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Mixture containing fatty acid ethyl sulfonate and preparation method thereof

A technology of fatty acid ethyl ester sulfonate and fatty acid ethyl ester sulfonic acid, which is applied in chemical instruments and methods, chemical/physical processes, dissolution and other directions, and can solve problems such as undiscovered, protein fiber damage, and carcinogenicity.

Inactive Publication Date: 2009-03-18
谢仁华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For washing products such as washing powder, sodium alkylbenzene sulfonate is often used as a surfactant. The disadvantage is that sodium alkylbenzene sulfonate contains a benzene ring and is a carcinogen; It has good detergency under certain conditions, so when washing clothes, it will cause damage to protein fibers, and if it is washed by hand, it will also have an adverse effect on the skin; third, in order to increase the washing effect, it is often necessary to add sodium tripolyphosphate as a water softener , while the discharge of phosphorus-containing substances pollutes the environment
So far, there is no report on the method of preparing fatty acid ethyl ester sulfonate with fatty acid ethyl ester

Method used

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  • Mixture containing fatty acid ethyl sulfonate and preparation method thereof
  • Mixture containing fatty acid ethyl sulfonate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (embodiment 1) preparation creamy mixture containing fatty acid ethyl ester sulfonate

[0023] ① Take fatty acids with a carbon chain length of 12-18 for ethylation reaction to obtain fatty acid ethyl esters, heat the fatty acid ethyl esters to 45°C, and then pressurize the heated fatty acid ethyl esters to 20kg / cm through a high-pressure pump 2 , and then sent into the high-pressure jet atomizer to atomize the fatty acid ethyl ester; carry out the sulfonation reaction with the atomized fatty acid ethyl ester and gaseous sulfur trioxide in a molar ratio of 1: 1.1, and the time of the sulfonation reaction is 15s, the temperature is 85°C, and the pressure is 0.05Mpa. The products are fatty acid ethyl ester sulfonic acid and sulfo fatty acid. Fatty acid ethyl ester is contacted and mixed with gaseous sulfur trioxide, wherein the foggy fatty acid ethyl ester flows in a straight line, while the gaseous sulfur trioxide flows in a vortex.

[0024] ② Add ethanol to the mixed ...

Embodiment 2

[0029] (embodiment 2) preparation creamy mixture containing fatty acid ethyl ester sulfonate

[0030] ① Take fatty acid with a carbon chain length of 12-18 for ethylation reaction to obtain fatty acid ethyl ester, heat the fatty acid ethyl ester to 50°C, and then pressurize the heated fatty acid ethyl ester to 30kg / cm through a high-pressure pump 2, and then sent into the high-pressure jet atomizer to atomize the fatty acid ethyl ester; carry out the sulfonation reaction with the atomized fatty acid ethyl ester and gas phase sulfur trioxide in a molar ratio of 1: 1.05, and the time of the sulfonation reaction is 25s, the temperature is 80°C, and the pressure is 0.01Mpa. The products are fatty acid ethyl ester sulfonic acid and sulfo fatty acid. Fatty acid ethyl ester is contacted and mixed with gaseous sulfur trioxide, wherein the foggy fatty acid ethyl ester flows in a straight line, while the gaseous sulfur trioxide flows in a vortex.

[0031] ② Add ethanol to the mixed ma...

Embodiment 3

[0036] (embodiment 3) preparation creamy mixture containing fatty acid ethyl ester sulfonate

[0037] ① Take fatty acid with a carbon chain length of 12-18 for ethylation reaction to obtain fatty acid ethyl ester, heat the fatty acid ethyl ester to 40°C, and then pressurize the heated fatty acid ethyl ester to 10kg / cm through a high-pressure pump 2 , and then sent into the high-pressure jet atomizer to atomize the fatty acid ethyl ester; carry out the sulfonation reaction with the atomized fatty acid ethyl ester and gaseous sulfur trioxide in a molar ratio of 1:1, and the time of the sulfonation reaction is 5s, the temperature is 90°C, and the pressure is 0.09Mpa. The products are fatty acid ethyl ester sulfonic acid and sulfo fatty acid. Fatty acid ethyl ester is contacted and mixed with gaseous sulfur trioxide, wherein the foggy fatty acid ethyl ester flows in a straight line, while the gaseous sulfur trioxide flows in a vortex.

[0038] ② Add ethanol to the mixed material...

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PUM

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Abstract

The invention relates to a mixture with aliphatic acid carbethoxy sulfonate salt, and relative production, wherein said mixture comprises 90-98 deals of aliphatic acid sulfonate salt, 1-4 deals of aliphatic acid sulfonate salt, 0.5-4 deals of sulfate, 0.1-2 deals of fatty acid ester, 0.3-3 deals of ethylsulfuric acid salt, and 1-50 deals of water. The production comprises that: 1, sulfonating the fatty acid ester and sulfur trioxide at 1:1-1:1. 1 mol ratios; 2, adding alcohol into mixture to be aged; 3, adding auricome into mixture to poach; 4, adding extractive into the mixture to extract; 5, adding alkali metal mixture into mixture to be neutralized to obtain the mixture. The inventive production is safe while the product purity is higher than 90%.

Description

technical field [0001] The invention belongs to the field of organic chemistry, and in particular relates to a mixture containing fatty acid ethyl ester sulfonate and a preparation method thereof. Background technique [0002] Fatty acid ester sulfonates are widely used as surfactants in the fields of medicine, daily chemicals, and washing. For detergents such as washing powder, sodium alkylbenzene sulfonate is often used as a surfactant. The disadvantage is that sodium alkylbenzene sulfonate contains benzene rings and is a carcinogen; It has good detergency under certain conditions, so when washing clothes, it will cause damage to protein fibers, and if it is washed by hand, it will also have an adverse effect on the skin; third, in order to increase the washing effect, it is often necessary to add sodium tripolyphosphate as a water softener , and the discharge of phosphorus-containing substances pollutes the environment. As an alternative product, people use fatty acid m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01F17/00C09K23/00
Inventor 谢仁华谢晓晨
Owner 谢仁华
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