Method for removing low-concentration heavy metal in waste water by sludge absorption
A low-concentration heavy metal and sludge adsorption technology, applied in the direction of adsorption water/sewage treatment, water/sludge/sewage treatment, sludge treatment, etc., can solve the problems of high cost and secondary pollution, and achieve great promotion potential, Strong practicability and wide applicability
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Embodiment 1
[0024] The treatment object is river water polluted by Pb, and its Pb concentration is determined to be 25mg / L by inductively coupled plasma emission spectrometry.
[0025] The dewatered sludge was taken from an urban sewage plant in Shanghai, dried in an oven at 50°C for 72 hours to constant weight, taken out and ground, and then passed through a 0.45mm national standard sieve, and the undersieve was non-living biomass adsorbent. Use HCl to adjust the pH of the river water to be treated to 3.5, add 10m 3 volume of stirred tank reactor, and then press every 1m 3 The ratio of 4kg of river water was added to the adsorbent; the stirring speed was controlled to 200r / min, and the mixing reaction was carried out at room temperature for 60min. The supernatant is clean river water from which heavy metals have been separated and removed. The Pb concentration is 0.06mg / L as measured by inductively coupled plasma emission spectrometry, and the removal rate of Pb reaches 99.76%. It can b...
Embodiment 2
[0027] The object of treatment is a metal processing plant subject to Cd and Cr 3+ Contaminated industrial wastewater, the concentration of hexavalent chromium in the wastewater measured by AWWA-3500 spectrophotometry is lower than the detection limit of the method, and the initial concentration of Cd and Cr are 10mg / L and 50mg / L respectively, measured by inductively coupled plasma emission spectrometry , Cr is calculated from the concentration difference between total chromium and hexavalent chromium 3+ The initial concentration is 50mg / L.
[0028] The dewatered sludge was taken from an urban sewage plant in Shanghai, dried in an oven at 55°C for 48 hours to constant weight, taken out and ground, and then passed through a 0.45mm national standard sieve, and the under-sieve was non-living biomass adsorbent. Use HCl to adjust the pH of the wastewater to 4, add 15m 3 volume of stirred tank reactor, and then press every 1m 3 The ratio of 2kg of waste water was added to the ads...
Embodiment 3
[0030]The object of treatment is an electroplating plant containing Cu and Cr 3+ For the industrial wastewater, the AWWA-3500 spectrophotometric method was used to measure the concentration of hexavalent chromium in the wastewater, which was lower than the detection limit of the method. It was measured by inductively coupled plasma emission spectrometry. Calculation of hexavalent chromium concentration difference Cr 3+ The initial concentration is 100mg / L.
[0031] Using the present invention as the pretreatment process of the biological treatment process, the dewatered sludge is taken from an urban sewage plant in Shanghai, dried in an oven at 55°C for 48 hours to constant weight, taken out and ground, and then passed through a 0.45mm national standard sieve, and the undersieve It is a non-living biomass adsorbent. Use HCl to adjust the pH of the wastewater to 4, add 15m 3 volume of stirred tank reactor, and then press every 1m 3 The ratio of 10kg of wastewater was added ...
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