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Water-dispersible, cationic polymers, a method of making same and items using same

a cationic polymer and water-dispersible technology, applied in the direction of synthetic resin layered products, greenhouse cultivation, printing, etc., can solve the problems of inability to create an economical coherent fibrous web, inability to disintegrate products in landfills, and inability to create a coherent fibrous web. , to achieve the effect of good cleaning, good cleaning and good textur

Inactive Publication Date: 2006-07-04
KIMBERLY-CLARK WORLDWIDE INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0013]The present invention further discloses an improved wetting composition for wet wipes. Wet wipes employing the polymer formulations of the present invention are stable during storage and retain a desired level of wet strength during use and are wetted with a wetting composition or cleaning agent that can be relatively free, or is substantially free, of organic solvents.

Problems solved by technology

For many years, the problem of disposability has plagued industries which provide disposable items, such as, diapers, wet wipes, incontinent garments and feminine care products.
While much headway has been made in addressing this problem, one of the weak links has been the inability to create an economical coherent fibrous web, which will readily dissolve or disintegrate in water, but still have sufficient in-use strength.
Furthermore, the ability of the product to disintegrate in a landfill is quite limited because a large portion of the product components, which may well be biodegradable or photodegradable, are encapsulated in or bound together by plastic which degrades over a long period of time, if at all.
Accordingly, if the plastic disintegrated in the presence of water, the internal components could degrade as a result of the rupture of the plastic encapsulation or binding.
However, fibrous webs comprising these compositions tended to be non-dispersible and present problems in typical household sanitation systems.
However, because of the presence of a small amount of sodium acrylate in the partially neutralized terpolymer, these binders fail to disperse in water containing more than about 15 ppm Ca2+ and / or Mg2+.
When placed in water containing more than about 15 ppm Ca2+ and / or Mg2+ ions, nonwoven webs using the above-described binders maintain a tensile strength greater than 30 g / in, which negatively affects the “dispersibility” of the web.
This limits the application of the polymer as a flushable binder material because most areas across the U.S. have hard water, which contains more than 15 ppm Ca2+ and / or Mg2+.
However, the Lion Corporation ion-sensitive polymers of the above-referenced patents and the sulfonate anion modified acrylic acid terpolymers of the co-pending application, when used as binders for personal care products, such as wet wipes, typically have reduced initial sheet wettability, increased dry sheet stiffness, increased sheet stickiness, reduced binder sprayability and relatively high product cost.
However, because of the high viscosity of carboxymethylcellulose, which makes it difficult to apply to fibrous webs, the presence of an organic solvent, and the sensitivity to hard water, the composition of this patent has little commercial applicability.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0181]Polymers were synthesized by free radical polymerization of varying combinations of the following monomers: acrylic acid, acrylamide, butyl acrylate, 2-ethylhexyl acrylate and [2(methacryloyloxy)ethyl] trimethyl ammonium chloride (“MQUAT”). Each polymerization was conducted in methanol. A typical procedure is stated below.

[0182]Acrylamide (39.1 g, 0.55 mol), butyl acrylate (32.0 g, 0.25 mol), 2-ethylhexyl acrylate (18.4 g, 0.10 mol), and MQUAT (27.6 g of 75 wt % solution, 0.10 mol) were dissolved in 50 g of methanol. A free radical initiator, 2,2″Azobisisobutyronitrile (“AIBN”) (0.66 g, 4.0×10′ mol) was dissolved in 20 ml of methanol. The monomer solution was deoxygenated by bubbling N2 through the solution for 20 minutes. To a 1000 ml round bottom, three neck flask equipped with a condenser, two addition funnels and a magnetic stirrer was added 125 g of methanol. The solvent was heated to gentle reflux under nitrogen. Monomers and initiator were added simultaneously from the ...

example 2

Polymerization

[0201]Polymers were synthesized by free radical polymerization in the same manner as described above. MQUAT, n-butyl acrylate (BA), and 2-ethylhexyl acrylate (EHA) were utilized in ratios indicated in Table 10.

[0202]Polymer composition was characterized by 13C NMR and the compositions for each sample appear in Table 11. In most cases the polymer compositions agree with the feed ratios within a few percentage points. This would be expected for a homogeneous solution polymerization where all the monomers have a similar reactivity.

[0203]

TABLE 10Polymer Feed Ratiosmole % Feedmole % Feedmole % FeedSampleNB #MQUATBAEHA#1 (028)7421-02820.040.040.0#2 (041)7421-04115.842.142.1#3 (046)7421-045243  43.232.4#4 (064)7421-06421.739.139.1#5 (075)7421-07512,658.928.5#6 (083)7421-08320.080.00.0#7 (094)7421-09417.941.141.0#8 (100)7421-10014.542.842.7#9 (130)7421-13027.330.436.3

[0204]

TABLE 11Polymer Compositionmole % MQUATmole % BAmole % EHASampleFoundFoundFound#1 (028)19.543.437.1#2 (04...

example 3

Polymerization

[0230]Cationic triggerable polymers were synthesized by free radical polymerization in the same manner as described above. MQUAT, n-butyl acrylate (BA), and 2-ethylhexyl acrylate (EHA) were utilized in the following ratios: MQUAT 20 mole percent, BA 40 mole percent and EHA 40 mole percent. It is stable in high salt solutions, such as 4 weight percent ZnCl2, and is soluble in water when the salt concentration drops below a certain level, such as 0.5 weight percent. Because of the nature of the charge groups the polymer carries, its dispersibility is virtually unaffected by the presence of divalent cations, such as Ca2+ and Mg2+ up to 200 ppm, and, therefore, the polymer performs well even in the hardest water found in the United States households.

Wet Wipe Sample Preparation

[0231]To make a wet wipe product, the ion-sensitive cationic polymer was applied in an aqueous solution to a substrate by spraying. The substrate was a water-dispersible, wet-laid non-woven composed o...

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Abstract

The present invention is directed to triggerable, water-dispersible cationic polymers. The present invention is also directed to a method of making triggerable, water-dispersible cationic polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising triggerable, water-dispersible binder compositions and their applicability in water-dispersible personal care products, such as wet wipes.

Description

FIELD OF THE INVENTION[0001]The present invention is directed to ion-sensitive or triggerable, water-dispersible or water-soluble cationic polymers and polymer formulations. The present invention is also directed to a method of making ion-sensitive or triggerable, water-dispersible or water-soluble cationic polymers and polymer formulations and their applicability as binder compositions for disposable items. The present invention is further directed to disposable items, such as wet-wipes comprising ion-sensitive or triggerable, water-dispersible binder compositions including cationic polymer or polymer formulations.BACKGROUND OF THE INVENTION[0002]For many years, the problem of disposability has plagued industries which provide disposable items, such as, diapers, wet wipes, incontinent garments and feminine care products. While much headway has been made in addressing this problem, one of the weak links has been the inability to create an economical coherent fibrous web, which will ...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): B32B5/24C08F8/44D04H1/64
CPCD04H1/641C08F8/44Y10S428/913Y10T428/2929Y10T428/24802Y10T428/2933Y10T428/24942D04H1/587D04H1/64Y10T442/60Y10T442/2557Y10T442/20Y10T442/2164Y10T428/31504Y10T428/249962Y10T428/249964Y10T442/2369Y10T428/31855Y10T442/2787Y10T428/31935Y10T442/2779
Inventor CHANG, YIHUALANG, FREDERICK J.BRANHAM, KELLY D.MCBRIDE, ERIN
Owner KIMBERLY-CLARK WORLDWIDE INC
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