Method for manufacturing semiconductor device
A manufacturing method and semiconductor technology, applied in semiconductor/solid-state device manufacturing, semiconductor devices, electric solid-state devices, etc., can solve problems such as increased cut-off current
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Embodiment approach 1
[0090] In this embodiment, referring to Fig. 1A to Figure 7B A manufacturing process of a thin film transistor used in a liquid crystal display device will be described. Figure 1A to Figure 3C is a sectional view showing a manufacturing process of a thin film transistor, and Figure 4 It is a top view of the connection area of a thin film transistor and a pixel electrode in a pixel. In addition, FIG. 5 is a timing chart showing a method of forming a microcrystalline semiconductor film. Figure 6A with 6B An example of a reaction chamber for forming a microcrystalline semiconductor film is shown. Figure 7A with 7B show will Figure 6A with 6B The shown perspective view and plan view of an example of a plasma CVD (Chemical Vapor Deposition) apparatus in which reaction chambers are stacked in the vertical direction.
[0091] As for thin film transistors having microcrystalline semiconductor films, n-type thin film transistors have higher mobility than p-type thin fil...
Embodiment approach 2
[0153] This embodiment mode shows an example of a multi-chamber plasma CVD apparatus suitable for forming the microcrystalline semiconductor film constituting the TFT described in the first embodiment mode.
[0154] Figure 6A An example of the plasma CVD apparatus shown in Embodiment 1 is shown, in which a film formation chamber 204a, which is a processing chamber capable of maintaining a reduced-pressure atmosphere, is provided outside the reaction chamber 208a where the microcrystalline semiconductor film 53 is formed.
[0155] exist Figure 6A In this example shown, the reaction chamber 208a is grounded, the reference numeral 205a denotes a high-frequency power supply, and the reference numeral 221 denotes a first electrode (upper electrode, shower electrode, high-frequency electrode) having a hollow structure through which raw material gas can pass. , reference numeral 225 represents a grounded second electrode (lower electrode, ground electrode), reference numeral 206a ...
Embodiment approach 3
[0170] In this embodiment mode, a method of manufacturing a thin film transistor having excellent characteristics by selecting a gas used for forming a microcrystalline semiconductor film by a CVD method and a film forming method will be described.
[0171]In one method, the field-effect mobility of the TFT is improved by making the microcrystalline semiconductor film 23 obtained under the first film-forming condition in Embodiment 1 into an n-type. Specifically, when forming the microcrystalline semiconductor film under the first film-forming conditions, an n-type impurity element is added. As the n-type impurity element used at this time, phosphorus, arsenic, and antimony can be used. In particular, it is preferable to use inexpensive phosphorus as the phosphine gas.
[0172] Furthermore, by exposing the surface of the gate insulating film to phosphine gas, phosphorus is attached (or reacted) before nitrogen and oxygen are attached to the surface of the gate insulating film...
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