Method for water plugging and profile controlling of underground polymerization of oil exploitation sludge

A technology of oil extraction sludge, water plugging and profile control, applied in the direction of water/sludge/sewage treatment, sludge treatment, chemical instruments and methods, etc., to achieve the effect of cost saving

Active Publication Date: 2009-11-11
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the method requires multiple processes in above-ground plant equipment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Add 10 grams of an aqueous solution containing 31.5% acrylamide in a 200 ml glass reaction vessel, then add 15 grams of pretreated oil production sludge (dry basis) after deoiling and desanding, add the remainder of tap water, stir and mix evenly, Then add 0.3 g of glycerin and 0.03 g of ammonium persulfate, stir and mix evenly, and place in an oven at a certain temperature for polymerization.

Embodiment 2

[0015] Add 2 grams of acrylamide crystals and 2 grams of acrylic acid (acrylic acid needs to be neutralized with alkali to form sodium acrylate) in a 200ml glass reaction vessel at 200°C, and then add 20 grams of oil production sludge pretreated for oil removal and sand removal (reduced dry meter), then add 75.68 grams of oilfield sewage, stir and mix. Then add 0.3 g of N,N-methylenebisacrylamide and 0.02 g of ammonium persulfate, stir and mix evenly, then place in an oven at a certain temperature for polymerization to obtain the desired product.

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Abstract

The invention relates to a method for water plugging and profile controlling of underground polymerization of oil exploitation sludge, comprising the following steps of: adding 2-7% of crylic acid, 0-3% of acrylamide, 0.2-0.6% of cross linking agent and 0.01-0.05% of initiator into 15-25% of oil exploitation sludge, injecting the mixture together with the oil field water or tap water in the ground; and subsequently generating plugging substances of solid mesh structure wrapping sludge owning to the polymerization reaction under the action of oil pool temperature, thus playing an effect of sealing the underground seams, wherein the oil exploitation sludge is a tank bottom sludge generated during the oil exploitation process of the oil field or the sludge in the sludge pool; the sludge is athin oil sludge; the cross linking agent is a polyol, a glycerin, an N, N-methylene bisacrylamide or N, N-dimethybisacrylamide; and the initiator is the alkali metal salt or the ammonium salt of a persulphuric acid. The method changes the aboveground polymerization process of the oil exploitation sludge grain profile control agent into the underground polymerization process, saves corresponding procedures and the equipment and devices, and generates the water-plugging profile control agent with high intensity and long-term effect by adjusting the concentration of the monomer.

Description

technical field [0001] The invention relates to a method for underground polymerization of oil production sludge for water plugging and profile control. Background technique [0002] Oilfield oil production sludge is a kind of waste produced in the oil production process. The traditional treatment method is landfill, which pollutes the environment and wastes resources. Current environmental regulations prohibit landfilling. The current non-landfill methods mainly include 1, pyrolysis method. 2. Profile control and water blocking method. The pyrolysis method is mainly aimed at heavy oil sludge with high oil content, and cracks the heavy oil in the sludge into usable thin oil through high temperature cracking. The profile control and water plugging method is to make the heavy oil sludge into the profile control agent used in the oil field and re-inject it into the underground oil reservoir, so as to realize the harmless and resource utilization of the sludge. Profile contr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E21B43/22E21B33/13C09K8/00C02F11/00
Inventor 李芮丽赵振兴马自俊李宜坤熊春明刘国良张娜杨宁刘玉章
Owner PETROCHINA CO LTD
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