Powdery polycarboxylic-acid cement dispersant and dispersant composition containing the dispersant
A cement dispersant and polycarboxylic acid-based technology, used in the field of dispersant compositions and powdered polycarboxylic acid-based cement dispersants, can solve the problems of insufficient improvement of the performance of concrete products, prevent caking and have excellent solubility. , Improve the effect of water reduction
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preparation example Construction
[0050] For the preparation of polyamide polyamine, that is, the polycondensation reaction of compounds a, b and c, for example, at first only compound a and compound b are polycondensed, and then adding compound c as a monobasic acid to continue polycondensation is a two-step reaction method, or A one-step reaction method of polycondensation by mixing compounds a, b, and c at the same time from the beginning, etc. However, no matter which method is used, since the polycondensation reaction, that is, the amidation reaction and the exchange amidation reaction proceed simultaneously, the acrylic acid residue or the methacrylic acid residue derived from the compound c is finally located at the end of the polyamide chain, and it can be considered that is to get the same result.
[0051] Next, the reaction molar ratios of the above three components constituting the polyamide polyamine will be described. The reaction ratio of compound b (diacid or its ester) to 1.0 mol of compound a...
Synthetic example 1
[0079] [Synthesis Example 1] Preparation of Polycarboxylic Copolymer
[0080] Add 1400g of water to a 5L (liter) reactor equipped with a stirrer, a nitrogen inlet pipe, a condenser, and a thermometer, and introduce nitrogen into the reaction vessel to make the synthesis system a nitrogen atmosphere, and then heat up to 80°C. Add 380 g of water and 496 g of polyamide polyamine as Compound A to the first dropping funnel equipped with a stirrer (compound A-1 prepared according to the production method described in Japanese Patent No. 3336456 (solid content 40%) , with respect to the added mass ratio of all monomers is 15%), 290g of methacrylic acid (compound B-1, mass ratio of 20%) as compound B, and 1244g of methoxy PEG (poly Ethylene glycol) (molecular weight 1000) ester (compound C-1, mass ratio 65%) mixture. To the second dropping funnel was added 440 g of a 10% aqueous solution of thioglycolic acid. Next, 489 g of 10% sodium persulfate aqueous solution was added to the thi...
Synthetic example 2~6
[0081] [Synthesis examples 2-6] Production of polycarboxylic acid-based copolymers
[0082] The kind, quality and alkali kind of each monomer of compound A, B, C are changed into the numerical value shown in following table 1, other according to the same method as above-mentioned synthetic example 1, prepare polycarboxylate copolymer 2~6 respectively of aqueous solution.
[0083] [Table 1]
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