Prepreg and laminate
A technology of prepreg and base material, applied in the field of prepreg and laminate, can solve the problem of low tolerance, and achieve the effect of high fire resistance, excellent chemical resistance, and excellent heat resistance after moisture absorption
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[0039] The present invention is explained in detail below with reference to synthesis examples, examples and comparative examples, but the present invention is not limited by these examples.
Synthetic example 1
[0040] (Synthesis example 1) Synthesis-1 of α-naphthol aralkyl type cyanate resin
[0041]
[0042] 103 g (0.47 moles of OH groups) of α-naphthol aralkyl resin (SN485, OH group equivalent: 219 g / eq., softening point: 86° C.) represented by the above general formula (4) were prepared by NipponSteel Chemical Co. ., Ltd.) was dissolved in 500 ml of chloroform, and 0.7 mol of triethylamine was mixed with the resulting solution. The resulting mixture was added dropwise to a solution of 0.93 molar cyanogen chloride in 300 g of chloroform at -10°C over 1.5 hours. The mixture was stirred for 30 minutes. To the mixture was further added dropwise a mixed solution of 0.1 mol of triethylamine and 30 g of chloroform, and the resulting mixture was stirred for 30 minutes to complete the reaction. The resulting triethylamine hydrochloride was isolated by filtration. The filtrate thus obtained was washed with 500 ml of 0.1N hydrochloric acid. The washing was then repeated 4 times with 5...
Synthetic example 2
[0044] (Synthesis example 2) Synthesis-2 of α-naphthol aralkyl type cyanate resin
[0045]An α-naphthol aralkyl type cyanate resin was synthesized in the same manner as in Synthesis Example 1, except that 103 g (0.47 moles of OH groups) of an α-naphthol aralkyl resin (SN485, OH group equivalent: 219 g / eq., softening point: 86°C, provided by Nippon Steel Chemical Co., Ltd.) replaced by 102 g (OH group 0.45 mole) α-naphthol aralkyl resin (SN4105, OH group equivalent: 226 g / eq., softening point: 105°C, provided by Nippon Steel Chemical Co., Ltd.), and the amount of cyanogen chloride was changed from 0.93 moles to 0.90 moles.
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