wet mixing, and then added 9% of the total weight of the above solid raw materials with a density of 1.35g / cm 3 sulfuric acid solution; mixed for 1 hour, the temperature of the paste during the control and paste process is 50~60°C, and when the temperature drops to 45°C, the material is discharged to obtain the negative lead paste for lead-carbon super battery, and then the negative lead paste is coated on both sides Covered on the 2.5mm thick grid-shaped lead alloy grid, cured at 40-70°C and relative humidity of 90-99% for 24-72 hours, and then at 50-80°C and relative humidity of 20-40 % u...
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