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Double reverse flotation process of middle-low grade phosphorite

A phosphorite and double reverse flotation technology, applied in flotation, solid separation, etc., can solve the problems of poor selectivity, lower flotation separation efficiency, deterioration of flotation process, etc., and achieve easy control and operation, desiliconization and reverse flotation Simple and smooth selection process

Active Publication Date: 2011-02-16
BLUESTAR LEHIGH ENG INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In reverse flotation desilication, amine cationic collectors are sensitive to slime, RNH 3 + It is easy to adsorb the surface of slime particles, resulting in increased consumption of collectors, and often produces a large amount of viscous foam
The selectivity of amine collectors is relatively poor, and at the same time, it has foaming properties. If the amount is added too much, it will often deteriorate the flotation process and reduce the flotation separation efficiency.

Method used

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  • Double reverse flotation process of middle-low grade phosphorite
  • Double reverse flotation process of middle-low grade phosphorite
  • Double reverse flotation process of middle-low grade phosphorite

Examples

Experimental program
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Effect test

Embodiment 1

[0014] Example 1. refer to figure 1 . A double reverse flotation process for medium and low-grade phosphorite, the steps of which are:

[0015] (1) After the phosphorite raw ore is ground to the particle size required by flotation, add reverse flotation magnesium removal regulator 5kg / t raw ore and magnesium removal collector 0.8kg / t raw ore to carry out magnesium roughing operation, magnesium roughing The tank contains coarse concentrate for magnesium removal; magnesium roughing foam is added with 1kg / t raw ore regulator to carry out magnesium re-election operation, and the magnesium re-election tank is for magnesium-removing medium ore, and the magnesium-removing medium ore returns to magnesium roughing in sequence. The magnesium re-election foam is carbonate tailings; the magnesium roughing flotation time is 5 minutes, and the magnesium re-election time is 4 minutes; the magnesium removal regulator is selected from sulfuric acid, phosphoric acid or sulfuric acid and phosp...

Embodiment 2

[0017] Example 2. refer to figure 1 . A double reverse flotation process for medium and low-grade phosphorite, the steps of which are:

[0018] (1) After the phosphorite raw ore is ground to the particle size required by flotation, 15kg / t of reverse flotation magnesium removal regulator and 2.5kg / t raw ore of magnesium removal collector are added to carry out magnesium roughing operation. The tank contains coarse concentrate for magnesium removal; magnesium roughing foam is added with 0.1kg / t raw ore regulator to carry out magnesium re-election operation, and the magnesium re-election tank is for magnesium-removing medium ore, and magnesium-removing medium ore returns to magnesium roughing in sequence The magnesium re-election foam is carbonate tailings; the magnesium roughing flotation time is 8 minutes, and the magnesium re-election time is 6 minutes; the magnesium removal regulator is selected from sulfuric acid, phosphoric acid or sulfuric acid and phosphoric acid in a m...

Embodiment 3

[0020] Example 3. refer to figure 1 . A double reverse flotation process for medium and low-grade phosphorite, the steps of which are:

[0021] (1) After the phosphorite raw ore is ground to the particle size required by flotation, add 10kg / t raw ore of reverse flotation magnesium removal regulator and 1.5kg / t raw ore of magnesium removal collector to carry out magnesium roughing operation, magnesium roughing The tank contains coarse ore for magnesium removal; the magnesium roughing foam is added with 0.5kg / t raw ore regulator, and the magnesium re-election operation is carried out. The magnesium re-election foam is carbonate tailings; the magnesium roughing flotation time is 6 minutes, and the magnesium re-election time is 5 minutes; the magnesium removal regulator is selected from sulfuric acid, phosphoric acid or sulfuric acid and phosphoric acid in a mass ratio of 1: 1, the magnesium removal collector is a saponified product of alkyl fatty acid;

[0022] (2) Add 200g / t...

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Abstract

The invention relates to a double reverse flotation process of middle-low grade phosphorite. The double reverse flotation process is characterized by comprising the following steps of: after milling raw phosphorite ores to the granularity required by flotation, adding a reverse flotation de-magging adjustor and a catching agent for executing rough magnesium flotation operation, wherein de-maggingrough concentrate is in a rough magnesium flotation groove; after adding the regulator in rough magnesium flotation foam, executing magnesium recleaning operation, wherein de-magging middling productis in a magnesium recleaning groove and the magnesium recleaning foam is carbonate gangue; adding a de-silication disperser and a de-silication catching agent in ore slurry in the groove after de-magging, and carrying out de-silication rougher flotation operation I; then adding a de-silication catching agent and non-polar oil for performing the de-silication rougher flotation operation II, wherein ore concentrate is in a rough silicon flotation groove; after combining the foam of the silicon rougher flotation I and the silicon rougher flotation II, adding the de-silication catching agent for performing the silicon recleaning, wherein de-silication middling product is in a silicon recleaning groove, and silicon recleaning foam is silica gangue; and combining the de-silication middling product and the ore concentrate to obtain the comprehensive phosphorus concentrate. The process can increase the catching of the silicon gangue, improve the selecting efficiency and reduce the consumptionof the reverse flotation de-silication catching agent.

Description

technical field [0001] The invention relates to a flotation process for phosphorite, in particular to a double-reverse flotation process for medium and low-grade phosphorite. Background technique [0002] Phosphorite is an important non-renewable resource. Its application in agriculture is irreplaceable and non-renewable. Phosphorite needs to be processed by flotation to reduce the content of associated gangue minerals (such as quartz, chalcedony, clay, feldspar, mica, dolomite and calcite) to meet the requirements of phosphate rock for acid processing phosphate fertilizer. [0003] Phosphate resources in my country are characterized by ancient ore-forming ages, P-containing 2 o 5 Medium and low grade, silicon-calcium refractory sedimentary phosphorite ore is the main body. Flotation of this type of phosphate rock not only requires the removal of carbonate gangue minerals (mainly dolomite), but also requires the discharge of some silicate gangue minerals (mainly quartz, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03D1/02B03D1/08
Inventor 杨勇李艳柳佃义朱孔金冯春晖刘星强
Owner BLUESTAR LEHIGH ENG INST CO LTD
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