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Polycarbonate resin composition and molded plate obtained therefrom

A technology of polycarbonate resin and polycarbonate, which is applied in the field of polycarbonate resin composition and its forming board, can solve the problems of impracticality, polycarbonate resin composition can not meet the transparency, etc., and achieve excellent thermal stability Effect

Inactive Publication Date: 2009-04-29
IDEMITSU KOSAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the polycarbonate resin composition obtained by this method cannot satisfy transparency (haze: haze) or thermal stability, and is not practical.

Method used

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  • Polycarbonate resin composition and molded plate obtained therefrom
  • Polycarbonate resin composition and molded plate obtained therefrom

Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0101] [Manufacture of polymer-based dispersant-treated ITO]

[0102] In 100 g of 15 mass % ITO toluene dispersion (manufactured by C.I. Chemical Industry Co., Ltd., ITO average particle diameter: 30 nm), 230 g of 20 mass % PMMA toluene solution was added to make polymethyl methacrylate (PMMA) relative to 1 part by mass of ITO was 3 parts by mass, mixed and stirred at room temperature (25° C.), and then heated and concentrated at 120° C. to obtain a viscous liquid. Then, after drying, it was pulverized to obtain 60 g of ITO treated with PMMA.

Embodiment 1～9、 comparative example 1～8

[0104] [mixed ingredients]

[0105] The types of materials used in Examples and Comparative Examples are as follows.

[0106] (A) polycarbonate

[0107] (A-1): Polycarbonate (trade name: Toughlon FN2200, manufactured by Idemitsu Kosan Co., Ltd., viscosity average molecular weight: 22,000)

[0108] (B) ATO or ITO

[0109] (B-1): ATO processed with a polymeric dispersant [trade name: FMDS-874, manufactured by Sumitomo Metal Mining Co., Ltd., made of 3 parts by mass of polymethacrylic acid relative to 1 part by mass of ATO Infrared shielding material composed of methyl ester dispersant, ATO average particle size: 80nm, antimony content in ATO: 10% by mass]

[0110] (B-2): ITO treated with a polymeric dispersant (PMMA) obtained in Production Example 1 above

[0111] (B-3): ATO powder [trade name: T-1, JEMCO type, ATO average particle diameter: 31nm (average particle diameter of dispersion liquid)) and stearic acid monoglyceride (low molecular system dispersant) (commodity Nam...

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Abstract

Provided are a polycarbonate resin composition including the following substances in a specific proportion: a polycarbonate, a fine particle of antimony-doped tin oxide (ATO) treated with a polymeric dispersant and / or a fine particle of tin-doped indium oxide (ITO) treated with a polymeric dispersant, and a reactive silicone compound having one or more alkoxy groups and a phenyl group in a molecule thereof, and a molded plate formed by subjecting the polycarbonate resin composition to an injection molding or an extrusion molding. That is, the polycarbonate resin composition which shields a mid-infrared region and is excellent in transparency and thermal stability and the molded plate obtained therefrom are provided.

Description

technical field [0001] The present invention relates to a polycarbonate resin composition and a molded sheet thereof. More specifically, it relates to shielding the mid-infrared region, has excellent thermal stability and transparency, and is suitable for building materials (exterior), resinous windows, electricity, and electronics. A polycarbonate resin composition for window parts and its formed sheet. Background technique [0002] A film or sheet is known which can prevent temperature rise due to sunlight, infrared lamps, etc. by effectively cutting off infrared rays. [0003] Polycarbonate is excellent in impact resistance, heat resistance, and transparency, and is widely used as transparent plates such as building materials, and a transparent plate in which an infrared absorbing material is mixed with polycarbonate is known. [0004] However, since this kind of transparent plate has deterioration of the resin caused by the infrared absorbing material or the deteriorati...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08J5/00C08K3/38C08K5/00C08K9/04C08L83/06
CPCC08K9/08C08L69/00C08K3/38C08L83/06C08G77/18
Inventor 中江贡
Owner IDEMITSU KOSAN CO LTD
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