Lubricant sheet for drilling and method of drilling
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example 1
[0036] 1 part of a blue water-soluble dye (edible coloring matter blue No.1), which did not contain a halogen, was added to 35 parts of a polyethylene oxide having a molecular weight of 500,000 and 65 parts of a polyglycerin monostearate having a molecular weight of 900. These were kneaded with a kneader at 130° C. under a nitrogen gas seal for 1 hour, to obtain a mixture having a viscosity of 160,000 poise. The mixture was passed through a heating roll at 130° C. to obtain a blue-colored sheet having a thickness of 0.05 mm.
[0037] Separately, 10 parts of a saturated polyester resin having a hydroxyl group at a terminal and having a molecular weight of 20,000 and a melt-viscosity of 800 poise (at 200° C.) and 3 parts of hexamethylene diisocyanate were dissolved in a mixed solvent of toluene / methyl ethyl ketone=3 / 1, to obtain a solution having a concentration of 10% by weight. The solution was applied to one surface of a hard aluminum foil having a thickness of 100 μm and the applied...
example 2
[0038] 10 parts of polyethylene glycol as a lubricant was added to 200 parts of a polyvinylacetal resin, 400 parts of an epoxy resin and 400 parts of a phenol resin, and 2 parts of edible coloring matter Yellow No.5 as a colorant was added to the mixture to obtain a thermosetting resin composition. The thermosetting resin composition was bonded to one surface of a hard aluminum foil (surface roughness average 1.6 μm, Max. 2.7 μm) having a thickness of 100 μm, to obtain a lubricant sheet for drilling which had a resin composition layer having a thickness of 100 μm (both surfaces of the lubricant sheet were apparently distinguishable from each other). Then, two 1.6 mm-thick glass epoxy copper-clad six-layered boards were stacked. The above lubricant sheet was disposed on the top surface of the stacked boards such that the resin composition layer of the lubricant sheet faced upward, and a 1.5 mm-thick paper-base-material phenol resin laminate was disposed on the lower surface of the st...
example 3
[0046] 35 parts of a polyethylene oxide having a molecular weight of 500,000 and 65 parts of a polyglycerin monostearate having a molecular weight of 900 were kneaded with a kneader at 130° C. under a nitrogen gas seal for 1 hour, to obtain a mixture having a viscosity of 160,000 poise. The mixture was passed through a heating roll at 130° C. to obtain a sheet having a thickness of 0.05 mm.
[0047] Separately, 10 parts of a saturated polyester resin having a hydroxyl group at a terminal and having a molecular weight of 20,000 and a melt-viscosity of 800 poise (at 200° C.) and 3 parts of hexamethylene diisocyanate were dissolved in a mixed solvent of toluene / methyl ethyl ketone=3 / 1, to obtain a solution having a concentration of 10% by weight. 3 parts of a blue pigment (phthalocyanine blue) which did not contain a halogen was added to the solution, and the blue pigment was uniformly dissolved and mixed in / with the solution. The resultant solution was applied to one surface of a hard a...
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