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Efficient composite modifying-refining agent for hypoeutectic cast aluminium-silicon alloy and treatment process

An aluminum-silicon alloy and compound modification technology, which is applied in the field of modification and refinement of hypoeutectic cast aluminum-silicon alloy, can solve the problems of easy segregation, poor modification or refinement effect, serious gas absorption tendency, etc., and achieve simplified melt Treatment process, good modification and refinement effect, and performance improvement effect

Inactive Publication Date: 2007-03-28
重庆工学院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although these reported modifiers or refiners have their own advantages, there are still many problems in terms of reported research results or practical applications: some have complex manufacturing processes and are not easy to maintain; some have complex processing processes, The operation is difficult; some have a long latent period of metamorphism, serious inhalation tendency, and are prone to segregation; some are expensive and cost too high; some have poor metamorphism or refinement effect, and are prone to metamorphosis; Metamorphism or refinement; some have a single function and do not have metamorphism and refinement at the same time
It is precisely because of the above-mentioned problems that the application of these developed modifiers or refiners in hypoeutectic Al-Si alloys is limited to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] The composition (percentage by weight) of the high-efficiency compound modification refiner: 20% sodium chloride (NaCl), 12% potassium chloride (KCl), 10% sodium fluoride (NaF), 25% potassium fluoroborate (KBF 4 ), 15% Potassium Fluotitanate (K 2 TiF 6 ), 5% strontium carbonate (SrCO 3 ), 4% cerium fluoride (CeF), 5% granular lanthanum-rich mixed rare earth (rare earth content greater than 90%, lanthanum content in rare earth greater than 60%, particle size not greater than 1 mm), 4% hexachloroethane (C 2 Cl 6 ).

[0015] The production method of the high-efficiency compound modification and refinement agent: firstly, heat the raw materials in an oven to 100-150°C to remove water, and then weigh the raw materials by weight percentage; put the weighed raw materials by weight percentage into a small Mechanically mix in a sand mill; use a press to press the uniformly mixed compound modification and refinement agent into a cylindrical shape of φ45×80mm, and then seal it...

Embodiment 2

[0018] The composition (percentage by weight) of the high-efficiency compound modification refiner: 25% sodium chloride (NaCl), 10% potassium chloride (KCl), 15% sodium fluoride (NaF), 20% potassium fluoroborate (KBF 4 ), 10% Potassium Fluotitanate (K 2 TiF 6 ), 7% strontium carbonate (SrCO 3 ), 5% cerium fluoride (CeF), 5% granular lanthanum-rich mixed rare earth (rare earth content greater than 90%, lanthanum content in rare earth greater than 60%, particle size not greater than 1 mm), 3% hexachloroethane (C 2 Cl 6 ).

[0019] The production method of the high-efficiency compound modification and refinement agent: firstly, heat the raw materials in an oven to 100-150°C to remove water, and then weigh the raw materials by weight percentage; put the weighed raw materials by weight percentage into a small Mechanically mix in a sand mill; use a press to press the uniformly mixed compound modification and refinement agent into a cylindrical shape of φ45×80mm, and then seal it...

Embodiment 3

[0022] The composition (percentage by weight) of the high-efficiency compound modification refiner: 30% sodium chloride (NaCl), 10% potassium chloride (KCl), 15% sodium fluoride (NaF), 20% potassium fluoroborate (KBF 4), 5% Potassium Fluotitanate (K 2 TiF 6 ), 12% strontium carbonate (SrCO 3 ), 2% cerium fluoride (CeF), 5% granular lanthanum-rich mixed rare earth (rare earth content greater than 90%, lanthanum content in rare earth greater than 60%, particle size not greater than 1 mm), 1% hexachloroethane (C 2 Cl 6 ).

[0023] The production method of the high-efficiency compound modification and refinement agent: firstly, heat the raw materials in an oven to 100-150°C to remove water, and then weigh the raw materials by weight percentage; put the weighed raw materials by weight percentage into a small Mechanically mix in a sand mill; use a press to press the uniformly mixed compound modification and refinement agent into a cylindrical shape of φ45×80mm, and then seal it ...

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PUM

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Abstract

The invention relates to a high efficiency compounded refiner for hypoeutectic aluminum-silicon alloy and the method of application. It contains 10-30wt% NaCl, 10-15wt% KCl, 10-20wt% sodium fluoride, 1-30wt% potassium fluoborate, and 1-20wt% potassium fluotitanate, 1-20wt% strontium carbonate, 1-15wt% cerium fluoride, 5-20wt% granular lanthanum abundant mixed rare earths and 1-5% heachloroethane. After taking the process of heating, dehydrating, mixing according to the ratio to equal, pressing to molding, it could be sealed to use. The technology includes the following steps: after the magnesium alloy melting in crucible, heating to 720-740 degree centigrade and removing the slag, standing for 3-5 minutes, pressing the refiner into alloy liquid to take refining process for 5-10 minutes, standing for 5-10 minutes after process to gain hypoeutectic aluminum-silicon alloy melt. The invention simplifies melt process technology, lowers cost and improves the capability of alloy.

Description

Technical field: [0001] The invention relates to a modification and refinement technology of a hypoeutectic cast aluminum-silicon alloy. technical background: [0002] As an important part of cast Al-Si alloy materials, hypoeutectic Al-Si alloy has been widely used in aerospace, automobiles and other transportation machinery because of its excellent casting properties, good mechanical properties and physical and chemical properties. Since the mechanical properties of the hypoeutectic Al-Si alloy are closely related to the shape and size of the eutectic silicon in the alloy structure, generally speaking, the smaller the size and the rounder the shape of the eutectic silicon in the alloy structure, the higher the mechanical properties of the alloy. Considering that when the alloy is not modified, the eutectic silicon in the alloy structure mainly appears in the form of coarse needle flakes, which severely splits the matrix, resulting in a decrease in the mechanical properties ...

Claims

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Application Information

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IPC IPC(8): C22C1/06C22C21/02C22C1/02
Inventor 杨明波潘复生汤爱涛胡红军代兵
Owner 重庆工学院
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