Monoamine organic compound simultaneously containing pyrenyl and benzoxazolyl or benzothiazolyl and application thereof
An organic compound and benzoxazole-based technology, which is applied in the field of OLED devices as a covering layer, can solve the problems of device black spots, limited improvement of device luminous efficiency, low light extraction efficiency, etc., achieve high glass transition temperature, improve Effects of light extraction efficiency and high visible light refractive index
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[0120] The present invention will be specifically described below in conjunction with the accompanying drawings and embodiments.
[0121] Synthesis Examples All raw materials and solvents were purchased from CECEP Wanrun Co., Ltd., Sinopharm Chemical Reagent Co., Ltd., Tokyo Chemical Industry Co., Ltd., and the solvents were used directly without further treatment.
[0122] I. the preparation of general formula (1) compound
[0123] 1. Synthesis of Intermediate B-1:
[0124]
[0125] In a 500ml three-neck flask, under the protection of nitrogen, add 0.012mol raw material I-1, 0.010mol raw material II-1, 150ml toluene and stir to mix, then add 5×10 -5 molPd 2 (dba) 3 , 5×10 -5 mol P(t-Bu) 3 , 0.03mol sodium tert-butoxide, heated to 105°C, reacted for 24 hours, took a sample point plate, showed no bromide remaining, and the reaction was complete; naturally cooled to room temperature, filtered, the filtrate was rotary evaporated to no fraction, passed through a neutral ...
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