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Structure and method for lead free solder electronic package interconnections

a technology of electronic package and structure, which is applied in the direction of soldering apparatus, semiconductor/solid-state device details, manufacturing tools, etc., can solve the problems of encapsulant walls being large, chip blm becoming molten, and subsequent reflow

Inactive Publication Date: 2005-05-19
FAROOQ MUKTA G +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

"The present invention provides a lead-free solder hierarchy structure for electronic package interconnections. This structure includes an electronic circuit chip attached to a chip carrier with a first lead-free off-eutectic solder composition, an array of lead-free solder connections attached to the chip carrier with a second lead-free off-eutectic solder composition, and a printed circuit board attached to the array of lead-free solder connections with a third lead-free off-eutectic solder composition. The first solder composition has a melting temperature greater than 250°C and dispersed grains of SnAg inter-metallic phase structure. The second solder composition has a lower liquidus temperature than the first solder composition. The third solder composition has a lower liquidus temperature than the second solder composition. The invention also provides a method for creating a lead-free solder melting hierarchy for first level assembly. The technical effects of this invention are that it provides a safer and more reliable electronic package interconnection structure that eliminates the use of lead-containing solder, and reduces the risk of environmental pollution and health hazards associated with lead-containing solder."

Problems solved by technology

A current problem now facing the industry is that lead elimination is a strategic requirement for all manufacturers.
An additional problem is that in manufacturing, joining the chip to a first level package, typically a ceramic or organic chip carrier, is the first step.
Using a Pb free, Sn rich alloy for both first level chip join and second level module to board join creates the problem of the chip BLM becoming molten during the second level attach processes and subsequent reflows such as may be required for rework.
Another problem is that when the first level SnAgCu solder interconnect becomes completely molten inside the underfill encapsulant, it produces large hydrostatic stresses on the walls of the encapsulant.
These forces create strains large enough to cause delamination, cracking, rupture and finally, catastrophic fail of the encapsulant regions.
This would likely cause shorting between the C4 solder connections, and potentially cause opens where the C4 solder connections may break away from their original as-joined position.
Whereas other alloy systems such as AuSn 80 / 20 may be employed to produce a solder temperature hierarchy, such solutions may not be widely applicable because of various manufacturing problems.
Examples include the cost of the materials, brittle metallurgical properties and solder interactions which cause stress on the chip.

Method used

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  • Structure and method for lead free solder electronic package interconnections
  • Structure and method for lead free solder electronic package interconnections
  • Structure and method for lead free solder electronic package interconnections

Examples

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first embodiment

[0032] In the present invention a Sn / Ag off-eutectic lead free solder composition is provided having between about 52.0-95.0 weight % Sn and between about 48.0-5.0 weight % Ag and having inter-metallics with a melting temperature greater than 250° C. The term “inter-metallic” has its ordinary meaning of a compound with two or more metals.

[0033] In a preferred embodiment of the present invention a 72Sn / 28Ag (weight %) solder alloy is used which has a liquidus temperature of approximately 400° C. A chip join C4 reflow cycle with a peak temperature of approximately 355-375° C., with adequate dwell time typically about 1-4 minutes, will suffice to create a homogenous lead free C4 solder alloy interconnection. A homogenized solder alloy interconnection has a uniformly distributed inter-metallic phase structure.

[0034] During the subsequent second level join / assembly process, the maximum peak temperature is approximately 250° C. This temperature will create a pasty two-phase inter-metalli...

second embodiment

[0038] In the present invention a Sn / Cu off-eutectic lead free solder composition of between about 84.0-99.3 weight % Sn and between about 16.0-0.7 weight % Cu and having inter-metallics with a melting temperature greater than 250° C.

[0039] In a preferred embodiment of the present invention a 84Sn / 16Cu (in weight %) solder alloy is used which has a liquidus temperature of approximately 500° C. A chip C4 reflow cycle with a peak temperature of approximately 350-375° C., with adequate dwell time typically about 1-4 minutes, will suffice to create a homogenized C4 solder alloy interconnection. Then during the subsequent second level join / assembly process, the maximum peak temperature is approximately 250° C. This temperature will create a pasty two-phase inter-metallic structure in the C4 solder alloy interconnect, comprised of approximately 72 weight % liquid phase, and approximately 28 weight % solid phase. This alloy structure will restrict the expansion of the C4 interconnections a...

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Abstract

An electronic package having a solder interconnect liquidus temperature hierarchy to limit the extent of the melting of the C4 solder interconnect during subsequent second level join / assembly and rework operations. The solder hierarchy employs the use of off-eutectic solder alloys of Sn / Ag and Sn / Cu with a higher liquidus temperature for the C4 first level solder interconnections, and a lower liquidus temperature alloy for the second level interconnections. When the second level chip carrier to PCB join / assembly operations occur, the chip to chip carrier C4 interconnections do not melt completely. They continue to have a certain fraction of solids, and a lower fraction of liquids, than a fully molten alloy. This provides reduced expansion of the solder join and consequently lower stresses on the C4 interconnect.

Description

RELATED APPLICATIONS [0001] This application is related to subject matter described and claimed in U.S. patent application Ser. No. 10 / 246,282 (attorney docket no. FIS9-2002-0017US1) entitled “Solder Hierarchy For Lead Free Solder Joint” by the inventors of the instant application.BACKGROUND OF THE INVENTION [0002] The present invention relates to a lead free solder structure for the assembly of electronic components, and more particularly, to a lead free solder hierarchy for use in the assembly of electronic components. [0003] Current controlled collapse chip connection (C4) or “flip chipinterconnection technology for joining chips to either ceramic or organic substrates typically employ a 97 / 3 Pb / Sn joining solder alloy as the ball-limiting metallurgy (BLM) on the chip side of the interconnect, and a suitable metallization, typically Ni / Au or Cr / Cu / Ni / Au, on the substrate side of the interconnect. This interconnect structure has to withstand temperature cycling. This temperature...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B23K35/26C22C13/00H01L21/56H01L21/60H01L21/68H01L23/31H01L23/485H01L23/498H05K3/28H05K3/34
CPCB23K35/262H01L2224/11334H01L21/563H01L21/6835H01L23/3128H01L23/49816H01L23/49866H01L24/11H01L24/16H01L24/81H01L2224/11003H01L2224/13099H01L2224/16H01L2224/73203H01L2224/73253H01L2224/8121H01L2224/81815H01L2924/01004H01L2924/01027H01L2924/01029H01L2924/0103H01L2924/01033H01L2924/01046H01L2924/01047H01L2924/01049H01L2924/01051H01L2924/01078H01L2924/01079H01L2924/01082H01L2924/01322H01L2924/01327H01L2924/15311H05K3/3463H01L2924/01005H01L2924/01006H01L2924/01024H01L2924/0105H01L2924/01075H01L2924/014H01L2224/81024H01L2224/131H01L2224/13111B23K2201/40H01L2924/00014H01L2924/15787H01L2924/181H01L2224/05573H01L2224/05568H01L2224/056B23K2101/40H01L24/05H01L2924/00B23K35/26
Inventor FAROOQ, MUKTA G.INTERRANTE, MARIOSABLINSKI, WILLIAM
Owner FAROOQ MUKTA G
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