Method of producing sodium tungstate solution using scheelite powder as raw material
A technology for the production of sodium tungstate and tungsten ore powder, applied in the direction of improving process efficiency, etc., can solve the problems of low decomposition rate of scheelite concentrate and effective utilization of resources, high requirements for corrosion resistance, and influence on smooth progress, etc. To achieve the effect of wide adaptability of raw materials, good product quality and high effective utilization rate
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Embodiment 1
[0017] This embodiment uses scheelite concentrate powder as raw material:
[0018] A. Ingredients: the particle size ≤ 45μm, which contains WO 3 : 70.61%, SiO 2 : 2.86% scheelite concentrate 1500g after pulping, add NaOH under stirring state: 566g (WO 3 1.55 times the theoretical amount), 85% of H 3 PO 4 : 358g, Al with a particle size of 74μm 2 o 3 : 20g, NaNO 3 : 15g, and the slurry density is adjusted to 1.58, and the alkalinity 105g / l makes the slurry of volume 3000ml;
[0019] B. Decomposition treatment: put the above slurry in a reaction kettle with a volume of 5000ml and a stirrer, stir and react at a speed of 100r.p.m at 165°C and a pressure of 0.6MPa for 2 hours, then cool to room temperature;
[0020] C. Filtration and separation: the above-mentioned decomposition treatment and slurry cooled to normal temperature are placed in a vacuum filter and filtered to obtain 2100mlNa 2 WO 4 solution, WO in solution 3 Content 410g / l, free NaOH42g / l, SiO 2 : 0.12g / l, ...
Embodiment 2
[0022] The present embodiment takes 1500g black and white mixed tungsten ore powder as raw material, wherein black tungsten accounts for 20%, scheelite 80% (WO 3 : 69.8%, SiO 2 : 3.1%).
[0023] A. Add WO to the slurry 3 1.45 times the theoretical amount of NaOH: 523g: 85% H 3 PO 4 : 288g, slurry density 1.60, basicity 158g / l, all the other are the same as embodiment 1, get 3000ml slurry;
[0024] B. The decomposition treatment temperature is 160°C, the pressure is 0.5MPa, and the treatment time is 2.5 hours;
[0025] C, the above-mentioned slurry is filtered with temperature and pressure into a vacuum filter to obtain 2250mlNa 2 WO 4 solution, WO in solution 3 Content 380g / l, free NaOH content 38g / l, SiO 2 Content 0.14g / l, P content 0.25g / l; drying slag weight 668g, insoluble WO in slag 3 The content is 0.35%, and the decomposition rate is 99.8%.
Embodiment 3
[0027] The present embodiment uses 1500g middle grade scheelite powder (WO 3 : 45.0%, SiO 2 : 8%) is raw material, and its process parameter is:
[0028] Add 1.5 times the theoretical amount of NaOH to the raw material slurry: 372g, 85% H 3 PO 4 : 257g, Al 2 o 3 : 75g, slurry density 1.59, alkalinity 110g / l, get 3000ml slurry, the rest and decomposition treatment etc. are all the same as
[0029] Embodiment 1 is the same;
[0030] 1850mlNa was separated by filtration 2 WO 4 Solution, the slag liquid contains WO 3 : 370g / l, P content 0.47g / l, SiO 2 Content: 0.08g / l, dry weight of filter residue after washing is 1109g, WO in residue 3 It is 0.15%, and the decomposition rate is 99.75%.
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