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Multifunctional reversed-phase suspension resistance reducing agent system for shale gas factory-like sand fracturing fluid

A technology of sand fracturing and reverse suspension, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problem of not having the performance of drainage aid, anti-swelling, etc., increasing the construction process and production cost, and drag-reducing agent Solve the problems of long dissolution and dispersion time, and achieve the effects of short dissolution and dispersion time, fast dispersion and dissolution time, and fast sticking time

Pending Publication Date: 2022-07-01
四川川庆井下科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, most of the drag reducers commonly used in China are prepared by dispersion polymerization, which is produced by the copolymerization of one or more different monomers such as polyacrylamide. During construction, it is necessary to pump additional drainage aid and anti-swelling agent through the sand mixer, which increases the construction process and production cost
[0005] Moreover, the commonly used drag reducing agents in China have a long dissolution and dispersion time in water, and slow viscous time. When the addition amount is 0.1%, the kinematic viscosity is 1-1.65mm2 / s, the viscosity is low, and the drag reduction rate is generally 65%~ Between 70%, the effect of reducing friction can not be achieved in the on-site sand fracturing operation, resulting in high construction pump pressure and increasing construction safety risks

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A multifunctional reversed-phase suspension drag-reducing agent system for shale gas industrialized sand fracturing fluid, the components of which are as follows: 12 parts of an oil phase, 20 parts of a water-soluble monomer, 6 parts of a suspending agent, and 6 parts of a surface active agent. Agent A is 6 parts, surfactant B is 12 parts, drainage aid is 1 part, anti-swelling agent is 1 part, initiator is 0.01 part, and water is 20 parts;

[0041] Among them, the drainage aid is organic fluorocarbon; the anti-swelling agent is hexamethylenetetramine ammonium chloride; the surfactant A is nonylphenol polyoxyethylene ether; and the surfactant B is octylaryl polyoxyethylene ether.

[0042] The compounding of nonylphenol polyoxyethylene ether and octylaryl polyoxyethylene ether can produce a synergistic effect, and after compounding, the temperature and salt resistance performance of the organic fluorocarbon of the drainage aid is improved.

[0043] Further, the water-solu...

Embodiment 2

[0056] A multifunctional reversed-phase suspension drag-reducing agent system for shale gas industrialized sanding and fracturing fluid, the components of which are as follows: 13 parts of oil phase, 23 parts of water-soluble monomer, 7 parts of suspending agent, surface The active agent A is 9 parts, the surfactant B is 15 parts, the drainage aid is 1.3 parts, the anti-swelling agent is 1.3 parts, the initiator is 0.02 parts, and the water is 19 parts.

[0057] The drainage aid is organic fluorocarbon;

[0058] Anti-swelling agent is hexamethylenetetramine ammonium chloride;

[0059] Surfactant A is 4.5 parts of Span 80 and 4.5 parts of Tween;

[0060] Surfactant B is 7 parts of octyl aryl polyoxyethylene ether and 8 parts of 12-hydroxystearic acid-polyoxyethylene ether.

[0061] Further, the water-soluble monomer is 2-methacrylamido propanesulfonic acid;

[0062] The oil phase is kerosene;

[0063] The suspending agent is bentonite;

[0064] The initiators were 0.01 par...

Embodiment 3

[0076] A multifunctional reversed-phase suspension drag-reducing agent system for shale gas industrialized sand-adding fracturing fluid, the components of which are as follows: 14 parts of oil phase, 24 parts of water-soluble monomer, 8 parts of suspending agent, and 8 parts of surface active agent. Agent A is 9 parts, surfactant B is 18 parts, drainage aid is 1.4 parts and 1.4 parts, anti-swelling agent is 1.4 parts, initiator is 0.025 parts, and water is 19 parts.

[0077] The drainage aid is organic fluorocarbon;

[0078] Anti-swelling agent is hexamethylenetetramine ammonium chloride;

[0079] Surfactant A is 5 parts of nonylphenol polyoxyethylene ether and 4 parts of Tween;

[0080] Surfactant B is 9 parts of octyl aryl polyoxyethylene ether and 9 parts of 12-hydroxystearic acid-polyoxyethylene ether.

[0081] Further, the water-soluble monomer is sodium acrylate;

[0082] The oil phase is biodiesel;

[0083] The suspending agent is bentonite;

[0084] The initiator ...

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Abstract

The invention relates to the technical field of resistance reducing agents, and discloses a multifunctional reversed-phase suspension resistance reducing agent system for shale gas factory-like sand fracturing fluid, which comprises an oil phase, a water-soluble monomer, a suspending agent, an initiator, a surfactant A, a surfactant B, a cleanup additive, an anti-swelling agent and clear water, the surfactant A is one or a composition of more of nonylphenol polyoxyethylene ether, span 80 and Tween; the surfactant B is one or a composition of more of alkylaryl polyoxyethylene ether and 12-hydroxystearic acid-polyoxyethylene ether; the surfactant B is one or a composition of more of alkylaryl polyoxyethylene ether and 12-hydroxystearic acid-polyoxyethylene ether; the discharge aiding agent is organic fluorocarbon; the anti-swelling agent is hexamethylenetetramine ammonium chloride. The scheme has the beneficial effects that the resistance reducing agent prepared by adopting a reversed-phase suspension polymerization method is quick in dispersion and dissolution time in water, high in viscosity and low in friction resistance, and can effectively reduce the friction resistance of fracturing construction, reduce the pumping pressure of construction and reduce the safety risk of construction at the same time; the system has discharge aiding and anti-swelling performance, and a discharge aiding agent and an anti-swelling agent do not need to be additionally pumped through a fracturing blender truck during construction.

Description

technical field [0001] The invention relates to the technical field of drag-reducing agents, in particular to a multifunctional reversed-phase suspension drag-reducing agent system for shale gas industrialized sand fracturing fluid. Background technique [0002] As an important unconventional natural gas resource, shale gas development has developed rapidly in my country in recent years, attracting extensive attention from all walks of life. [0003] In the process of shale gas exploitation, it is necessary to reform the reservoir volume by fracturing to generate complex fracture network diversion, thereby improving the recovery rate. The shale gas reserves in the Sichuan-Chongqing region are very rich. At present, the shale gas in the Sichuan-Chongqing region has entered the stage of large-scale exploration and development, and the shale gas slick water and sand fracturing reservoir reconstruction is the current shale gas in the Sichuan-Chongqing region. An important means...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68C09K8/88C08F2/32C08F120/06C08F120/56C08F120/58
CPCC09K8/68C09K8/882C08F2/32C08F120/56C08F120/58C08F120/06C09K2208/12
Inventor 吴安林王鹏祥李嘉孙亚东张晓虎吴越于世虎周怡张祥枫陈星宇
Owner 四川川庆井下科技有限公司
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