Method for rapidly measuring reinforcing steel tarnishing criticality chlorine ion concentration
A technology of chloride ion concentration and steel corrosion, applied in the direction of electrochemical variables of materials, etc., can solve the problems of real-time monitoring of non-corroding batteries, high voltage, long test time, etc., and achieve the effect of reducing the time for critical concentration determination.
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[0022] In a certain test, the mass of concrete powder obtained by sampling the concrete on the surface of the electrode was 6.9g, and the concentration of silver nitrate used was C AgNO3 =0.01mol / l, the cement content C%=17.58% in the concrete, and the volume relationship between the potential measured during titration and the consumed silver nitrate solution and its first-order and second-order derivatives are shown in the following table:
[0023] V AgNO3
Potential difference E / mV
ΔE / ΔV(mV / ml)
ΔE 2 / ΔV 2 (mV / ml 2 )
0.0
211.0
2.0
221.0
5
4.0
248.4
13.7
4.35
5.5
281.8
22.3
5.73
6.0
289.3
15.0
-14.6
8.0
312.5
11.6
-1.7
10.0
321.6
4.5
-14.2
[0024] Use the interpolation method to calculate the corresponding second-order differential quotient ΔE 2 / ΔV 2 is zero when V...
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