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Long glass fibre reinforced polypropylene material and preparation method thereof

A technology of long glass fiber and polypropylene material, which is applied in the field of long glass fiber reinforced polypropylene material and its preparation, can solve the problem that the fluidity of polypropylene affects the impregnation effect, the stability of polypropylene fluidity is poor, and the thermal stability of the material is reduced. and other problems, to achieve the effect of improving product performance and quality stability, improving impregnation effect, and improving lubricating effect.

Inactive Publication Date: 2011-04-13
NANJING JULONG SCI&TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the flow modifier is PP cooling masterbatch, the main component is peroxide, and the free radical termination reaction between peroxide and antioxidant in the system will cause a large amount of peroxide to be consumed by the reaction of antioxidant, which is not only for The improvement of polypropylene fluidity is limited, which affects the impregnation effect, and the stability of polypropylene fluidity improvement is also very poor, and product quality control is very difficult; at the same time, due to free radical termination reactions between peroxides and antioxidants in the system, Peroxide will consume a large amount of antioxidants, and the thermal stability of the material will be greatly reduced, resulting in a greatly shortened service life of the material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A long glass fiber reinforced polypropylene material is composed of the following components: 37.5wt% polypropylene, 60wt% long glass fiber, 2wt% compatibilizer, and 0.5wt% antioxidant. Polypropylene is high melting point polypropylene with a melt index of 65g / 10min. High melting point polypropylene is one or a mixture of high melting point homopolypropylene and copolymerized polypropylene. The compatibilizer is maleic anhydride grafted polypropylene, and the maleic anhydride grafting ratio is 0.9. Long glass fibers are long glass fibers treated with a coupling agent.

[0021] The long glass fiber is LFT continuous roving, the fiber type is E glass, and the fiber monofilament diameter is 2400Tex 17μm.

[0022] The preparation method of long glass fiber reinforced polypropylene material comprises the following steps:

[0023] Step 1: Add polypropylene, compatibilizer and antioxidant to the mixer to make them fully mixed evenly;

[0024] The second step: Add the mixtur...

Embodiment 2

[0028] A long glass fiber reinforced polypropylene material is composed of the following components: 64wt% polypropylene, 30wt% long glass fiber, 5wt% compatibilizer, and 1.0wt% antioxidant. Polypropylene is high melting point polypropylene with a melt index of 50g / 10min. High melting point polypropylene is one or a mixture of high melting point homopolypropylene and copolymerized polypropylene. The compatibilizer is maleic anhydride grafted polypropylene, and the maleic anhydride grafting ratio is 1.2. Long glass fibers are long glass fibers treated with a coupling agent.

[0029] The long glass fiber is LFT continuous roving, the fiber type is E glass, and the fiber monofilament diameter is 2400Tex 17μm.

[0030] The preparation method of long glass fiber reinforced polypropylene material comprises the following steps:

[0031] Step 1: Add polypropylene, compatibilizer and antioxidant to the mixer to make them fully mixed evenly;

[0032] The second step: Add the mixture ...

Embodiment 3

[0036] A long glass fiber reinforced polypropylene material is composed of the following components: 48.7wt% polypropylene, 50wt% long glass fiber, 1wt% compatibilizer, and 0.3wt% antioxidant. Polypropylene is high melting point polypropylene with a melt index of 500g / 10min. High melting point polypropylene is one or a mixture of high melting point homopolypropylene and copolymerized polypropylene. The compatibilizer is maleic anhydride grafted polypropylene, and the maleic anhydride grafting ratio is 1.1. Long glass fibers are long glass fibers treated with a coupling agent.

[0037] The long glass fiber is LFT continuous roving, the fiber type is E glass, and the fiber monofilament diameter is 1200Tex 16μm.

[0038] The preparation method of long glass fiber reinforced polypropylene material comprises the following steps:

[0039] Step 1: Add polypropylene, compatibilizer and antioxidant to the mixer to make them fully mixed evenly;

[0040] The second step: Add the mixtu...

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Abstract

The invention belongs to field of a polymer material and shaping thereof, in particular to a long glass fiber reinforced polypropylene material and a preparation method thereof. The long glass fiber reinforced polypropylene material is prepared from the following components: 35-68wt% of polypropylene, 30-60wt% of long glass fiber, 1-5wt% of compatilizer and 0.3-1.0wt% of antioxidant, wherein the polypropylene is polypropylene with a melt index as high as 50-500g / 10min. The preparation method comprises the following steps: mixing the polypropylene, the compatilizer and the antioxidant; feeding the mixture in a double-screw extruder; enabling the long glass fiber to be fully soaked by melts through a soaking die; and cooling, drawing and pelletizing the fully soaked long glass fiber to obtain the long glass fiber reinforced polypropylene material. By the invention, the soaking effect of the glass fiber in polypropylene melts can be reinforced, substances harmful to human bodies can be eliminated or reduced, the odor is lightened, and the soaking effect and mechanical property of the material can be effectively improved.

Description

technical field [0001] The invention belongs to the field of polymer materials and their molding processing, and relates to a long glass fiber reinforced polypropylene material and a preparation method thereof. Background technique [0002] In the manufacturing process of short fiber reinforced thermoplastics, when the fiber is mixed with the resin in the extruder, the fiber will be damaged due to the shear between the screw and the barrel. The original 6mm fiber is in the pellet. The length becomes 0.2-1mm (generally below 0.7mm). Since the properties of reinforced plastics are related to fiber length, short fibers are difficult to use for structural purposes. The length of glass fiber in long glass fiber reinforced polypropylene material is longer, and the distribution of fiber length is better, which can improve the mechanical properties of the product, especially the impact strength is significantly improved, and the rigidity is increased, which is conducive to the appl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/14C08L51/06C08K13/06C08K9/00C08K7/14B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 吴建国李兰军郭洪涛
Owner NANJING JULONG SCI&TECH CO LTD
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