Bio-based flame-retardant polyether polyol and preparation method thereof
A flame-retardant polyether and polyol technology, applied in the field of bio-based flame-retardant polyether polyol and its preparation, can solve the problems of easy dissociation, poor combination of bio-based materials and polyols, and reduced flame-retardant performance question
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Embodiment 1
[0026] The invention provides a bio-based flame-retardant polyether polyol, which comprises: 9.20% of ethylene glycol, 18.40% of diethylene glycol, 18.40% of propylene glycol, 9.20% of dipropylene glycol, 18.40% of Butanediol, 0.45% nano magnesium hydroxide, 0.32% nano cerium oxide, 0.25% nano tin antimony oxide, and the rest is corn starch;
[0027] The weight of the ethylene glycol, the diethylene glycol, the propylene glycol, the dipropylene glycol and the butanediol is in a ratio of 1:2:2:1:2;
[0028] The present invention also provides a preparation method of bio-based flame-retardant polyether polyol, the specific preparation steps are as follows:
[0029] Step 1: weighing ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, butanediol, nano magnesium hydroxide, nano cerium oxide, nano tin antimony oxide and cornstarch according to the above weight percentage;
[0030] Step 2: Mix 1 / 2 weight portion of nano-magnesium hydroxide in step 1 with 1 / 4 we...
Embodiment 2
[0038] Different from Example 1, it includes: 10.30% ethylene glycol, 20.60% diethylene glycol, 20.60% propylene glycol, 10.30% dipropylene glycol, 20.60% butanediol, 0.75% Nano magnesium hydroxide, 0.42% nano cerium oxide, 0.39% nano tin antimony oxide, and the rest are corn starch.
Embodiment 3
[0040] All different from Examples 1-2, it includes: 9.75% ethylene glycol, 19.50% diethylene glycol, 19.50% propylene glycol, 9.75% dipropylene glycol, 19.50% butanediol, 0.60% nano magnesium hydroxide, 0.37% nano cerium oxide, 0.32% nano tin antimony oxide, and the rest is corn starch.
[0041] Take the bio-based flame-retardant polyether polyol prepared in the above-mentioned Examples 1-3 and the bio-based flame-retardant polyether polyol of the control group 1, the bio-based flame-retardant polyether polyol of the control group 2, and the bio-based flame-retardant polyether polyol of the control group 3 respectively. The bio-based flame-retardant polyether polyol and the bio-based flame-retardant polyether polyol of the control group 4 were tested, and the bio-based flame-retardant polyether polyol of the control group 1 was a common bio-based flame-retardant polyether polyol on the market , the bio-based flame-retardant polyether polyol of the control group two is compare...
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