Iron-cobalt-nickel-manganese-copper high-entropy cast iron and preparation method and application thereof
An iron-cobalt-nickel, high-entropy technology, used in additive processing and other directions, can solve the problems of insufficient plasticity, insufficient strength, and high plasticity of high-entropy alloys, and achieve the effects of reducing solidification temperature, reducing shrinkage, and facilitating production
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[0024] A preparation method of iron-cobalt-nickel-manganese-copper high-entropy cast iron, comprising the following steps:
[0025] Step 1, weighing raw materials according to the molar ratio of each element in the alloy component of the iron-cobalt-nickel-manganese-copper high-entropy cast iron;
[0026] Step 2, put the raw materials into an induction melting furnace, pass in an inert gas or add a covering agent to prevent oxidation during melting, and obtain the iron-cobalt-nickel-manganese-copper high-entropy cast iron through melting.
[0027] Among them, high-entropy cast iron is obtained by adjusting the distribution state of carbon element in the raw material to control its microstructure. The distribution state of carbon element refers to the form in which carbon element is distributed in the cast iron structure. If the carbon is distributed in a spherical shape, high-entropy nodular cast iron is obtained. , if the carbon element is distributed in sheets, high-entropy ...
Embodiment 1
[0031] The alloy of the iron-cobalt-nickel-manganese-copper high-entropy cast iron of the present embodiment becomes Fe a co b Ni c mn d Cu e C f x g , where a=22.98, b=19.155%, c=19.155%, d=19.155%, e=19.155%, f=0.4% and g=0%, namely Fe 1.2 CoNiMnCuC 0.4 .
[0032] The preparation method of the iron-cobalt-nickel-manganese-copper high-entropy cast iron of this embodiment is as follows: pre-treat the high-purity raw materials to reduce the content of harmful impurities; weigh the raw materials according to the molar ratio of each element; put the raw materials into an induction melting furnace, During smelting, an inert gas is introduced or a covering agent is added to prevent oxidation. After smelting, a 50g ingot is obtained, in which graphite exists in a high-entropy matrix in the form of nodular graphite.
[0033] In this example, high-entropy ductile iron was obtained by adjusting the content of each principal component.
Embodiment 2
[0035] The alloy of the iron-cobalt-nickel-manganese-copper high-entropy cast iron of the present embodiment becomes Fe a co b Ni c mn d Cu e C f x g , where X is Mo, a=19.888%, b=19.888%, c=19.888%, d=19.888%, e=19.888%, f=0.36% and g=0.2%, namely FeCoNiMnCuC 0.36 Mo 0.2 .
[0036] The preparation method of the iron-cobalt-nickel-manganese-copper high-entropy cast iron of this embodiment is as follows: pre-treat the high-purity raw materials to reduce the content of harmful impurities; weigh the raw materials according to the molar ratio of each element; put the raw materials into an induction melting furnace, During smelting, an inert gas is introduced or a covering agent is added to prevent oxidation. After smelting, a 50g ingot is obtained, in which graphite exists in a high-entropy matrix in the form of nodular graphite.
[0037] In this example, high-entropy ductile iron was obtained by adjusting the content of each principal component.
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