Polyurethane for orthopedic external fixation system in complicated environment and preparation method thereof
A complex environment, polyurethane technology, applied in medical science, prosthesis, bandages, etc., can solve the problem of polyurethane hardening and heat generation, achieve superior comprehensive cost performance, ideal effect, and avoid the effect of inducing cardiovascular and cerebrovascular diseases
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Embodiment 1
[0042] Preparation of modified isocyanate: react polyphenyl polymethylene isocyanate with polyether diol at 70-90°C to obtain modified isocyanate;
[0043] The preparation of polyether polyol mixture: the polyether polyol of 60 weight parts, the triethylenediamine of 0.5 weight part, the organosilicon stabilizer of 1 weight part, the water of 0.5 weight part, the calcium carbonate of 37 weight parts and 1 The polyether polyol mixture is obtained after the silicon dioxide of weight part is mixed;
[0044] Preparation of polyurethane: mix the polyether polyol mixture and modified isocyanate prepared above in a weight ratio of 1:0.6 to obtain polyurethane.
Embodiment 2
[0046] The preparation of modified isocyanate is with embodiment 1;
[0047] The preparation of polyether polyol mixture: the polyether polyol of 61 weight parts, the triethylenediamine of 1 weight part, the organosilicon stabilizer of 2 weight parts, the water of 0.1 weight part, the calcium carbonate of 35.4 weight parts and 0.5 The polyether polyol mixture is obtained after the silicon dioxide of weight part is mixed;
[0048] Preparation of polyurethane: mix the polyether polyol mixture and modified isocyanate prepared above in a weight ratio of 1:0.65 to obtain polyurethane.
Embodiment 3
[0050] The preparation of modified isocyanate is with embodiment 1;
[0051] The preparation of polyether polyol mixture: the polyether polyol of 62 weight parts, the triethylenediamine of 0.3 weight part, the organosilicon stabilizer of 2 weight parts, the water of 2 weight parts, the calcium carbonate of 33 weight parts and 0.7 The polyether polyol mixture is obtained after the silicon dioxide of weight part is mixed;
[0052] Preparation of polyurethane: mix the polyether polyol mixture and modified isocyanate prepared above in a weight ratio of 1:0.65 to obtain polyurethane.
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