A preparation method of thin undenatured skin collagen sheet material

A sheet material and leather collagen technology, applied in small raw hide/big raw hide/leather/fur treatment, small raw hide/big raw hide/leather skin/fur chemical treatment, leather impregnation, etc. Limited precision, difficult to achieve the thinness of the skin, etc., to achieve the effect of uniform product thickness, wide range of uses, and strong implementability

Active Publication Date: 2022-04-05
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The multi-layer sheet material obtained by peeling can be processed and sold in different degrees, and the debris generated by shaving is difficult to produce economic benefits. However, the precision of peeling processing is limited, and very thin skin collagen sheets cannot be obtained. Although the processing precision is high and the thickness of the product can be very low, the shaving process will generate high temperature. In order to prevent shaving and collagen denaturation, it is often necessary to tan the hide to make it have a higher Only when the shrinkage temperature is higher can the skin collagen sheet material with a thinner thickness be obtained. Although the hides treated by pickling or tanning can also be shaved, but the thickness of the product is thick, it is difficult to achieve the level achieved by shaved and tanned hides. Thinness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Adjust the thickness of the depilated and limed cattle head layer hide to 0.8mm with a peeling machine, and adjust the pH value of the bare hide to 7.5 with ammonium sulfate and ammonium chloride according to the deliming method of conventional tanning processing; adjust the peeling machine Add 0.2% of the weight of potassium hydroxide to the skin at one time after the thickness, and carry out swelling treatment for 2 hours after adding, until the skin is uniformly expanded to translucent; put the expanded skin into 300% of its own weight in ethylene glycol ether After immersing in medium for 60 minutes, replace the dehydrating agent. During the dehydration process, the bare hide is soaked in ethylene glycol ether for 4 times until the moisture content (by mass fraction) in the dehydrating agent is 3.0%. Squeeze the water squeezer to remove excess ethylene glycol ether, the pressure of the through-type water squeezer is 0.7MPa, and the running speed is 8m / min. Then use ...

Embodiment 2

[0018] Adjust the thickness of the goat skin after depilation and liming to 1.4mm with a skinning machine, and adjust the pH value of the bare skin to 8.5 with an ammonia-free deliming agent according to the deliming method of conventional tanning processing; adjust the thickness of the skinning machine Add 0.4% sodium hydroxide of the weight of the bare skin in 2 times with an interval of 120 minutes. After adding, expand the skin for 4 hours until the skin is evenly expanded to translucent; put the expanded skin into acetone with 300% of its own weight. After soaking for 120 minutes, replace the dehydrating agent. During the dehydration treatment process, the bare hide is soaked in acetone for 3 times until the moisture content (by mass fraction) in the dehydrating agent reaches 2.8%. Squeeze to remove excess acetone, the pressure of the through-type water squeezer is 0.4MPa, and the running speed is 3m / min. Then use a shaving machine to shave evenly to obtain a thin undenat...

Embodiment 3

[0020] Adjust the thickness of the depilated and limed pig head layer skin to 0.8mm with a skinning machine, and adjust the pH value of the bare hide to 8.0 with ammonium sulfate and formic acid according to the deliming method of conventional tanning processing; after adjusting the thickness of the skinning machine Sodium hydroxide of 0.6% of the weight of the bare hide is added in 3 times at an interval of 60 minutes, and the expansion treatment is carried out for 6 hours after adding, until the bare hide is uniformly expanded to translucent; the expanded bare hide is put into 300% of its own weight in methanol After soaking for 90 minutes, replace the dehydrating agent. During the dehydration treatment process, the bare hide is soaked in methanol for 5 times until the moisture content (by mass fraction) in the dehydrating agent reaches 2.4%. Press to remove excess methanol, the pressure of the water squeezer is 0.6MPa, and the running speed is 4m / min. Then use a shaving mac...

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Abstract

A method for preparing a thin undenatured leather collagen sheet material, characterized in that the thickness of the bare hide after depilation and liming is first adjusted with a peeling machine, then delimed according to the conventional deliming method for leather processing, and then used with a swelling agent Treat until the bare skin swells evenly to a translucent state; after the swelling is completed, soak it in a dehydrating agent for at least 30 minutes and then replace the dehydrating agent. During the dehydrating treatment, soak it in the dehydrating agent for 3-6 times; Squeeze with a water machine, and then smooth it with a smoother to obtain a thin skin collagen sheet material with a thickness of 0.3-0.5mm. In this method, the dehydrating agent is used to dehydrate the naked skin in the state of swelling, so that the collagen fiber bundles are dispersed and the porous structure is maintained, and the volatile characteristics of the dehydrating agent are used to prevent the thermal denaturation of the skin during the shaving process, and untanned undenatured thin skin collagen can be obtained Protein flake material. The product retains the natural structure of collagen in the leather block, and can be used not only in leather processing, but also in the fields of biomedicine and food.

Description

technical field [0001] The invention belongs to the technical fields of leather chemistry and engineering and film processing, and in particular relates to a preparation method of a thin leather collagen sheet material which maintains the triple helix structure of skin collagen and is not tanned by a tanning agent. Background technique [0002] In the process of tanning and flaky collagen processing, the thickness adjustment directly affects the range of product use, and also directly affects the economic benefits of the production enterprise. At present, the thickness adjustment in the processing of tanning and flaky collagen materials mainly includes two operations of slicing and shaving. The slicing is to use a sharp belt knife to cut the skin into the required thickness, and at the same time obtain multi-layer sheet materials. Shaving is to use a sharp spiral knife to cut the hide to obtain a layer of flake material with a specific thickness, and the excess part is disca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C14B1/58C14C9/00C14C11/00
CPCC14B1/58C14C9/00C14C11/00
Inventor 张金伟
Owner SICHUAN UNIV
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