A preparation method of multi-scale high-strength high-entropy alloy material for corrosive environment

A high-entropy alloy and corrosive environment technology, applied in the field of metal composite materials, can solve the problems of long period of high-entropy alloy powder and reduce the corrosion resistance of high-entropy alloy, so as to achieve the effect of short preparation period, improved mechanical strength, and improved strength

Active Publication Date: 2021-06-25
西安稀有金属材料研究院有限公司 +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method sinters multi-scale high-entropy alloy powders with homogeneous and different average particle sizes to obtain multi-scale high-strength high-entropy alloy materials, which solves the problem of long cycle time for mechanical alloying to prepare high-entropy alloy powders, and reduces impurities in the preparation process. The pollution of the powder is formed by ball milling the powder to form a multi-scale homogeneous powder to avoid the addition of heterogeneous phases. According to the mechanical properties required by the design, the high-entropy alloy powder prepared under different ball milling processes is mixed in proportion. After mixing evenly, Sintering densification, while improving the strength of the material, avoids reducing the corrosion resistance of the high-entropy alloy

Method used

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  • A preparation method of multi-scale high-strength high-entropy alloy material for corrosive environment
  • A preparation method of multi-scale high-strength high-entropy alloy material for corrosive environment
  • A preparation method of multi-scale high-strength high-entropy alloy material for corrosive environment

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Experimental program
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Effect test

Embodiment 1

[0027] This embodiment includes the following steps:

[0028] Step 1: Carry out ball milling on the spherical high-entropy alloy powders respectively and then package them to obtain multi-scale high-entropy alloy powder A and multi-scale high-entropy alloy powder B; the ball milling process for obtaining the multi-scale high-entropy alloy powder A is: The stainless steel balls with a mass ratio of 25:1 and the CoCrFeNiCu high-entropy alloy powder with a particle size of 200 mesh prepared by gas atomization are put into the stainless steel ball mill tank of the liquid nitrogen type low-temperature planetary ball mill, and then the stainless steel ball mill tank is filled with After argon, ball milling for 120min under the condition of rotating speed of 450r / min, multiscale high-entropy alloy powder A is obtained in a stainless steel ball mill tank; the ball milling process for obtaining the multiscale high-entropy alloy powder B is as follows: the mass ratio is 25:1 200-mesh Co...

Embodiment 2

[0045] This embodiment includes the following steps:

[0046] Step 1: Carry out ball milling on the spherical high-entropy alloy powders respectively and then package them to obtain multi-scale high-entropy alloy powder A and multi-scale high-entropy alloy powder B; the ball milling process for obtaining the multi-scale high-entropy alloy powder A is: The stainless steel balls with a mass ratio of 25:1 and the CoCrFeNiCu high-entropy alloy powder with a particle size of 200 mesh prepared by gas atomization are put into the stainless steel ball mill tank of the liquid nitrogen type low-temperature planetary ball mill, and then the stainless steel ball mill tank is filled with After argon, ball milling for 120min under the condition of rotating speed of 450r / min, multiscale high-entropy alloy powder A is obtained in a stainless steel ball mill tank; the ball milling process for obtaining the multiscale high-entropy alloy powder B is as follows: the mass ratio is 25:1 200-mesh Co...

Embodiment 3

[0052] This embodiment includes the following steps:

[0053] Step 1: Carry out ball milling on the spherical high-entropy alloy powders respectively and then package them to obtain multi-scale high-entropy alloy powder A and multi-scale high-entropy alloy powder B; the ball milling process for obtaining the multi-scale high-entropy alloy powder A is: The stainless steel ball with a mass ratio of 10:1 and the CoCrFeNiMn high-entropy alloy powder with a particle size of 50 mesh prepared by gas atomization are loaded into the stainless steel ball mill tank of the liquid nitrogen type low-temperature planetary ball mill, and then the stainless steel ball mill tank is filled with After the argon gas, ball milling for 30min at a speed of 300r / min to obtain the multiscale high-entropy alloy powder A in a stainless steel ball mill tank; the ball milling process to obtain the multiscale high-entropy alloy powder B is as follows: the mass ratio is 25:1 200-mesh CoCrFeNiMn high-entropy ...

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Abstract

The invention discloses a method for preparing a multi-scale high-strength high-entropy alloy material used in a corrosive environment. Entropy alloy powder A and multi-scale high-entropy alloy powder B; 2. Mix multi-scale high-entropy alloy powder A and multi-scale high-entropy alloy powder B to obtain multi-level multi-scale high-entropy alloy powder; The scale high-entropy alloy powder is sintered to obtain a multi-scale high-strength high-entropy alloy material. In the present invention, the multi-scale high-entropy alloy powder with homogeneity and different average particle size is blended and then sintered to obtain a multi-scale high-strength high-entropy alloy material, which reduces the pollution of impurities in the preparation process and avoids the addition of heterogeneous phases. According to The required mechanical properties are designed, and the high-entropy alloy powders prepared by different ball milling processes are mixed in proportion to improve the strength of multi-scale high-strength high-entropy alloy materials while avoiding the reduction of corrosion resistance.

Description

technical field [0001] The invention belongs to the technical field of metal composite materials, and in particular relates to a preparation method of a multi-scale high-strength high-entropy alloy material used in a corrosive environment. Background technique [0002] The emergence of high-entropy alloys has broken the design concept of traditional alloys. Compared with traditional alloys with one or two components as the matrix, high-entropy alloys composed of four or five components have many excellent special properties, such as Radiation resistance, corrosion resistance, oxidation resistance, ultra-low temperature and high temperature mechanical properties, etc. As reported, the mechanical properties of CoCrFeNiMn alloys under low temperature liquid nitrogen conditions are more excellent than those at room temperature; AlCoCrFeNi 2.1 Eutectic high-entropy alloys have good fluidity, high-temperature oxidation resistance, high-temperature mechanical properties, and radia...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/04B22F1/00B22F9/04C22C30/00
CPCC22C1/04B22F9/04C22C30/00B22F2009/043B22F1/052
Inventor 董龙龙夏洪勇霍望图刘跃李亮张伟卢金文张于胜周廉
Owner 西安稀有金属材料研究院有限公司
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