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Wet & heat stretching method and apparatus for acrylonitrile fibre

An acrylonitrile-based, stretching device technology, applied in the direction of fiber chemical characteristics, textiles and papermaking, single-component synthetic polymer rayon, etc., can solve the problem of low stretching processing speed and coarsening of acrylic fiber bundles , Unable to perform uniform stretching and other problems

Inactive Publication Date: 2003-11-05
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] If the thickness (number of fibers) of the acrylic fiber bundle to be processed is not as thick as it is now, and the stretching processing speed is also low, the necessary amount of thermal energy is equalized by applying steam in the above-mentioned conventional wet heat stretching device. It is still possible to give all the fibers constituting the fiber bundles, but the thickness of the acrylic fiber bundles processed in recent years has greatly increased. In the end, it is impossible to perform a uniform treatment
This means not being able to adapt to the need to increase production speed
[0005] That is to say, if the conventional wet heat stretching device is used to obtain a necessary draw ratio at the same stretching speed, the entire constituent fibers of the acrylic fiber bundle cannot generally obtain equal heat, but heat Unevenness, not only can not be stretched uniformly, but also fiber breakage often occurs, which greatly reduces productivity

Method used

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  • Wet & heat stretching method and apparatus for acrylonitrile fibre
  • Wet & heat stretching method and apparatus for acrylonitrile fibre
  • Wet & heat stretching method and apparatus for acrylonitrile fibre

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~28

[0055] (Examples 1-28, Comparative Examples 1-8)

[0056] An acrylonitrile-based copolymer with a reduced viscosity of 1.95 (acrylonitrile / vinyl acetate=93 / 7 weight ratio) was obtained by aqueous suspension polymerization. This was dissolved in dimethylacetamide so that the copolymer concentration was 25% by weight to prepare a spinning dope. This spinning dope was wet-spun in a spinning bath filled with a 40°C, 30% by weight aqueous solution of dimethylacetamide, and stretched once at a draw ratio of 5 times while washing the solvent in boiling water. . The drawn yarn having a swelling property of 80% after the first stretching was taken out and then dehydrated, and then neutralized (pH 8.3) in a 0.1% by weight sodium hydroxide aqueous solution.

[0057] Then, excess sodium hydroxide was washed to remove adhering oil agent, and then dried and densified with a hot roll at 150°C. Next, relaxation heat treatment was performed in pressurized steam of 250 kPaG to obtain an acry...

Embodiment 29~56 and comparative example 9~16

[0066] Except using the above-mentioned wet heat stretching device with the number of ejection ports changed as shown in Table 2, and supplying the acrylic fiber bundle after the relaxation heat treatment obtained by the same method as in Example 1 at a speed of 150 m / sec, the same method as in Example 1 was used. 1 Stretching was carried out under the same treatment conditions under different steam atmospheres with different steam injection states, to obtain acrylic fiber bundles having various steam shrinkage ratios in Examples 29 to 56 and Comparative Examples 9 to 16 shown in Table 2. Among them, the steam shrinkage rate of the obtained acrylic fiber bundle was measured 30 times, and the average shrinkage rate is shown in Table 2.

[0067] Acrylic fiber

total fineness of dimension

(kTex)

processing speed

(m / min)

For 1kg acrylonitrile

Steam volume of fiber bundle

(g)

Injection caliber

(mm)

Number of jets

Ejec...

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Abstract

The present invention provides a wet heat stretching method and a wet heat stretching device for acrylonitrile fiber bundles, which can improve productivity and can stably obtain high-quality acrylonitrile fiber bundles as raw materials for high-bulk products. In the present invention, in the wet heat stretching process of continuously stretching the acrylic fiber after the relaxation heat treatment in a humid heat atmosphere, the stretched 1kg acrylic fiber bundle is sprayed at a speed of 10 to 30m / s. Spray 50-200g of steam. At this time, the distance between the ejection port and the ejection surface of the acrylic fiber bundle was 8 to 22 mm, and the injection steam was ejected from a plurality of atmospheric pressure steam ejection ports (22a) with a diameter of 1.0 to 3.0 mm. Regardless of the thickness, even if the drawing treatment speed is high, moist heat can be applied uniformly to the entire fiber bundle, and high-quality acrylic fibers having a desired high steam shrinkage rate can be obtained.

Description

technical field [0001] The present invention relates to a wet heat stretching method and a stretching device for imparting a necessary heat shrinkage rate to acrylic fiber bundles subjected to relaxation heat treatment, and particularly relates to a method capable of imparting uniform heat energy to acrylonitrile fiber bundles in a hot and humid atmosphere and realizing The invention relates to a wet heat stretching method and a stretching device thereof with increased stretching speed. Background technique [0002] Usually, wet-spun acrylic fiber bundles are stretched once at a draw ratio of 4 to 5 times in a high-temperature washing solution in a desolventizing process, and then undergo a drying process for relaxation heat treatment (slow cooling). In order to impart high bulkiness to the final acrylic fiber product, low stretching of about 1.1 to 2 times is performed in a humid heat atmosphere after relaxation heat treatment. Usually, the wet heat stretching of this seco...

Claims

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Application Information

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IPC IPC(8): D02J1/22D01F6/18
Inventor 中村辉男能村素郎
Owner MITSUBISHI CHEM CORP
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