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Gold catalyst as well as preparation method and application thereof

A gold catalyst and reaction technology, which is applied in the field of gold catalyst and its preparation, can solve the problems of raw material waste and waste gas, secondary pollution of waste gas, complex treatment process, etc., achieve reduction of waste gas and waste water generation, high raw material utilization rate, and simple preparation method Effect

Pending Publication Date: 2022-03-01
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, the disadvantage of the deposition-precipitation method is that the conditions are not easy to control, and the reproducibility is often poor. A considerable part of the gold nucleates and grows in the solution instead of depositing on the surface of the carrier. The deposition-precipitation method generally requires roasting the sample under a certain atmosphere and temperature. , or after reduction treatment, the catalyst can be activated. The treatment process is relatively complicated, and the deposition and precipitation method has the problems of waste of raw materials, waste water and waste gas generated by high-temperature roasting and other secondary pollution problems.
[0009] The currently commonly used catalyst that can efficiently remove formaldehyde and CO at room temperature is a platinum catalyst. For example, CN112371121A discloses a catalyst for eliminating formaldehyde and carbon monoxide at room temperature and a preparation method thereof. The catalyst uses platinum-based noble metals as active components. The manganese-potassium-type octahedral molecular sieve is used as a carrier to load the platinum-based noble metal active components on the manganese-potassium-type octahedral molecular sieve carrier; however, the cost of the catalyst is high, and the preparation method requires high-temperature roasting and reduction pretreatment, and the process is cumbersome And there is secondary pollution such as exhaust gas

Method used

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  • Gold catalyst as well as preparation method and application thereof
  • Gold catalyst as well as preparation method and application thereof
  • Gold catalyst as well as preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0044] This embodiment provides a gold catalyst and a preparation method thereof, the preparation method comprising the following steps:

[0045] (1) the chloroauric acid solution is adjusted to an end point pH of 10 by pH to obtain an alkaline gold solution;

[0046] (2) CeO 2 After the carrier is mixed with the alkaline gold solution described in step (1), the pH is 10 and 25° C. for standing reaction for 18 days to obtain the supernatant and the gold catalyst; the obtained gold catalyst is dried at 60° C. for 4 hours; the obtained supernatant Liquid circulation is reused to step (1) as chloroauric acid solution;

[0047] Among them, CeO 2 The mass ratio of the carrier to the chloroauric acid in the chloroauric acid solution described in step (1) is 1:0.05.

[0048] The gold catalyst obtained in this embodiment is tested for the removal rate of formaldehyde and carbon monoxide, and the test method is as follows:

[0049] Put 50mg gold catalyst in the fixed-bed quartz flo...

Embodiment 2

[0055] This embodiment provides a gold catalyst and a preparation method thereof, the preparation method comprising the following steps:

[0056] (1) the chloroauric acid solution is adjusted to an end point pH of 9 through pH adjustment to obtain an alkaline gold solution;

[0057] (2) TiO 2 After the carrier is mixed with the alkaline gold solution described in step (1), the reaction is left to stand at pH 9 and 30°C for 14 days to obtain the supernatant and the gold catalyst; the obtained gold catalyst is dried at 40°C for 8 hours; the obtained supernatant Liquid circulation is reused to step (1) as chloroauric acid solution;

[0058] Among them, TiO 2 The mass ratio of the carrier to the chloroauric acid in the chloroauric acid solution described in step (1) is 1:0.0002.

Embodiment 3

[0060] This embodiment provides a gold catalyst and a preparation method thereof, the preparation method comprising the following steps:

[0061] (1) the chloroauric acid solution is adjusted to an end point pH of 11 by pH to obtain an alkaline gold solution;

[0062] (2) Al 2 o 3 After the carrier is mixed with the alkaline gold solution described in step (1), the reaction is left to stand at pH 8 and 20°C for 20 days to obtain the supernatant and the gold catalyst; the obtained gold catalyst is dried at 50°C for 6 hours; the obtained supernatant Liquid circulation is reused to step (1) as chloroauric acid solution;

[0063] Among them, Al 2 o 3 The mass ratio of the carrier to the chloroauric acid in the chloroauric acid solution described in step (1) is 1:0.1.

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Abstract

According to the gold catalyst and the preparation method and application thereof, heating, repeated washing and roasting are omitted, a deposition-precipitation method is improved for preparing the supported gold catalyst, the obtained gold catalyst has excellent formaldehyde and carbon monoxide oxidation performance, and the preparation method is simple, high in repeatability and suitable for industrial production. Reaction conditions are mild, heating reaction, high-temperature roasting and repeated washing are not needed, the preparation cost is low, the raw material utilization rate is high, and waste gas and waste water are reduced.

Description

technical field [0001] The invention belongs to the technical field of catalyst preparation, and in particular relates to a gold catalyst and its preparation method and application. Background technique [0002] Both formaldehyde and carbon monoxide are the main indoor air pollutants, which have serious harm to the human body. The main hazard of formaldehyde is the irritation to the skin and mucous membranes. When formaldehyde reaches a certain concentration indoors, people will feel uncomfortable, which is greater than 0.08mg / m 3 High formaldehyde concentrations can cause red eyes, itchy eyes, throat discomfort or pain, hoarseness, sneezing, chest tightness, wheezing, dermatitis, etc. Carbon monoxide is a highly toxic pollutant to the blood and nervous system. Carbon monoxide in the air enters the human blood through the respiratory system and combines with hemoglobin in the blood to form a reversible conjugate. The combination of carbon monoxide and hemoglobin not only r...

Claims

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Application Information

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IPC IPC(8): B01J23/66B01J23/52B01D53/86B01D53/62B01D53/72
CPCB01J23/66B01J23/52B01D53/8668B01D53/864Y02A50/20
Inventor 张长斌秦晓晓陈敏陈学燕张江浩
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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