Method of electrolytic ceramic coating for metal, electrolyte for use in electrolytic ceramic coating for metal, and metal material
A metal material, ceramic coating technology, applied in the direction of electrolytic coating, surface reaction electrolytic coating, coating, etc., can solve the problem that it is difficult to form a dense hard anodic oxide film, and achieve excellent wear resistance and sliding properties, hardness High, excellent toughness effect
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Embodiment 1
[0213] Use surface area 0.12dm 2 An aluminum plate (JIS 1000 series) was used as an anode, and a stainless steel plate was used as a cathode, and electrolytic treatment was performed for 10 minutes by a bipolar electrolysis method to form a film on the surface of the aluminum plate. When the surface of the anode during electrolytic treatment was observed, light emission due to spark discharge and glow discharge was observed.
[0214] As the electrolytic solution, an electrolytic solution (pH 11.7) containing 0.01 mol / L potassium zirconium carbonate, 0.015 mol / L sodium pyrophosphate, and 0.036 mol / L potassium hydroxide in water was used.
[0215] As the voltage waveform, a voltage waveform having a frequency of 60 Hz in which an AC component with an effective value of 300 V was superimposed on a DC component of 300 V was used. The maximum value of the voltage value is about 720V, and the minimum value is about -120V. The current density is about 150A / dm at the positive peak ...
Embodiment 2
[0217] Except using the electrolytic solution (pH11.8) that the potassium hydroxide that contains 0.01mol / L zirconium carbonate in water, the potassium hydroxide that 0.036mol / L obtains as electrolytic solution, carry out electrolytic treatment according to the same method as embodiment 1, in A film is formed on the surface of the aluminum plate. When the surface of the anode during electrolytic treatment was observed, light emission due to spark discharge and glow discharge was observed.
Embodiment 3
[0219] In addition to using an electrolyte (pH 11.6) containing 0.01 mol / L potassium zirconium carbonate, 0.015 mol / L sodium pyrophosphate, 0.036 mol / L potassium hydroxide, and 0.02 mol / L hydrogen peroxide in water Except for the electrolytic solution, electrolytic treatment was performed in the same manner as in Example 1 to form a film on the surface of the aluminum plate. When the surface of the anode during electrolytic treatment was observed, light emission due to spark discharge and glow discharge was observed.
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