Method for hydrogenation and catalytic cracking of residual oil

A catalytic cracking and hydrotreating technology, applied in the production of gasoline products, can solve the problems of increased investment costs, limited naphtha and diesel yield, and reduced total yield, so as to reduce equipment investment and operating energy consumption, save Duplicate processing steps, reduce the effect of heat exchange equipment

Active Publication Date: 2013-03-20
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

However, in this method, a fractionation system is installed in both the hydrotreating and catalytic cracking processes, which increases the investment cost; due to the heat exchange in the process, the heat energy loss is more; at the same time, both the hydrotreating unit and the catalytic cracking unit have diesel products, relatively speaking , the total yield of gasoline and gas products will decrease
In addition, the residual oil cracking rate of the residual oil hydrotreating unit is low, and the yields of naphtha and diesel oil obtained by fractionating the hydrogenated oil are limited, and the diesel fraction obtained during the residual oil hydrotreating process still cannot meet the high quality requirements. Requirements for Diesel Products

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  • Method for hydrogenation and catalytic cracking of residual oil
  • Method for hydrogenation and catalytic cracking of residual oil

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Embodiment

[0032] This embodiment adopts the combined method of residual oil hydrotreating and catalytic cracking provided by the present invention, and all the liquid phase products of hydrotreating directly enter the catalytic cracking unit without fractionation, and the fractionation system of catalytic cracking reaction effluent is simplified in design, and only the dry gas is fractionated out , liquefied petroleum gas and gasoline fractions, catalytic cracking diesel oil, catalytic cracking cycle oil and catalytic oil slurry are directly used as catalytic cracking heavy fractions without fractionation. The catalytic cracking heavy fractions are filtered out of solid impurities and then recycled to the hydrotreating unit for further processing. Table 2, Table 3, and Table 5 are process conditions, product distribution, and main product properties, respectively.

[0033] The comparison results show that after hydrotreating the FCC heavy distillate oil and the fresh residue raw material...

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Abstract

The invention discloses a method for the hydrogenation and catalytic cracking of residual oil. In the method, the hydrogenation of a residual oil raw material is performed in the presence of hydrogen and a hydrogenation catalyst; the effluent of the hydrogenation is subjected to gas-liquid separation; a gas phase is circularly used for hydrogenation; a liquid phase directly enters a catalytic cracking device without fractionation; and dry gases, liquefied gases and the catalytic cracking heavy fraction obtained after the catalytic cracking of gasoline are separated from the effluent of the catalytic cracking reaction and mixed with a hydrogenating raw material to undergo hydrogenation. Compared with the prior art, the method can produce gasoline with a maximum yield and can save equipment investment, make full use of reaction heat energy and reduce production energy consumption at the same time.

Description

technical field [0001] The invention relates to a method for lightening residual oil, in particular to a process for mainly producing gasoline products by organically combining residual oil hydrotreating and catalytic cracking and using residual oil as a raw material. Background technique [0002] As crude oil becomes heavier and worse, more and more residues need to be processed. The processing of heavy and residual oil is not only to crack it into products with low boiling points, such as naphtha, middle distillate oil and vacuum gas oil, but also to increase their hydrogen-carbon ratio, which requires decarbonization Or hydrogenation method to achieve. The decarbonization process includes coking, solvent deasphalting, heavy oil catalytic cracking, etc.; hydrogenation includes hydrocracking, hydrofining, etc. The hydrogenation method can hydrogenate and convert residual oil, improve the yield of liquid products, and remove heteroatoms therein, and the product quality is ...

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/04
Inventor 关明华刘铁斌耿新国张学萍
Owner CHINA PETROLEUM & CHEM CORP
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