Adhesive composition, filmy adhesive, adhesive sheet, and semiconductor device made with the same
A technology of adhesives and compositions, applied in the direction of film/sheet adhesives, pressure-sensitive films/sheets, non-polymer organic compound adhesives, etc., can solve problems such as insufficiency, and achieve simplification of the pasting process, It has the effect of picking up and suppressing chip flying
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[0201] Hereinafter, the present invention will be specifically described based on examples, but the present invention is not limited to these examples.
[0202] Synthesis of Polyimide Resin (PI)
[0203] (PI-1)
[0204] In a 300mL flask equipped with a thermometer, a stirrer, a condenser tube and a nitrogen inflow tube, 2.71 g (0.045 mol) of 1,12-diaminododecane, polyether diamine (D2000 (molecular weight: 1923)) 5.77g (0.01mol), 1,3-bis(3-aminopropyl)tetramethyldisiloxane (LP-7100 manufactured by Shin-Etsu Chemical Co., Ltd.) 3.35g (0.045mol) and N-methyl - 113 g of 2-pyrrolidone, and the reaction liquid was stirred. After 1,12-diaminododecane and polyetherdiamine are dissolved, cool the flask in an ice bath and add 4,4'-(4,4'-isosubstance, which has been refined by recrystallization with acetic anhydride in small amounts. Propyldiphenoxy)bis(phthalic dianhydride) 15.62 g (0.1 mol) (difference between endothermic start temperature and endothermic peak temperature measured ...
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