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Cementing and blocking type wall fixing agent for water-based drilling fluid as well as preparation method and application of cementing and blocking type wall fixing agent

A technology of water-based drilling fluid and wall-fixing agent, applied in chemical instruments and methods, drilling compositions, fibrous fillers, etc., can solve problems such as high drilling and completion costs, stuck drilling, and well wall collapse. , to achieve the effect of stabilizing the fractured formation well wall, enhancing the rock strength, and enhancing the temperature resistance.

Active Publication Date: 2022-07-08
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Micro-fractures and fractures are developed in destructive formations. During drilling, water-based drilling fluid easily enters deep formations along the pores and fractures, causing serious wellbore collapse and pipe sticking accidents, resulting in longer drilling cycle and high drilling and completion costs
The existing treatment technology is mainly to add plugging agent to plug the fractured formation pores and fractures: asphalt type plugging agent requires its softening point to match the formation temperature, and the plugging strength is insufficient; calcium carbonate type plugging agent has high plugging strength, However, its shape and size are difficult to accurately match the formation pores and fractures, and cannot be effectively plugged; polymer microsphere plugging agents can effectively match the formation pores and fractures shape and size, but the plugging strength is not high
[0003] In recent years, chemical cementing wall-solidifying agents have gradually become a research hotspot for stabilizing fractured formation well walls. Carboxymethyl shells grafted with dopamine groups on the main chain Polysaccharides (CN104177517A, CN106634878A), polymers grafted with dopamine groups on the main chain (CN109679598A, CN108456286 A) can cement formation pores, but their temperature resistance and plugging strength are insufficient; epoxy resins (CN107502322A) It can effectively cement formation pores and fractures, but its compatibility with drilling fluid is poor

Method used

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  • Cementing and blocking type wall fixing agent for water-based drilling fluid as well as preparation method and application of cementing and blocking type wall fixing agent
  • Cementing and blocking type wall fixing agent for water-based drilling fluid as well as preparation method and application of cementing and blocking type wall fixing agent
  • Cementing and blocking type wall fixing agent for water-based drilling fluid as well as preparation method and application of cementing and blocking type wall fixing agent

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0033] (1) Preparation of modified silica: disperse nano-silica in absolute ethanol to obtain dispersion system A, disperse γ-(methacryloyloxy)propyltrimethoxysilane (KH570) in water / absolute ethanol system, obtain dispersion system B, then mix the dispersion system A and the dispersion system B and adjust the pH value to 8-9, then add phenothiazine to react, after the reaction, filter and The obtained product is washed and dried to obtain modified silica;

[0034] (2) The modified silica, acrylamide, acrylic acid, sodium p-styrene sulfonate, dimethyl diallyl ammonium chloride, 1-ethyl-(3-dimethyl ammonium chloride) prepared in step (1) (base aminopropyl) carbodiimide, dopamine hydrochloride and water are mixed, and under stirring and heating conditions, a protective gas is introduced to remove oxygen, and then an initiator is added to react;

[0035] (3) After the reaction is completed, the product obtained in the step (2) is washed, dried and pulverized to obtain a cement...

Embodiment 1

[0069] Take 2.5g modified silica, 15g acrylamide, 3.5g acrylic acid, 1.5g sodium p-styrene sulfonate, 2.5g dimethyl diallyl ammonium chloride, 0.2g 1-ethyl-(3-di Methylaminopropyl) carbodiimide and 5g of dopamine hydrochloride were added to the flask containing 150g of water, respectively, and stirred until fully dispersed; the flask was heated to 60°C in a water bath, kept stirring and heated, and deoxygenated with nitrogen for 30 minutes; Add 0.35g of V50 to the flask and maintain the reaction for 4h; after the reaction, the viscous product is taken out, washed with acetone for 3 times, dried and pulverized to obtain the wall solidifying agent A1.

Embodiment 2

[0071] Take 2.5g modified silica, 16g acrylamide, 3g acrylic acid, 1.8g sodium p-styrene sulfonate, 3g dimethyl diallyl ammonium chloride, 0.3g 1-ethyl-(3-dimethyl Aminopropyl) carbodiimide and 3.5 g of dopamine hydrochloride were added to the flask containing 160 g of water, and stirred until fully dispersed; the flask was heated to 65°C in a water bath, kept stirring and heated, and deoxygenated with nitrogen for 30 minutes; Add 0.3g of V50 to the medium, and maintain the reaction for 5h; after the reaction, take out the viscous product, wash it with acetone for 3 times, dry and pulverize it, it is the wall-fixing agent A2.

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Abstract

The invention relates to the technical field of well drilling, and discloses a cementing plugging type wall fixing agent as well as a preparation method and application thereof. The method comprises the following steps: (1) preparing a dispersion system A from nano silicon dioxide, preparing a dispersion system B from gamma-(methacryloyloxy) propyltrimethoxysilane, mixing the dispersion system A and the dispersion system B, adjusting the pH value to 8-9, adding phenothiazine for reaction, filtering after the reaction is finished, and washing and drying a product; (2) mixing the modified silicon dioxide prepared in the step (1), acrylamide, acrylic acid, sodium p-styrenesulfonate, dimethyl diallyl ammonium chloride, 1-ethyl-(3-dimethylaminopropyl) carbodiimide, dopamine hydrochloride and water, introducing protective gas to remove oxygen, and adding an initiator to react; and (3) washing, drying and crushing the product obtained in the step (2) to obtain the wall fixing agent. The wall fixing agent disclosed by the invention is beneficial to maintaining and even enhancing rock strength, so that an effect of stabilizing a fractured formation well wall is achieved.

Description

technical field [0001] The invention relates to the technical field of drilling, in particular to a cementing and plugging-type wall solidifying agent for water-based drilling fluids and a preparation method and application thereof. Background technique [0002] Micro-fractures and fractures are developed in the fractured formation. During the drilling process, the water-based drilling fluid is easy to enter the deep formation along the pores and fractures, causing serious accidents such as wellbore collapse and pipe sticking, resulting in a long drilling cycle and high drilling and completion costs. No less. The existing treatment technology is mainly to add a plugging agent to plug the fractured formation pores and fractures: the asphalt plugging agent requires its softening point to match the formation temperature, and the plugging strength is insufficient; the calcium carbonate plugging agent has high plugging strength, However, its shape and size are difficult to accur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/03C09K8/24C09K8/508C09C1/30C09C3/12C08F220/56C08F220/06C08F212/14C08F226/02
CPCC09K8/03C09K8/24C09K8/5083C09C1/3081C09C3/12C08F220/56C08F220/06C08F212/30C08F226/02C04B14/062C09K8/426C09K8/467C09K8/18C09K8/5045C09K8/508C04B20/1051C09K2109/00
Inventor 刘敬平张泰丰孙金声吕开河王宗轮张宪法黎剑黄贤斌王金堂白英睿金家锋
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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